[N,N′-Bis(2,4,6-trimethylphenyl)ethane-1,2-diimine-κ2N,N′]tetracarbonylchromium(0)
The octahedral coordination of the Cr0 atom in the title compound, [Cr(C20H24N2)(CO)4], displays some distortion. This is manifested by an exocyclic torsion angle C(mesitylene)—N—Cr—C(carbonyl) that deviates by more than 20° from planarity. Anot...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2012-07-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812024786 |
| _version_ | 1798017138198315008 |
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| author | Marilé Landman Roan Fraser René Pretorius Rohen Prinsloo David C. Liles Petrus H. van Rooyen |
| author_facet | Marilé Landman Roan Fraser René Pretorius Rohen Prinsloo David C. Liles Petrus H. van Rooyen |
| author_sort | Marilé Landman |
| collection | DOAJ |
| description | The octahedral coordination of the Cr0 atom in the title compound, [Cr(C20H24N2)(CO)4], displays some distortion. This is manifested by an exocyclic torsion angle C(mesitylene)—N—Cr—C(carbonyl) that deviates by more than 20° from planarity. Another structural feature is the significant distortion from linearity of the Cr—C—O angles of the two carbonyl groups that interact with both ortho-methyl groups of the two mesitylene rings. The remaining two carbonyl groups overlap with the centres of the mesitylene rings themselves and are linear within <3°. |
| first_indexed | 2024-04-11T16:00:50Z |
| format | Article |
| id | doaj.art-dd9e9b1b946f41c199e92cf9090808d1 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T16:00:50Z |
| publishDate | 2012-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-dd9e9b1b946f41c199e92cf9090808d12022-12-22T04:15:01ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-07-01687m930m93010.1107/S1600536812024786[N,N′-Bis(2,4,6-trimethylphenyl)ethane-1,2-diimine-κ2N,N′]tetracarbonylchromium(0)Marilé LandmanRoan FraserRené PretoriusRohen PrinslooDavid C. LilesPetrus H. van RooyenThe octahedral coordination of the Cr0 atom in the title compound, [Cr(C20H24N2)(CO)4], displays some distortion. This is manifested by an exocyclic torsion angle C(mesitylene)—N—Cr—C(carbonyl) that deviates by more than 20° from planarity. Another structural feature is the significant distortion from linearity of the Cr—C—O angles of the two carbonyl groups that interact with both ortho-methyl groups of the two mesitylene rings. The remaining two carbonyl groups overlap with the centres of the mesitylene rings themselves and are linear within <3°.http://scripts.iucr.org/cgi-bin/paper?S1600536812024786 |
| spellingShingle | Marilé Landman Roan Fraser René Pretorius Rohen Prinsloo David C. Liles Petrus H. van Rooyen [N,N′-Bis(2,4,6-trimethylphenyl)ethane-1,2-diimine-κ2N,N′]tetracarbonylchromium(0) Acta Crystallographica Section E |
| title | [N,N′-Bis(2,4,6-trimethylphenyl)ethane-1,2-diimine-κ2N,N′]tetracarbonylchromium(0) |
| title_full | [N,N′-Bis(2,4,6-trimethylphenyl)ethane-1,2-diimine-κ2N,N′]tetracarbonylchromium(0) |
| title_fullStr | [N,N′-Bis(2,4,6-trimethylphenyl)ethane-1,2-diimine-κ2N,N′]tetracarbonylchromium(0) |
| title_full_unstemmed | [N,N′-Bis(2,4,6-trimethylphenyl)ethane-1,2-diimine-κ2N,N′]tetracarbonylchromium(0) |
| title_short | [N,N′-Bis(2,4,6-trimethylphenyl)ethane-1,2-diimine-κ2N,N′]tetracarbonylchromium(0) |
| title_sort | n n amp 8242 bis 2 4 6 trimethylphenyl ethane 1 2 diimine amp 954 2n n amp 8242 tetracarbonylchromium 0 |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812024786 |
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