Synthesis of (L)-Lactataldehyde and stereoselectivity of its Wittig reaction(L-乳醛的合成及Wittig反应立体选择性)
L-乳醛可以由L-乳酸甲酯经过一步硅保护，然后用二异丙基氢化铝溶液(DIBAl—H)还原制备得到.立体选择性化合物的制备是当代有机合成化学中非常重要而且具有挑战性的领域之一.高度立体选择性的各类化合物，包括立体高度选择性的烯烃化合物正在越来越频繁的运用在合成当中.本文系统地研究了L-乳醛与一系列不同类型的叶立德试剂在不同条件（改变温度、溶剂、碱）下发生Wittig反应的立体选择性，总结了一些基本规律，为今后得到立体专一的烯烃打下基础....
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| Format: | Article |
| Language: | zho |
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Zhejiang University Press
2008-01-01
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| Series: | Zhejiang Daxue xuebao. Lixue ban |
| Subjects: | |
| Online Access: | https://doi.org/zjup/1008-9497.2008.35.1.52-54 |
| _version_ | 1797236263291453440 |
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| author | ZHANGQian-yan(张前炎) HUQi-yan(胡琦艳) YANGDe-yu(杨德育) |
| author_facet | ZHANGQian-yan(张前炎) HUQi-yan(胡琦艳) YANGDe-yu(杨德育) |
| author_sort | ZHANGQian-yan(张前炎) |
| collection | DOAJ |
| description | L-乳醛可以由L-乳酸甲酯经过一步硅保护，然后用二异丙基氢化铝溶液(DIBAl—H)还原制备得到.立体选择性化合物的制备是当代有机合成化学中非常重要而且具有挑战性的领域之一.高度立体选择性的各类化合物，包括立体高度选择性的烯烃化合物正在越来越频繁的运用在合成当中.本文系统地研究了L-乳醛与一系列不同类型的叶立德试剂在不同条件（改变温度、溶剂、碱）下发生Wittig反应的立体选择性，总结了一些基本规律，为今后得到立体专一的烯烃打下基础. |
| first_indexed | 2024-04-24T17:01:04Z |
| format | Article |
| id | doaj.art-dd4d846999b7476ea012c25cc5b558d6 |
| institution | Directory Open Access Journal |
| issn | 1008-9497 |
| language | zho |
| last_indexed | 2024-04-24T17:01:04Z |
| publishDate | 2008-01-01 |
| publisher | Zhejiang University Press |
| record_format | Article |
| series | Zhejiang Daxue xuebao. Lixue ban |
| spelling | doaj.art-dd4d846999b7476ea012c25cc5b558d62024-03-29T01:58:25ZzhoZhejiang University PressZhejiang Daxue xuebao. Lixue ban1008-94972008-01-013515254zjup/1008-9497.2008.35.1.52-54Synthesis of (L)-Lactataldehyde and stereoselectivity of its Wittig reaction(L-乳醛的合成及Wittig反应立体选择性)ZHANGQian-yan(张前炎)0HUQi-yan(胡琦艳)1YANGDe-yu(杨德育)2Department of Chemistry, Zhejiang University, Hangzhou 310027, China(浙江大学化学系，浙江 杭州 310027)Department of Chemistry, Zhejiang University, Hangzhou 310027, China(浙江大学化学系，浙江 杭州 310027)Department of Chemistry, Zhejiang University, Hangzhou 310027, China(浙江大学化学系，浙江 杭州 310027)L-乳醛可以由L-乳酸甲酯经过一步硅保护，然后用二异丙基氢化铝溶液(DIBAl—H)还原制备得到.立体选择性化合物的制备是当代有机合成化学中非常重要而且具有挑战性的领域之一.高度立体选择性的各类化合物，包括立体高度选择性的烯烃化合物正在越来越频繁的运用在合成当中.本文系统地研究了L-乳醛与一系列不同类型的叶立德试剂在不同条件（改变温度、溶剂、碱）下发生Wittig反应的立体选择性，总结了一些基本规律，为今后得到立体专一的烯烃打下基础.https://doi.org/zjup/1008-9497.2008.35.1.52-54l-乳醛磷叶立德膦酸酯wittig反应立体选择性 |
| spellingShingle | ZHANGQian-yan(张前炎) HUQi-yan(胡琦艳) YANGDe-yu(杨德育) Synthesis of (L)-Lactataldehyde and stereoselectivity of its Wittig reaction(L-乳醛的合成及Wittig反应立体选择性) Zhejiang Daxue xuebao. Lixue ban l-乳醛 磷叶立德 膦酸酯 wittig反应 立体选择性 |
| title | Synthesis of (L)-Lactataldehyde and stereoselectivity of its Wittig reaction(L-乳醛的合成及Wittig反应立体选择性) |
| title_full | Synthesis of (L)-Lactataldehyde and stereoselectivity of its Wittig reaction(L-乳醛的合成及Wittig反应立体选择性) |
| title_fullStr | Synthesis of (L)-Lactataldehyde and stereoselectivity of its Wittig reaction(L-乳醛的合成及Wittig反应立体选择性) |
| title_full_unstemmed | Synthesis of (L)-Lactataldehyde and stereoselectivity of its Wittig reaction(L-乳醛的合成及Wittig反应立体选择性) |
| title_short | Synthesis of (L)-Lactataldehyde and stereoselectivity of its Wittig reaction(L-乳醛的合成及Wittig反应立体选择性) |
| title_sort | synthesis of l lactataldehyde and stereoselectivity of its wittig reaction l 乳醛的合成及wittig反应立体选择性 |
| topic | l-乳醛 磷叶立德 膦酸酯 wittig反应 立体选择性 |
| url | https://doi.org/zjup/1008-9497.2008.35.1.52-54 |
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