Poly[[tetrakis(μ2-pyrazine N,N′-dioxide-κ2O:O′)neodymium(III)] tris(perchlorate)]
The title three-dimensional coordination network, {[Nd(C4H4N2O2)4](ClO4)3}n, is isostructural to that of other lanthanides. The Nd+3 cation lies on a fourfold roto-inversion axis. It is coordinated in a distorted square-antiprismatic fashion by eight O atoms from bridging pyrazine N,N′...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-09-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810031818 |
| _version_ | 1818283238532055040 |
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| author | Benjamin G. Quinn-Elmore James D. Buchner Keith B. Beach Jacqueline M. Knaust |
| author_facet | Benjamin G. Quinn-Elmore James D. Buchner Keith B. Beach Jacqueline M. Knaust |
| author_sort | Benjamin G. Quinn-Elmore |
| collection | DOAJ |
| description | The title three-dimensional coordination network, {[Nd(C4H4N2O2)4](ClO4)3}n, is isostructural to that of other lanthanides. The Nd+3 cation lies on a fourfold roto-inversion axis. It is coordinated in a distorted square-antiprismatic fashion by eight O atoms from bridging pyrazine N,N′-dioxide ligands. There are two unique pyrazine N,N′-dioxide ligands. One ring is located around an inversion center, and there is a twofold rotation axis at the center of the other ring. There are also two unique perchlorate anions. One is centered on a twofold rotation axis and the other on a fourfold roto-inversion axis. The perchlorate anions are located in channels that run perpendicular to (001) and (110) and interact with the coordination network through C—H...O hydrogen bonds. |
| first_indexed | 2024-12-13T00:33:44Z |
| format | Article |
| id | doaj.art-de0950e558224ba582b0599880c822c0 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T00:33:44Z |
| publishDate | 2010-09-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-de0950e558224ba582b0599880c822c02022-12-22T00:05:15ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-09-01669m1104m110510.1107/S1600536810031818Poly[[tetrakis(μ2-pyrazine N,N′-dioxide-κ2O:O′)neodymium(III)] tris(perchlorate)]Benjamin G. Quinn-ElmoreJames D. BuchnerKeith B. BeachJacqueline M. KnaustThe title three-dimensional coordination network, {[Nd(C4H4N2O2)4](ClO4)3}n, is isostructural to that of other lanthanides. The Nd+3 cation lies on a fourfold roto-inversion axis. It is coordinated in a distorted square-antiprismatic fashion by eight O atoms from bridging pyrazine N,N′-dioxide ligands. There are two unique pyrazine N,N′-dioxide ligands. One ring is located around an inversion center, and there is a twofold rotation axis at the center of the other ring. There are also two unique perchlorate anions. One is centered on a twofold rotation axis and the other on a fourfold roto-inversion axis. The perchlorate anions are located in channels that run perpendicular to (001) and (110) and interact with the coordination network through C—H...O hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536810031818 |
| spellingShingle | Benjamin G. Quinn-Elmore James D. Buchner Keith B. Beach Jacqueline M. Knaust Poly[[tetrakis(μ2-pyrazine N,N′-dioxide-κ2O:O′)neodymium(III)] tris(perchlorate)] Acta Crystallographica Section E |
| title | Poly[[tetrakis(μ2-pyrazine N,N′-dioxide-κ2O:O′)neodymium(III)] tris(perchlorate)] |
| title_full | Poly[[tetrakis(μ2-pyrazine N,N′-dioxide-κ2O:O′)neodymium(III)] tris(perchlorate)] |
| title_fullStr | Poly[[tetrakis(μ2-pyrazine N,N′-dioxide-κ2O:O′)neodymium(III)] tris(perchlorate)] |
| title_full_unstemmed | Poly[[tetrakis(μ2-pyrazine N,N′-dioxide-κ2O:O′)neodymium(III)] tris(perchlorate)] |
| title_short | Poly[[tetrakis(μ2-pyrazine N,N′-dioxide-κ2O:O′)neodymium(III)] tris(perchlorate)] |
| title_sort | poly tetrakis amp 956 2 pyrazine n n amp 8242 dioxide amp 954 2o o amp 8242 neodymium iii tris perchlorate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810031818 |
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