Synthesis and characterization of palladium(II) and platinum(II) mixed ligand complexes of the type [M(bpozs)2(dppf)]Cl2, bpozs=2-(benzylthio)-5-phenyl-1,3,4-oxadiazole
Treatment of [PdCl2(dppf)].CH2Cl2 or [PtCl2(dppf)] with two moles of 2-(benzylthio)-5-phenyl-1,3,4-oxadiazole (bpozs) in (ethanol: chloroform) solvents for (2 h) afford [M(bpozs)2(dppf)]Cl2 in good yield. The synthesized ligand and complexes were identified using FT-IR, 1H-NMR, 13C-NMR, 13P-NMR, CHN...
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| Format: | Article |
| Language: | English |
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Salahaddin University-Erbil
2021-03-01
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| Series: | Zanco Journal of Pure and Applied Sciences |
| Subjects: | |
| Online Access: | https://zancojournals.su.edu.krd/index.php/JPAS/article/view/3698 |
| _version_ | 1818891193453379584 |
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| author | Rezan Ali Saleh Hikmat A. Mohammad |
| author_facet | Rezan Ali Saleh Hikmat A. Mohammad |
| author_sort | Rezan Ali Saleh |
| collection | DOAJ |
| description | Treatment of [PdCl2(dppf)].CH2Cl2 or [PtCl2(dppf)] with two moles of 2-(benzylthio)-5-phenyl-1,3,4-oxadiazole (bpozs) in (ethanol: chloroform) solvents for (2 h) afford [M(bpozs)2(dppf)]Cl2 in good yield. The synthesized ligand and complexes were identified using FT-IR, 1H-NMR, 13C-NMR, 13P-NMR, CHNS analysis, Uv-Visible spectra and conductivity measurements. The physiochemical data indicated that the prepared complexes have square planar geometries and the metal ions coordinate with the ligands through two phosphorous atoms of (dppf) and nitrogen atom of (bpozs). |
| first_indexed | 2024-12-19T17:36:55Z |
| format | Article |
| id | doaj.art-ddc7e05a27aa4895966501e810730d80 |
| institution | Directory Open Access Journal |
| issn | 2218-0230 2412-3986 |
| language | English |
| last_indexed | 2024-12-19T17:36:55Z |
| publishDate | 2021-03-01 |
| publisher | Salahaddin University-Erbil |
| record_format | Article |
| series | Zanco Journal of Pure and Applied Sciences |
| spelling | doaj.art-ddc7e05a27aa4895966501e810730d802022-12-21T20:12:19ZengSalahaddin University-ErbilZanco Journal of Pure and Applied Sciences2218-02302412-39862021-03-0133779010.21271/ZJPAS.33.1.9Synthesis and characterization of palladium(II) and platinum(II) mixed ligand complexes of the type [M(bpozs)2(dppf)]Cl2, bpozs=2-(benzylthio)-5-phenyl-1,3,4-oxadiazoleRezan Ali Saleh0Hikmat A. Mohammad1Department of Chemistry, College of Education, Salahaddin University-Erbil, Kurdistan Region, IraqDepartment of Chemistry, College of Education, Salahaddin University-Erbil, Kurdistan Region, IraqTreatment of [PdCl2(dppf)].CH2Cl2 or [PtCl2(dppf)] with two moles of 2-(benzylthio)-5-phenyl-1,3,4-oxadiazole (bpozs) in (ethanol: chloroform) solvents for (2 h) afford [M(bpozs)2(dppf)]Cl2 in good yield. The synthesized ligand and complexes were identified using FT-IR, 1H-NMR, 13C-NMR, 13P-NMR, CHNS analysis, Uv-Visible spectra and conductivity measurements. The physiochemical data indicated that the prepared complexes have square planar geometries and the metal ions coordinate with the ligands through two phosphorous atoms of (dppf) and nitrogen atom of (bpozs).https://zancojournals.su.edu.krd/index.php/JPAS/article/view/3698pd(ii); pt(ii); bphozs; dppf; mixed ligand. |
| spellingShingle | Rezan Ali Saleh Hikmat A. Mohammad Synthesis and characterization of palladium(II) and platinum(II) mixed ligand complexes of the type [M(bpozs)2(dppf)]Cl2, bpozs=2-(benzylthio)-5-phenyl-1,3,4-oxadiazole Zanco Journal of Pure and Applied Sciences pd(ii); pt(ii); bphozs; dppf; mixed ligand. |
| title | Synthesis and characterization of palladium(II) and platinum(II) mixed ligand complexes of the type [M(bpozs)2(dppf)]Cl2, bpozs=2-(benzylthio)-5-phenyl-1,3,4-oxadiazole |
| title_full | Synthesis and characterization of palladium(II) and platinum(II) mixed ligand complexes of the type [M(bpozs)2(dppf)]Cl2, bpozs=2-(benzylthio)-5-phenyl-1,3,4-oxadiazole |
| title_fullStr | Synthesis and characterization of palladium(II) and platinum(II) mixed ligand complexes of the type [M(bpozs)2(dppf)]Cl2, bpozs=2-(benzylthio)-5-phenyl-1,3,4-oxadiazole |
| title_full_unstemmed | Synthesis and characterization of palladium(II) and platinum(II) mixed ligand complexes of the type [M(bpozs)2(dppf)]Cl2, bpozs=2-(benzylthio)-5-phenyl-1,3,4-oxadiazole |
| title_short | Synthesis and characterization of palladium(II) and platinum(II) mixed ligand complexes of the type [M(bpozs)2(dppf)]Cl2, bpozs=2-(benzylthio)-5-phenyl-1,3,4-oxadiazole |
| title_sort | synthesis and characterization of palladium ii and platinum ii mixed ligand complexes of the type m bpozs 2 dppf cl2 bpozs 2 benzylthio 5 phenyl 1 3 4 oxadiazole |
| topic | pd(ii); pt(ii); bphozs; dppf; mixed ligand. |
| url | https://zancojournals.su.edu.krd/index.php/JPAS/article/view/3698 |
| work_keys_str_mv | AT rezanalisaleh synthesisandcharacterizationofpalladiumiiandplatinumiimixedligandcomplexesofthetypembpozs2dppfcl2bpozs2benzylthio5phenyl134oxadiazole AT hikmatamohammad synthesisandcharacterizationofpalladiumiiandplatinumiimixedligandcomplexesofthetypembpozs2dppfcl2bpozs2benzylthio5phenyl134oxadiazole |