Preparation of low-cost nano and microcomposites from chicken eggshell, nano-silica and rice husk ash and their utilisations as additives for producing geopolymer cements

This work aims to prepare low-cost nanocomposite and microcomposite with lower molar ratio CaO/SiO2 (0.4). Nano-silica, rice husk ash and calcined chicken eggshell have been used as silica and calcium sources. Metakaolin has been separately replaced by 0, 10 and 20 wt% of each composite in order to...

Full description

Bibliographic Details
Main Authors: H. K. Tchakouté, D. E. Tchinda Mabah, C. Henning Rüscher, E. Kamseu, F. Andreola, M. C. Bignozzi, C. Leonelli
Format: Article
Language:English
Published: Taylor & Francis Group 2020-01-01
Series:Journal of Asian Ceramic Societies
Subjects:
Online Access:http://dx.doi.org/10.1080/21870764.2020.1718860
_version_ 1831753395500744704
author H. K. Tchakouté
D. E. Tchinda Mabah
C. Henning Rüscher
E. Kamseu
F. Andreola
M. C. Bignozzi
C. Leonelli
author_facet H. K. Tchakouté
D. E. Tchinda Mabah
C. Henning Rüscher
E. Kamseu
F. Andreola
M. C. Bignozzi
C. Leonelli
author_sort H. K. Tchakouté
collection DOAJ
description This work aims to prepare low-cost nanocomposite and microcomposite with lower molar ratio CaO/SiO2 (0.4). Nano-silica, rice husk ash and calcined chicken eggshell have been used as silica and calcium sources. Metakaolin has been separately replaced by 0, 10 and 20 wt% of each composite in order to study their behavior on the properties of geopolymers. The hardener used is sodium waterglass from rice husk ash. The surface area of nano-silica and rice husk ash was 54.40 and 4.08 m2/g, respectively. The cumulative volumes of the control geopolymer, the ones containing 10 wt% of microcomposite and nanocomposite are 119.71, 89.92 and 110.49 mm3/g, respectively. The compressive strength of the control specimen is around 64.02 MPa. The one using 10 wt% of microcomposite was 68.97 MPa. It drops to 42.88 MPa when metakaolin was replaced by 20 wt % of microcomposite. Whereas the one using 10 wt% of nanocomposite was 30.03 MPa and it decreases to 26.05 MPa when metakaolin was substituted by 20 wt% of nanocomposite. It can be concluded that 10 wt% of microcomposite could be mixed to metakaolin for strength development and nanocomposite does not recommend to use as an additive for producing high strength of geopolymer cements.
first_indexed 2024-12-21T23:21:12Z
format Article
id doaj.art-dd51efe5562d482d9e39de595d356195
institution Directory Open Access Journal
issn 2187-0764
language English
last_indexed 2024-12-21T23:21:12Z
publishDate 2020-01-01
publisher Taylor & Francis Group
record_format Article
series Journal of Asian Ceramic Societies
spelling doaj.art-dd51efe5562d482d9e39de595d3561952022-12-21T18:46:48ZengTaylor & Francis GroupJournal of Asian Ceramic Societies2187-07642020-01-018114916110.1080/21870764.2020.17188601718860Preparation of low-cost nano and microcomposites from chicken eggshell, nano-silica and rice husk ash and their utilisations as additives for producing geopolymer cementsH. K. Tchakouté0D. E. Tchinda Mabah1C. Henning Rüscher2E. Kamseu3F. Andreola4M. C. Bignozzi5C. Leonelli6University of Yaounde IUniversity of Yaounde IInstitut für MineralogieLocal Materials Promotion AuthorityUniversity of Modena and Reggio EmiliaUniversity of BolognaUniversity of Modena and Reggio EmiliaThis work aims to prepare low-cost nanocomposite and microcomposite with lower molar ratio CaO/SiO2 (0.4). Nano-silica, rice husk ash and calcined chicken eggshell have been used as silica and calcium sources. Metakaolin has been separately replaced by 0, 10 and 20 wt% of each composite in order to study their behavior on the properties of geopolymers. The hardener used is sodium waterglass from rice husk ash. The surface area of nano-silica and rice husk ash was 54.40 and 4.08 m2/g, respectively. The cumulative volumes of the control geopolymer, the ones containing 10 wt% of microcomposite and nanocomposite are 119.71, 89.92 and 110.49 mm3/g, respectively. The compressive strength of the control specimen is around 64.02 MPa. The one using 10 wt% of microcomposite was 68.97 MPa. It drops to 42.88 MPa when metakaolin was replaced by 20 wt % of microcomposite. Whereas the one using 10 wt% of nanocomposite was 30.03 MPa and it decreases to 26.05 MPa when metakaolin was substituted by 20 wt% of nanocomposite. It can be concluded that 10 wt% of microcomposite could be mixed to metakaolin for strength development and nanocomposite does not recommend to use as an additive for producing high strength of geopolymer cements.http://dx.doi.org/10.1080/21870764.2020.1718860metakaolinmicrocompositenanocompositesodium waterglassgeopolymer cements
spellingShingle H. K. Tchakouté
D. E. Tchinda Mabah
C. Henning Rüscher
E. Kamseu
F. Andreola
M. C. Bignozzi
C. Leonelli
Preparation of low-cost nano and microcomposites from chicken eggshell, nano-silica and rice husk ash and their utilisations as additives for producing geopolymer cements
Journal of Asian Ceramic Societies
metakaolin
microcomposite
nanocomposite
sodium waterglass
geopolymer cements
title Preparation of low-cost nano and microcomposites from chicken eggshell, nano-silica and rice husk ash and their utilisations as additives for producing geopolymer cements
title_full Preparation of low-cost nano and microcomposites from chicken eggshell, nano-silica and rice husk ash and their utilisations as additives for producing geopolymer cements
title_fullStr Preparation of low-cost nano and microcomposites from chicken eggshell, nano-silica and rice husk ash and their utilisations as additives for producing geopolymer cements
title_full_unstemmed Preparation of low-cost nano and microcomposites from chicken eggshell, nano-silica and rice husk ash and their utilisations as additives for producing geopolymer cements
title_short Preparation of low-cost nano and microcomposites from chicken eggshell, nano-silica and rice husk ash and their utilisations as additives for producing geopolymer cements
title_sort preparation of low cost nano and microcomposites from chicken eggshell nano silica and rice husk ash and their utilisations as additives for producing geopolymer cements
topic metakaolin
microcomposite
nanocomposite
sodium waterglass
geopolymer cements
url http://dx.doi.org/10.1080/21870764.2020.1718860
work_keys_str_mv AT hktchakoute preparationoflowcostnanoandmicrocompositesfromchickeneggshellnanosilicaandricehuskashandtheirutilisationsasadditivesforproducinggeopolymercements
AT detchindamabah preparationoflowcostnanoandmicrocompositesfromchickeneggshellnanosilicaandricehuskashandtheirutilisationsasadditivesforproducinggeopolymercements
AT chenningruscher preparationoflowcostnanoandmicrocompositesfromchickeneggshellnanosilicaandricehuskashandtheirutilisationsasadditivesforproducinggeopolymercements
AT ekamseu preparationoflowcostnanoandmicrocompositesfromchickeneggshellnanosilicaandricehuskashandtheirutilisationsasadditivesforproducinggeopolymercements
AT fandreola preparationoflowcostnanoandmicrocompositesfromchickeneggshellnanosilicaandricehuskashandtheirutilisationsasadditivesforproducinggeopolymercements
AT mcbignozzi preparationoflowcostnanoandmicrocompositesfromchickeneggshellnanosilicaandricehuskashandtheirutilisationsasadditivesforproducinggeopolymercements
AT cleonelli preparationoflowcostnanoandmicrocompositesfromchickeneggshellnanosilicaandricehuskashandtheirutilisationsasadditivesforproducinggeopolymercements