Crystal structure of β-d,l-allose
The title compound, C6H12O6, a C-3 position epimer of glucose, was crystallized from an equimolar mixture of d- and l-allose. It was confirmed that d-allose (l-allose) formed β-pyranose with a 4C1 (1C4) conformation in the crystal. In the crystal, molecules are linked by O—H...O hydrogen bond, formi...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2015-02-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989015000353 |
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| author | Tomohiko Ishii Tatsuya Senoo Taro Kozakai Kazuhiro Fukada Genta Sakane |
| author_facet | Tomohiko Ishii Tatsuya Senoo Taro Kozakai Kazuhiro Fukada Genta Sakane |
| author_sort | Tomohiko Ishii |
| collection | DOAJ |
| description | The title compound, C6H12O6, a C-3 position epimer of glucose, was crystallized from an equimolar mixture of d- and l-allose. It was confirmed that d-allose (l-allose) formed β-pyranose with a 4C1 (1C4) conformation in the crystal. In the crystal, molecules are linked by O—H...O hydrogen bond, forming a three-dimensional framework. The cell volume of the racemic β-d,l-allose is 739.36 (3) Å3, which is about 10 Å3 smaller than that of chiral β-d-allose [V = 751.0 (2) Å3]. |
| first_indexed | 2024-12-24T04:32:20Z |
| format | Article |
| id | doaj.art-ddc0b7eab6684f4eaa9cdfd515941ea8 |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-12-24T04:32:20Z |
| publishDate | 2015-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-ddc0b7eab6684f4eaa9cdfd515941ea82022-12-21T17:15:22ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902015-02-01712o139o13910.1107/S2056989015000353is5386Crystal structure of β-d,l-alloseTomohiko Ishii0Tatsuya Senoo1Taro Kozakai2Kazuhiro Fukada3Genta Sakane4Department of Advanced Materials Science, Faculty of Engineering, Kagawa University, 2217-20 Hayashi-cho, Takamatsu, Kagawa 761-0396, JapanDepartment of Advanced Materials Science, Faculty of Engineering, Kagawa University, 2217-20 Hayashi-cho, Takamatsu, Kagawa 761-0396, JapanDepartment of Applied Biological Science, Faculty of Agriculture, Kagawa University, 2393 Ikenobe, Kagawa 761-0795, JapanDepartment of Applied Biological Science, Faculty of Agriculture, Kagawa University, 2393 Ikenobe, Kagawa 761-0795, JapanDepartment of Chemistry, Faculty of Science, Okayama University of Science, 1-1 Ridaicho, Kita-ku, Okayama 700-0005, JapanThe title compound, C6H12O6, a C-3 position epimer of glucose, was crystallized from an equimolar mixture of d- and l-allose. It was confirmed that d-allose (l-allose) formed β-pyranose with a 4C1 (1C4) conformation in the crystal. In the crystal, molecules are linked by O—H...O hydrogen bond, forming a three-dimensional framework. The cell volume of the racemic β-d,l-allose is 739.36 (3) Å3, which is about 10 Å3 smaller than that of chiral β-d-allose [V = 751.0 (2) Å3].http://scripts.iucr.org/cgi-bin/paper?S2056989015000353crystal structureracemic compoundrare sugarO—H...O hydrogen bonding |
| spellingShingle | Tomohiko Ishii Tatsuya Senoo Taro Kozakai Kazuhiro Fukada Genta Sakane Crystal structure of β-d,l-allose Acta Crystallographica Section E: Crystallographic Communications crystal structure racemic compound rare sugar O—H...O hydrogen bonding |
| title | Crystal structure of β-d,l-allose |
| title_full | Crystal structure of β-d,l-allose |
| title_fullStr | Crystal structure of β-d,l-allose |
| title_full_unstemmed | Crystal structure of β-d,l-allose |
| title_short | Crystal structure of β-d,l-allose |
| title_sort | crystal structure of β d l allose |
| topic | crystal structure racemic compound rare sugar O—H...O hydrogen bonding |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989015000353 |
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