Tuning catalyst performance in the SILP-catalyzed gas-phase hydroformylation of but-1-ene by choice of the ionic liquid

Tuning catalyst performance in the SILP-catalyzed gas-phase hydroformylation of but-1-ene by choice of the ionic liquid

For the industrially relevant hydroformylation of but‑1-ene the concept of supported ionic liquid phase (SILP) has been applied previously. In this work, we have studied the influence of the type of ionic liquid (imidazolium and phosphonium based cations, various anions) on the solubility of the thr...

Full description

Bibliographic Details
Main Authors:	Markus Schörner, Andreas Schönweiz, Stefanie Vignesh, Liudmila Mokrushina, Matthias Thommes, Robert Franke, Marco Haumann
Format:	Article
Language:	English
Published:	Elsevier 2023-12-01
Series:	Journal of Ionic Liquids
Subjects:	Supported ionic liquid phase (SILP) Hydroformylation Solubility Rhodium Aldol condensation Kamlet-Taft-parameter
Online Access:	http://www.sciencedirect.com/science/article/pii/S2772422023000137

Similar Items

Efficient Synthesis of New Fluorinated Building Blocks by means of Hydroformylation
by: Lidia Fanfoni, et al.
Published: (2014-06-01)

Reductive Hydroformylation of Isosorbide Diallyl Ether
by: Jérémy Ternel, et al.
Published: (2021-12-01)

Insights in the Rhodium-Catalyzed Tandem Isomerization-Hydroformylation of 10-Undecenitrile: Evidence for a Fast Isomerization Regime
by: Lucas Le Goanvic, et al.
Published: (2018-04-01)

Current State of the Art of the Solid Rh-Based Catalyzed Hydroformylation of Short-Chain Olefins
by: Schirin Hanf, et al.
Published: (2020-05-01)

Ionic liquids, the mixture of ionic liquids and their co-solvent with N, N-dimethylformamide as solvents for cellulose using experimental and COSMO study
by: Ntebogeng Mqoni, et al.
Published: (2022-09-01)

Hydroformylation of Alkenes over Phosphorous-Free Rhodium Supported on N-Doped Silica
by: Yulia Kardasheva, et al.
Published: (2023-04-01)

Ligand design and mechanism in hydroformylation
by: Kent, A
Published: (1981)

Ligand Hydrogenation during Hydroformylation Catalysis Detected by In Situ High-Pressure Infra-Red Spectroscopic Analysis of a Rhodium/Phospholene-Phosphite Catalyst
by: José A. Fuentes, et al.
Published: (2024-02-01)

The Influence of Monomer Structure on the Properties of Ionogels Obtained by Thiol–Ene Photopolymerization
by: Aneta Lewandowska, et al.
Published: (2021-11-01)

Synthesis of Nixantphos Core-Functionalized Amphiphilic Nanoreactors and Application to Rhodium-Catalyzed Aqueous Biphasic 1-Octene Hydroformylation
by: Ahmad Joumaa, et al.
Published: (2020-05-01)

Bifunctional Silica-Supported Ionic Liquid Phase (SILP) Catalysts in Silane Production: Their Synthesis, Characterization and Catalytic Activity
by: Nataliia V. Abarbanel, et al.
Published: (2023-12-01)

Hidroformilação do oleato de metila catalisada por complexos de ródio
by: Ana Nery Furlan Mendes, et al.
Published: (2012-01-01)

Rhodium catalysts build into the structure of a silicate support in the hydroformylation of alkenes
by: Borrmann Thomas, et al.
Published: (2013-04-01)

Solvatochromism of isatin based Schiff bases: An LSER and LFER study
by: Brkić Dominik R., et al.
Published: (2016-01-01)

Probing Interactions in Combined Hydroxide Base Solvents for Improving Dissolution of Cellulose
by: Beatrice Swensson, et al.
Published: (2020-06-01)

Solvent, substituents and pH effects towards the spectral shifts of some highly colored indicators
by: Masoud Mamdouh S., et al.
Published: (2017-01-01)

The classification of solvents based on solvatochromic characteristics: the choice of optimal parameters for artificial neural networks
by: Pushkarova Yaroslava, et al.
Published: (2012-08-01)

Gel Polymer Electrolytes with Mixture of Triazolium Ionic Liquids and Propylene Carbonate
by: Aneta Lewandowska, et al.
Published: (2022-06-01)

Single-atom catalysts for hydroformylation of olefins
by: Shu Tao, et al.
Published: (2023-03-01)

Development of a correlation equation between the diesterification of maleic anhydride and the acidic ionic liquids nature
by: Yumei Liu, et al.
Published: (2023-03-01)

Effect of SILPs on the Vulcanization and Properties of Ethylene–Propylene–Diene Elastomer
by: Anna Sowińska, et al.
Published: (2020-05-01)

Study of the Ternary Mixture of Methanol/Formamide/Acetonitrile via Solvatochromic Probes
by: Nelson Nunes, et al.
Published: (2024-01-01)

Effect of acetylene linkage on solvatochromism of betaine consisting of 1-methylpyridinium and phenolate units
by: Takao Okazaki, et al.
Published: (2023-01-01)

Transition metal-catalyzed branch-selective hydroformylation of olefins in organic synthesis
by: Yingtang Ning, et al.
Published: (2021-08-01)

One-Pot Synthesis of Fatty Amines: Rh-Catalyzed Hydroaminomethylation of 1-Decene in an Aqueous Microemulsion System—Influence of Reaction Conditions on the Reaction Performance
by: Ariane Weber, et al.
Published: (2022-07-01)

Solvent effects on the absorption spectra of potentially pharmacologically active 5-alkyl-5-arylhydantoins: A structure-property relationship study
by: Hmuda Sleem F., et al.
Published: (2013-01-01)

Organic solvents in electromembrane extraction: recent insights
by: Huang Chuixiu, et al.
Published: (2016-12-01)

Monolithic membrane reactors based on supported ionic liquid phase (SILP) materials – hydroformylation and water-gas shift case studies
by: Markus Schörner, et al.
Published: (2021-12-01)

Unimolecular Solvolyses in Ionic Liquid: Alcohol Dual Solvent Systems
by: Elizabeth D. Kochly, et al.
Published: (2016-01-01)

Hydroformylation over polyoxometalates supported single-atom Rh catalysts
by: Feng Shixiang, et al.
Published: (2023-02-01)

Ionic Liquids as homogeneous photocatalyst for CO2 reduction in protic solvents
by: Yulan Peng, et al.
Published: (2022-11-01)

Olefin hydroformylation catalysis with RuCl2(DMSO)4.
by: Marisela Reyes*, et al.
Published: (2008-05-01)

Phosphinocyclodextrins as confining units for catalytic metal centres. Applications to carbon–carbon bond forming reactions
by: Matthieu Jouffroy, et al.
Published: (2014-10-01)

Aldol condensation of 2,5-dimethoxybenzaldehyde with acetone under basic condition
by: Mohd Shah, Siti Aminah, et al.
Published: (2010)

Synthesis, characterization and Hydroformylation Catalytic Activity of 1-hexene of Water-soluble RuCl2(DMSO)2(PySO3Na)2 Complex
by: Yuraima Fonseca, et al.
Published: (2012-05-01)

Immobilization of Rh(I)-N-Xantphos and Fe(II)-C-Scorpionate onto Magnetic Nanoparticles: Reusable Catalytic System for Sequential Hydroformylation/Acetalization
by: Fábio M. S. Rodrigues, et al.
Published: (2021-05-01)

Mechanism and Kinetic Study on Synthesis of Methacrolein Catalyzed by Amine/Acid
by: Tao Wang, et al.
Published: (2023-04-01)

Rh NPs Immobilized on Phosphonium- based Supported Ionic Liquid Phases (Rh@SILPs) as Hydrogenation Catalysts
by: Johannes Zenner, et al.
Published: (2021-09-01)

Synthesis of polyfunctionalised cyclopentanes
by: Hui, A, et al.
Published: (1995)

Modern aldol reactions /
by: Mahrwald, Rainer
Published: (2004)