A Study of the Brönsted Site Acidity of Crystalline and Amorphous Aluminosilicates: 2. Thermal Decomposition of Grafted Acetyl Groups
A study has been made by desorption mass spectrometry of the destruction of grafted acetyl groups on the surface of H-mordenite, H-ZSM-5, H-Y-faujasite, Al-containing aerosil and aluminosilicate compounds layered on an aerosil surface. It has been established that the thermal decomposition of acetyl...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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SAGE Publications
1996-12-01
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| Series: | Adsorption Science & Technology |
| Online Access: | https://doi.org/10.1177/026361749601400603 |
| _version_ | 1797283690473062400 |
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| author | V.V. Brei A.V. Brichka |
| author_facet | V.V. Brei A.V. Brichka |
| author_sort | V.V. Brei |
| collection | DOAJ |
| description | A study has been made by desorption mass spectrometry of the destruction of grafted acetyl groups on the surface of H-mordenite, H-ZSM-5, H-Y-faujasite, Al-containing aerosil and aluminosilicate compounds layered on an aerosil surface. It has been established that the thermal decomposition of acetyl groups attached through Brönsted acid sites proceeds with the formation of ketene over the same temperature range (320–360°C) for all the samples. The implications of this result for the strength of acid sites are discussed. |
| first_indexed | 2024-03-07T17:34:30Z |
| format | Article |
| id | doaj.art-dd72bab490a54acb8e3abf46867f582c |
| institution | Directory Open Access Journal |
| issn | 0263-6174 2048-4038 |
| language | English |
| last_indexed | 2024-03-07T17:34:30Z |
| publishDate | 1996-12-01 |
| publisher | SAGE Publications |
| record_format | Article |
| series | Adsorption Science & Technology |
| spelling | doaj.art-dd72bab490a54acb8e3abf46867f582c2024-03-02T17:12:07ZengSAGE PublicationsAdsorption Science & Technology0263-61742048-40381996-12-011410.1177/026361749601400603A Study of the Brönsted Site Acidity of Crystalline and Amorphous Aluminosilicates: 2. Thermal Decomposition of Grafted Acetyl GroupsV.V. BreiA.V. BrichkaA study has been made by desorption mass spectrometry of the destruction of grafted acetyl groups on the surface of H-mordenite, H-ZSM-5, H-Y-faujasite, Al-containing aerosil and aluminosilicate compounds layered on an aerosil surface. It has been established that the thermal decomposition of acetyl groups attached through Brönsted acid sites proceeds with the formation of ketene over the same temperature range (320–360°C) for all the samples. The implications of this result for the strength of acid sites are discussed.https://doi.org/10.1177/026361749601400603 |
| spellingShingle | V.V. Brei A.V. Brichka A Study of the Brönsted Site Acidity of Crystalline and Amorphous Aluminosilicates: 2. Thermal Decomposition of Grafted Acetyl Groups Adsorption Science & Technology |
| title | A Study of the Brönsted Site Acidity of Crystalline and Amorphous Aluminosilicates: 2. Thermal Decomposition of Grafted Acetyl Groups |
| title_full | A Study of the Brönsted Site Acidity of Crystalline and Amorphous Aluminosilicates: 2. Thermal Decomposition of Grafted Acetyl Groups |
| title_fullStr | A Study of the Brönsted Site Acidity of Crystalline and Amorphous Aluminosilicates: 2. Thermal Decomposition of Grafted Acetyl Groups |
| title_full_unstemmed | A Study of the Brönsted Site Acidity of Crystalline and Amorphous Aluminosilicates: 2. Thermal Decomposition of Grafted Acetyl Groups |
| title_short | A Study of the Brönsted Site Acidity of Crystalline and Amorphous Aluminosilicates: 2. Thermal Decomposition of Grafted Acetyl Groups |
| title_sort | study of the bronsted site acidity of crystalline and amorphous aluminosilicates 2 thermal decomposition of grafted acetyl groups |
| url | https://doi.org/10.1177/026361749601400603 |
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