Transient Study of Femtosecond Laser–Induced Ge<sub>2</sub>Sb<sub>2</sub>Te<sub>5</sub> Phase Change Film Morphology

Femtosecond laser-induced crystallization and ablation of Ge<sub>2</sub>Sb<sub>2</sub>Te<sub>5</sub> (GST) phase change film is investigated by reflectivity pump-probing technology. Below the ablation threshold, the face-centered cubic structure (FCC) state in the...

Full description

Bibliographic Details
Main Authors: Wenju Zhou, Zifeng Zhang, Qingwei Zhang, Dongfeng Qi, Tianxiang Xu, Shixun Dai, Xiang Shen
Format: Article
Language:English
Published: MDPI AG 2021-05-01
Series:Micromachines
Subjects:
Online Access:https://www.mdpi.com/2072-666X/12/6/616
_version_ 1797532487401865216
author Wenju Zhou
Zifeng Zhang
Qingwei Zhang
Dongfeng Qi
Tianxiang Xu
Shixun Dai
Xiang Shen
author_facet Wenju Zhou
Zifeng Zhang
Qingwei Zhang
Dongfeng Qi
Tianxiang Xu
Shixun Dai
Xiang Shen
author_sort Wenju Zhou
collection DOAJ
description Femtosecond laser-induced crystallization and ablation of Ge<sub>2</sub>Sb<sub>2</sub>Te<sub>5</sub> (GST) phase change film is investigated by reflectivity pump-probing technology. Below the ablation threshold, the face-centered cubic structure (FCC) state in the central area can be formed, and cylindrical rims are formed in the peripheral dewetting zone due to the solidification of transported matter. The time of surface temperature dropping to the crystallization point needs about 30 ps for 5.86 mJ/cm<sup>2</sup> and 82 ps for 7.04 mJ/cm<sup>2</sup>, respectively. At higher laser fluence, crystallization GST island structures appear in the central ablation region due to the extremely short heating time (100 ps). Furthermore, crystallization rate is faster than the ablation rate of the GST film, which is caused by different reflectivity.
first_indexed 2024-03-10T11:00:57Z
format Article
id doaj.art-dd630e3ced4b4697bef4562ecebf135a
institution Directory Open Access Journal
issn 2072-666X
language English
last_indexed 2024-03-10T11:00:57Z
publishDate 2021-05-01
publisher MDPI AG
record_format Article
series Micromachines
spelling doaj.art-dd630e3ced4b4697bef4562ecebf135a2023-11-21T21:34:26ZengMDPI AGMicromachines2072-666X2021-05-0112661610.3390/mi12060616Transient Study of Femtosecond Laser–Induced Ge<sub>2</sub>Sb<sub>2</sub>Te<sub>5</sub> Phase Change Film MorphologyWenju Zhou0Zifeng Zhang1Qingwei Zhang2Dongfeng Qi3Tianxiang Xu4Shixun Dai5Xiang Shen6Laboratory of Infrared Materials and Devices, Ningbo University, Ningbo 315211, ChinaCollege of Mechanical and Electronic Engineering, Chaohu University, Hefei 230000, ChinaLaboratory of Infrared Materials and Devices, Ningbo University, Ningbo 315211, ChinaCenter for Advanced Laser Manufacturing (CALM), Shandong University of Technology, Zibo 255000, ChinaLaboratory of Infrared Materials and Devices, Ningbo University, Ningbo 315211, ChinaLaboratory of Infrared Materials and Devices, Ningbo University, Ningbo 315211, ChinaLaboratory of Infrared Materials and Devices, Ningbo University, Ningbo 315211, ChinaFemtosecond laser-induced crystallization and ablation of Ge<sub>2</sub>Sb<sub>2</sub>Te<sub>5</sub> (GST) phase change film is investigated by reflectivity pump-probing technology. Below the ablation threshold, the face-centered cubic structure (FCC) state in the central area can be formed, and cylindrical rims are formed in the peripheral dewetting zone due to the solidification of transported matter. The time of surface temperature dropping to the crystallization point needs about 30 ps for 5.86 mJ/cm<sup>2</sup> and 82 ps for 7.04 mJ/cm<sup>2</sup>, respectively. At higher laser fluence, crystallization GST island structures appear in the central ablation region due to the extremely short heating time (100 ps). Furthermore, crystallization rate is faster than the ablation rate of the GST film, which is caused by different reflectivity.https://www.mdpi.com/2072-666X/12/6/616laser-induced crystallizationpump-probing technologypulse laser irradiation
spellingShingle Wenju Zhou
Zifeng Zhang
Qingwei Zhang
Dongfeng Qi
Tianxiang Xu
Shixun Dai
Xiang Shen
Transient Study of Femtosecond Laser–Induced Ge<sub>2</sub>Sb<sub>2</sub>Te<sub>5</sub> Phase Change Film Morphology
Micromachines
laser-induced crystallization
pump-probing technology
pulse laser irradiation
title Transient Study of Femtosecond Laser–Induced Ge<sub>2</sub>Sb<sub>2</sub>Te<sub>5</sub> Phase Change Film Morphology
title_full Transient Study of Femtosecond Laser–Induced Ge<sub>2</sub>Sb<sub>2</sub>Te<sub>5</sub> Phase Change Film Morphology
title_fullStr Transient Study of Femtosecond Laser–Induced Ge<sub>2</sub>Sb<sub>2</sub>Te<sub>5</sub> Phase Change Film Morphology
title_full_unstemmed Transient Study of Femtosecond Laser–Induced Ge<sub>2</sub>Sb<sub>2</sub>Te<sub>5</sub> Phase Change Film Morphology
title_short Transient Study of Femtosecond Laser–Induced Ge<sub>2</sub>Sb<sub>2</sub>Te<sub>5</sub> Phase Change Film Morphology
title_sort transient study of femtosecond laser induced ge sub 2 sub sb sub 2 sub te sub 5 sub phase change film morphology
topic laser-induced crystallization
pump-probing technology
pulse laser irradiation
url https://www.mdpi.com/2072-666X/12/6/616
work_keys_str_mv AT wenjuzhou transientstudyoffemtosecondlaserinducedgesub2subsbsub2subtesub5subphasechangefilmmorphology
AT zifengzhang transientstudyoffemtosecondlaserinducedgesub2subsbsub2subtesub5subphasechangefilmmorphology
AT qingweizhang transientstudyoffemtosecondlaserinducedgesub2subsbsub2subtesub5subphasechangefilmmorphology
AT dongfengqi transientstudyoffemtosecondlaserinducedgesub2subsbsub2subtesub5subphasechangefilmmorphology
AT tianxiangxu transientstudyoffemtosecondlaserinducedgesub2subsbsub2subtesub5subphasechangefilmmorphology
AT shixundai transientstudyoffemtosecondlaserinducedgesub2subsbsub2subtesub5subphasechangefilmmorphology
AT xiangshen transientstudyoffemtosecondlaserinducedgesub2subsbsub2subtesub5subphasechangefilmmorphology