Dicarbonyl(η5-cyclopentadienyl)bis(trimethylphosphine)molybdenum(II) trifluoromethanesulfonate
In the title compound, [Mo(C5H5)(CO)2(C3H9P)2]CF3SO3, the cationic complex displays a classical four-legged piano-stool square-pyramidal geometry with a trans configuration of the basal ligands around the Mo atom. The cyclopentadienyl (Cp) ligand occupies the apical position of the piano-stool confi...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2008-11-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808032662 |
| Summary: | In the title compound, [Mo(C5H5)(CO)2(C3H9P)2]CF3SO3, the cationic complex displays a classical four-legged piano-stool square-pyramidal geometry with a trans configuration of the basal ligands around the Mo atom. The cyclopentadienyl (Cp) ligand occupies the apical position of the piano-stool configuration. The average Mo—P bond length of the two trans PMe3 ligands is 2.474 (5) Å and the Mo—Cp centroid distance is 2.003 (2) Å. |
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| ISSN: | 1600-5368 |