Oxa-Michael-initiated cascade reactions of levoglucosenone

The reactions of aromatic aldehydes and levoglucosenone promoted by methoxide gives bridged α,β-unsaturated ketones, formed by a series of oxa-Michael-initiated cascade reactions in yields of up to 91% (14 examples). A complex series of equilibria operate during the reaction, and the formation of th...

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Bibliographic Details
Main Authors: Julian Klepp, Thomas Bousfield, Hugh Cummins, Sarah V. A.-M. Legendre, Jason E. Camp, Ben W. Greatrex
Format: Article
Language:English
Published: Beilstein-Institut 2022-10-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
Online Access:https://doi.org/10.3762/bjoc.18.151