Magnetic Properties of FeNiCoAlTiNb Shape Memory Alloys

The magnetic properties of the new Fe<sub>41</sub>Ni<sub>28</sub>Co<sub>17</sub>Al<sub>11.5</sub>(Ti+Nb)<sub>2.5</sub> (at. %) shape memory alloy system were studied in this work. The magnetic properties were characterized by thermo-magneti...

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Main Authors: Chau-Yi Tsai, Li-Wei Tseng, Yu-Chih Tzeng, Po-Yu Lee
Format: Article
Language:English
Published: MDPI AG 2022-01-01
Series:Crystals
Subjects:
Online Access:https://www.mdpi.com/2073-4352/12/1/121
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author Chau-Yi Tsai
Li-Wei Tseng
Yu-Chih Tzeng
Po-Yu Lee
author_facet Chau-Yi Tsai
Li-Wei Tseng
Yu-Chih Tzeng
Po-Yu Lee
author_sort Chau-Yi Tsai
collection DOAJ
description The magnetic properties of the new Fe<sub>41</sub>Ni<sub>28</sub>Co<sub>17</sub>Al<sub>11.5</sub>(Ti+Nb)<sub>2.5</sub> (at. %) shape memory alloy system were studied in this work. The magnetic properties were characterized by thermo-magnetization and a vibrating sample magnetometer (VSM). In iron-based shape memory alloys, aging heat treatment is crucial for obtaining the properties of superelasticity and shape memory. In this study, we focus on the magnetization, martensitic transformation temperatures, and microstructure of this alloy during the aging process at 600 °C. From the X-ray diffraction (XRD) results, the new peak γ’ is presented during the aging process. The intensity of this new peak (γ’) increases with the aging time, while the intensity of the FCC (111) austenite peak decreases with aging time. Transmission electron microscope (TEM) results show that the size of the precipitate increases with increasing the aging times from 24 to 72 h. Thermo-magnetization results show that: (1) phase transformation is observed when the aging time is at least 24 h, (2) the transformation temperature increases with the aging time, (3) transformation temperatures tend to increase while the magnetic field increases from 0.05 to 7 Tesla, and (4) the magnetization saturates after aging time reaches 24 h. Vibrating sample magnetometer (VSM) results show that thermal process was found to significantly affect the magnetic properties of this alloy, especially on saturated magnetic magnetization and magnetic moment reversal behavior.
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spelling doaj.art-dd8887321a3f4ad281b504ffa9ba5b7a2023-11-23T13:25:34ZengMDPI AGCrystals2073-43522022-01-0112112110.3390/cryst12010121Magnetic Properties of FeNiCoAlTiNb Shape Memory AlloysChau-Yi Tsai0Li-Wei Tseng1Yu-Chih Tzeng2Po-Yu Lee3Department of Materials Science and Engineering, National Formosa University, Yunlin 632301, TaiwanDepartment of Mechatronics Engineering, National Changhua University of Education, Changhua 50007, TaiwanDepartment of Power Vehicle and Systems Engineering, Chung Cheng Institute of Technology, National Defense University, Taoyuan City 33550, TaiwanDepartment of Mechatronics Engineering, National Changhua University of Education, Changhua 50007, TaiwanThe magnetic properties of the new Fe<sub>41</sub>Ni<sub>28</sub>Co<sub>17</sub>Al<sub>11.5</sub>(Ti+Nb)<sub>2.5</sub> (at. %) shape memory alloy system were studied in this work. The magnetic properties were characterized by thermo-magnetization and a vibrating sample magnetometer (VSM). In iron-based shape memory alloys, aging heat treatment is crucial for obtaining the properties of superelasticity and shape memory. In this study, we focus on the magnetization, martensitic transformation temperatures, and microstructure of this alloy during the aging process at 600 °C. From the X-ray diffraction (XRD) results, the new peak γ’ is presented during the aging process. The intensity of this new peak (γ’) increases with the aging time, while the intensity of the FCC (111) austenite peak decreases with aging time. Transmission electron microscope (TEM) results show that the size of the precipitate increases with increasing the aging times from 24 to 72 h. Thermo-magnetization results show that: (1) phase transformation is observed when the aging time is at least 24 h, (2) the transformation temperature increases with the aging time, (3) transformation temperatures tend to increase while the magnetic field increases from 0.05 to 7 Tesla, and (4) the magnetization saturates after aging time reaches 24 h. Vibrating sample magnetometer (VSM) results show that thermal process was found to significantly affect the magnetic properties of this alloy, especially on saturated magnetic magnetization and magnetic moment reversal behavior.https://www.mdpi.com/2073-4352/12/1/121shape memory alloysFeNiCoAlTiNbmagnetic propertytransformation temperaturesaging heat treatment
spellingShingle Chau-Yi Tsai
Li-Wei Tseng
Yu-Chih Tzeng
Po-Yu Lee
Magnetic Properties of FeNiCoAlTiNb Shape Memory Alloys
Crystals
shape memory alloys
FeNiCoAlTiNb
magnetic property
transformation temperatures
aging heat treatment
title Magnetic Properties of FeNiCoAlTiNb Shape Memory Alloys
title_full Magnetic Properties of FeNiCoAlTiNb Shape Memory Alloys
title_fullStr Magnetic Properties of FeNiCoAlTiNb Shape Memory Alloys
title_full_unstemmed Magnetic Properties of FeNiCoAlTiNb Shape Memory Alloys
title_short Magnetic Properties of FeNiCoAlTiNb Shape Memory Alloys
title_sort magnetic properties of fenicoaltinb shape memory alloys
topic shape memory alloys
FeNiCoAlTiNb
magnetic property
transformation temperatures
aging heat treatment
url https://www.mdpi.com/2073-4352/12/1/121
work_keys_str_mv AT chauyitsai magneticpropertiesoffenicoaltinbshapememoryalloys
AT liweitseng magneticpropertiesoffenicoaltinbshapememoryalloys
AT yuchihtzeng magneticpropertiesoffenicoaltinbshapememoryalloys
AT poyulee magneticpropertiesoffenicoaltinbshapememoryalloys