Correlation of chemical structures of thiazole accelerators with rheokinetic properties of elastomeric compounds
The quantum-chemical calculation of structures of sulfur vulcanization organic thiazole accelerators was performed. It was established that there is a correlation between the atomic electronegativity of nitrogen, the S–N length bond of and the rheokinetic properties of sulfur vulcanizates with Shung...
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| Format: | Article |
| Language: | Russian |
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MIREA - Russian Technological University
2014-10-01
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| Series: | Тонкие химические технологии |
| Subjects: | |
| Online Access: | https://www.finechem-mirea.ru/jour/article/view/440 |
| _version_ | 1797882074969931776 |
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| author | Yu. А. Glebova А. V. Krylov V. V. Egorova V. А. Scherschnev S. V. Reznichenko Yu. I. Lyakin |
| author_facet | Yu. А. Glebova А. V. Krylov V. V. Egorova V. А. Scherschnev S. V. Reznichenko Yu. I. Lyakin |
| author_sort | Yu. А. Glebova |
| collection | DOAJ |
| description | The quantum-chemical calculation of structures of sulfur vulcanization organic thiazole accelerators was performed. It was established that there is a correlation between the atomic electronegativity of nitrogen, the S–N length bond of and the rheokinetic properties of sulfur vulcanizates with Shungite and ZnO as activators. Moreover, scorching time was influenced on type of an activator. It should be noted that in the presence of Shungite under vulcanization began earlier than with ZnO except for MBT. So the strength of the physical adsorption of MBT on the surface of ZnO similars to Shungite. |
| first_indexed | 2024-04-10T03:30:17Z |
| format | Article |
| id | doaj.art-dda1072bf3254f9ebbc20e238abc058d |
| institution | Directory Open Access Journal |
| issn | 2410-6593 2686-7575 |
| language | Russian |
| last_indexed | 2024-04-10T03:30:17Z |
| publishDate | 2014-10-01 |
| publisher | MIREA - Russian Technological University |
| record_format | Article |
| series | Тонкие химические технологии |
| spelling | doaj.art-dda1072bf3254f9ebbc20e238abc058d2023-03-13T07:25:35ZrusMIREA - Russian Technological UniversityТонкие химические технологии2410-65932686-75752014-10-01955560434Correlation of chemical structures of thiazole accelerators with rheokinetic properties of elastomeric compoundsYu. А. Glebova0А. V. Krylov1V. V. Egorova2V. А. Scherschnev3S. V. Reznichenko4Yu. I. Lyakin5M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571The quantum-chemical calculation of structures of sulfur vulcanization organic thiazole accelerators was performed. It was established that there is a correlation between the atomic electronegativity of nitrogen, the S–N length bond of and the rheokinetic properties of sulfur vulcanizates with Shungite and ZnO as activators. Moreover, scorching time was influenced on type of an activator. It should be noted that in the presence of Shungite under vulcanization began earlier than with ZnO except for MBT. So the strength of the physical adsorption of MBT on the surface of ZnO similars to Shungite.https://www.finechem-mirea.ru/jour/article/view/440vulcanization accelerators, chemical structures, rheokinetic properties, sulfur vulcanization, activators of vulcanization, shungite. |
| spellingShingle | Yu. А. Glebova А. V. Krylov V. V. Egorova V. А. Scherschnev S. V. Reznichenko Yu. I. Lyakin Correlation of chemical structures of thiazole accelerators with rheokinetic properties of elastomeric compounds Тонкие химические технологии vulcanization accelerators, chemical structures, rheokinetic properties, sulfur vulcanization, activators of vulcanization, shungite. |
| title | Correlation of chemical structures of thiazole accelerators with rheokinetic properties of elastomeric compounds |
| title_full | Correlation of chemical structures of thiazole accelerators with rheokinetic properties of elastomeric compounds |
| title_fullStr | Correlation of chemical structures of thiazole accelerators with rheokinetic properties of elastomeric compounds |
| title_full_unstemmed | Correlation of chemical structures of thiazole accelerators with rheokinetic properties of elastomeric compounds |
| title_short | Correlation of chemical structures of thiazole accelerators with rheokinetic properties of elastomeric compounds |
| title_sort | correlation of chemical structures of thiazole accelerators with rheokinetic properties of elastomeric compounds |
| topic | vulcanization accelerators, chemical structures, rheokinetic properties, sulfur vulcanization, activators of vulcanization, shungite. |
| url | https://www.finechem-mirea.ru/jour/article/view/440 |
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