An efficient energy characteristics and explosion heat improving method of FOX-7-based aluminized explosives

Exploring new composite explosives based on 1,1-diamino-2,2-dinitroethylene (FOX-7) is significant in the field of insensitive high explosives (IHE). Despite having good detonation performance compared to RDX, FOX-7 has not been successfully applied in the preparations of aluminized explosives due t...

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Main Authors: Xiong Yang, Kai Zhao, Xuan Tian, Zhiqun Chen, Xueqian Fang, Qi Xiao, Xin Li, Jun Dong, Yafeng Hang, Xiaofeng Wang
Format: Article
Language:English
Published: KeAi Communications Co. Ltd. 2021-03-01
Series:FirePhysChem
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2667134421000043
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author Xiong Yang
Kai Zhao
Xuan Tian
Zhiqun Chen
Xueqian Fang
Qi Xiao
Xin Li
Jun Dong
Yafeng Hang
Xiaofeng Wang
author_facet Xiong Yang
Kai Zhao
Xuan Tian
Zhiqun Chen
Xueqian Fang
Qi Xiao
Xin Li
Jun Dong
Yafeng Hang
Xiaofeng Wang
author_sort Xiong Yang
collection DOAJ
description Exploring new composite explosives based on 1,1-diamino-2,2-dinitroethylene (FOX-7) is significant in the field of insensitive high explosives (IHE). Despite having good detonation performance compared to RDX, FOX-7 has not been successfully applied in the preparations of aluminized explosives due to the poor explosion heat values. In this paper, the explosion heat and detonation velocity of FOX-7-based aluminized explosives were studied systematically. The experiment results showed that the explosion heat of FOX-7-based aluminized explosives are significantly lower than that of RDX-based ones, especially when the content of aluminum powder exceeds 30%. To solve this problem, a simple but effective method of adding RDX to FOX-7-based aluminized explosives was developed, leading to a huge growth of explosion heat values. Finally, in order to compare the safety performance with RDX-based aluminized explosives, the low vulnerability of the FOX-7/RDX-based aluminized explosives formulation was investigated by fast cook-off, sympathetic detonation and 12.7 mm bullet impact tests. The results showed that the safety performance of FOX-7/RDX-based aluminized explosives is better than that of RDX-based aluminized explosives, proving that good low vulnerability is kept with the addition of RDX into FOX-7-based aluminized explosives.
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spelling doaj.art-dd97f44e6ad144198cc412d9ad1b52a82022-12-27T04:40:28ZengKeAi Communications Co. Ltd.FirePhysChem2667-13442021-03-011117An efficient energy characteristics and explosion heat improving method of FOX-7-based aluminized explosivesXiong Yang0Kai Zhao1Xuan Tian2Zhiqun Chen3Xueqian Fang4Qi Xiao5Xin Li6Jun Dong7Yafeng Hang8Xiaofeng Wang9Xi'an Modern Chemistry Research Institute, Xi'an 710065, ChinaXi'an Modern Chemistry Research Institute, Xi'an 710065, ChinaXi'an Modern Chemistry Research Institute, Xi'an 710065, ChinaXi'an Modern Chemistry Research Institute, Xi'an 710065, ChinaXi'an Modern Chemistry Research Institute, Xi'an 710065, ChinaXi'an Modern Chemistry Research Institute, Xi'an 710065, ChinaXi'an Modern Chemistry Research Institute, Xi'an 710065, ChinaXi'an Modern Chemistry Research Institute, Xi'an 710065, ChinaCorresponding authors.; Xi'an Modern Chemistry Research Institute, Xi'an 710065, ChinaCorresponding authors.; Xi'an Modern Chemistry Research Institute, Xi'an 710065, ChinaExploring new composite explosives based on 1,1-diamino-2,2-dinitroethylene (FOX-7) is significant in the field of insensitive high explosives (IHE). Despite having good detonation performance compared to RDX, FOX-7 has not been successfully applied in the preparations of aluminized explosives due to the poor explosion heat values. In this paper, the explosion heat and detonation velocity of FOX-7-based aluminized explosives were studied systematically. The experiment results showed that the explosion heat of FOX-7-based aluminized explosives are significantly lower than that of RDX-based ones, especially when the content of aluminum powder exceeds 30%. To solve this problem, a simple but effective method of adding RDX to FOX-7-based aluminized explosives was developed, leading to a huge growth of explosion heat values. Finally, in order to compare the safety performance with RDX-based aluminized explosives, the low vulnerability of the FOX-7/RDX-based aluminized explosives formulation was investigated by fast cook-off, sympathetic detonation and 12.7 mm bullet impact tests. The results showed that the safety performance of FOX-7/RDX-based aluminized explosives is better than that of RDX-based aluminized explosives, proving that good low vulnerability is kept with the addition of RDX into FOX-7-based aluminized explosives.http://www.sciencedirect.com/science/article/pii/S2667134421000043Aluminized explosives1,1-diamino-2,2-dinitroethylene (FOX-7)Explosion heatInsensitive high explosivesLow vulnerability
spellingShingle Xiong Yang
Kai Zhao
Xuan Tian
Zhiqun Chen
Xueqian Fang
Qi Xiao
Xin Li
Jun Dong
Yafeng Hang
Xiaofeng Wang
An efficient energy characteristics and explosion heat improving method of FOX-7-based aluminized explosives
FirePhysChem
Aluminized explosives
1,1-diamino-2,2-dinitroethylene (FOX-7)
Explosion heat
Insensitive high explosives
Low vulnerability
title An efficient energy characteristics and explosion heat improving method of FOX-7-based aluminized explosives
title_full An efficient energy characteristics and explosion heat improving method of FOX-7-based aluminized explosives
title_fullStr An efficient energy characteristics and explosion heat improving method of FOX-7-based aluminized explosives
title_full_unstemmed An efficient energy characteristics and explosion heat improving method of FOX-7-based aluminized explosives
title_short An efficient energy characteristics and explosion heat improving method of FOX-7-based aluminized explosives
title_sort efficient energy characteristics and explosion heat improving method of fox 7 based aluminized explosives
topic Aluminized explosives
1,1-diamino-2,2-dinitroethylene (FOX-7)
Explosion heat
Insensitive high explosives
Low vulnerability
url http://www.sciencedirect.com/science/article/pii/S2667134421000043
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