Parameters controlling the advanced oxidation degradation kinetics of nitroglycerin and pentaerythritol tetranitrate

Several advanced oxidation processes have been performed for the decomposition of ester nitrates (ENs), such as nitroglycerine (NG) and pentaerythritol tetranitrate (PETN). The reaction kinetics for removing NG and PETN by some of the advanced oxidation processes (e.g. UV-H2O2, Fenton, UV-Fenton) fo...

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Main Authors: Khue Do Ngoc, Lam Tran Dai, Hung Dao Duy, Bach Vu Quang, Anh Nguyen Van, Nam Nguyen Hoai, Thai Nguyen Viet, Minh Do Binh
Format: Article
Language:English
Published: De Gruyter 2018-02-01
Series:Green Processing and Synthesis
Subjects:
Online Access:https://doi.org/10.1515/gps-2016-0210
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author Khue Do Ngoc
Lam Tran Dai
Hung Dao Duy
Bach Vu Quang
Anh Nguyen Van
Nam Nguyen Hoai
Thai Nguyen Viet
Minh Do Binh
author_facet Khue Do Ngoc
Lam Tran Dai
Hung Dao Duy
Bach Vu Quang
Anh Nguyen Van
Nam Nguyen Hoai
Thai Nguyen Viet
Minh Do Binh
author_sort Khue Do Ngoc
collection DOAJ
description Several advanced oxidation processes have been performed for the decomposition of ester nitrates (ENs), such as nitroglycerine (NG) and pentaerythritol tetranitrate (PETN). The reaction kinetics for removing NG and PETN by some of the advanced oxidation processes (e.g. UV-H2O2, Fenton, UV-Fenton) followed the pseudo-first-order model. The reaction rates in different systems followed the sequence ENs/UV<ENs/H2O2<ENs/UV-H2O2<ENs/Fenton<ENs/UV-Fenton. The effect of various parameters, such as pH, concentration of hydrogen peroxide, and temperature, on the degradation of NG and PETN were studied.
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spelling doaj.art-de0e8c387c4748b4a07a7698fb2495192022-12-21T21:30:54ZengDe GruyterGreen Processing and Synthesis2191-95422191-95502018-02-0171616710.1515/gps-2016-0210Parameters controlling the advanced oxidation degradation kinetics of nitroglycerin and pentaerythritol tetranitrateKhue Do Ngoc0Lam Tran Dai1Hung Dao Duy2Bach Vu Quang3Anh Nguyen Van4Nam Nguyen Hoai5Thai Nguyen Viet6Minh Do Binh7Institute of Chemistry and Materials, 17 Hoang Sam, Cau Giay, Hanoi, VietnamGraduate University of Science and Technology, Vietnam Academy of Science and Technology, Hanoi, VietnamInstitute of Chemistry and Materials, 17 Hoang Sam, Cau Giay, Hanoi, VietnamInstitute of Chemistry and Materials, 17 Hoang Sam, Cau Giay, Hanoi, VietnamHanoi University of Science and Technology, Hanoi, VietnamThuyloi University, Hanoi, VietnamInstitute of Chemistry and Materials, 17 Hoang Sam, Cau Giay, Hanoi, VietnamInstitute of Chemistry and Materials, 17 Hoang Sam, Cau Giay, Hanoi, VietnamSeveral advanced oxidation processes have been performed for the decomposition of ester nitrates (ENs), such as nitroglycerine (NG) and pentaerythritol tetranitrate (PETN). The reaction kinetics for removing NG and PETN by some of the advanced oxidation processes (e.g. UV-H2O2, Fenton, UV-Fenton) followed the pseudo-first-order model. The reaction rates in different systems followed the sequence ENs/UV<ENs/H2O2<ENs/UV-H2O2<ENs/Fenton<ENs/UV-Fenton. The effect of various parameters, such as pH, concentration of hydrogen peroxide, and temperature, on the degradation of NG and PETN were studied.https://doi.org/10.1515/gps-2016-0210advanced oxidation process (aop)fentonnitroglycerin (ng)pentaerythritol tetranitrate (petn)uv-fentonuv-h2o2
spellingShingle Khue Do Ngoc
Lam Tran Dai
Hung Dao Duy
Bach Vu Quang
Anh Nguyen Van
Nam Nguyen Hoai
Thai Nguyen Viet
Minh Do Binh
Parameters controlling the advanced oxidation degradation kinetics of nitroglycerin and pentaerythritol tetranitrate
Green Processing and Synthesis
advanced oxidation process (aop)
fenton
nitroglycerin (ng)
pentaerythritol tetranitrate (petn)
uv-fenton
uv-h2o2
title Parameters controlling the advanced oxidation degradation kinetics of nitroglycerin and pentaerythritol tetranitrate
title_full Parameters controlling the advanced oxidation degradation kinetics of nitroglycerin and pentaerythritol tetranitrate
title_fullStr Parameters controlling the advanced oxidation degradation kinetics of nitroglycerin and pentaerythritol tetranitrate
title_full_unstemmed Parameters controlling the advanced oxidation degradation kinetics of nitroglycerin and pentaerythritol tetranitrate
title_short Parameters controlling the advanced oxidation degradation kinetics of nitroglycerin and pentaerythritol tetranitrate
title_sort parameters controlling the advanced oxidation degradation kinetics of nitroglycerin and pentaerythritol tetranitrate
topic advanced oxidation process (aop)
fenton
nitroglycerin (ng)
pentaerythritol tetranitrate (petn)
uv-fenton
uv-h2o2
url https://doi.org/10.1515/gps-2016-0210
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