State-of-Charge Monitoring and Battery Diagnosis of NiCd Cells Using Impedance Spectroscopy

With respect to aeronautical applications, the state-of-charge (SOC) and state-of-health (SOH) of rechargeable nickel&#8722;cadmium batteries was investigated with the help of the frequency-dependent reactance Im <i>Z</i>(<i>&#969;</i>) and the pseudo-capacitance <...

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Bibliographic Details
Main Authors: Peter Kurzweil, Wolfgang Scheuerpflug
Format: Article
Language:English
Published: MDPI AG 2020-01-01
Series:Batteries
Subjects:
Online Access:https://www.mdpi.com/2313-0105/6/1/4
Description
Summary:With respect to aeronautical applications, the state-of-charge (SOC) and state-of-health (SOH) of rechargeable nickel&#8722;cadmium batteries was investigated with the help of the frequency-dependent reactance Im <i>Z</i>(<i>&#969;</i>) and the pseudo-capacitance <i>C</i>(<i>&#969;</i>) in the frequency range between 1 kHz and 0.1 Hz. The method of SOC monitoring using impedance spectroscopy is evaluated with the example of 1.5-year long-term measurements of commercial devices. A linear correlation between voltage and capacitance is observed as long as overcharge and deep discharge are avoided. Pseudo-charge <i>Q</i>(<i>&#969;</i>) = <i>C</i>(<i>&#969;</i>)&#8901;<i>U</i> at 1 Hz with respect to the rated capacity is proposed as a reliable SOH indicator for rapid measurements. The benefit of different evaluation methods and diagram types for impedance data is outlined.
ISSN:2313-0105