Dicarbonyl(η5-cyclopentadienyl)bis(trimethylphosphine)molybdenum(II) trifluoromethanesulfonate
In the title compound, [Mo(C5H5)(CO)2(C3H9P)2]CF3SO3, the cationic complex displays a classical four-legged piano-stool square-pyramidal geometry with a trans configuration of the basal ligands around the Mo atom. The cyclopentadienyl (Cp) ligand occupies the apical position of the piano-stool confi...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2008-11-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808032662 |
| _version_ | 1818320943837085696 |
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| author | Samuel Jali Holger B. Friedrich Muhammad D. Bala |
| author_facet | Samuel Jali Holger B. Friedrich Muhammad D. Bala |
| author_sort | Samuel Jali |
| collection | DOAJ |
| description | In the title compound, [Mo(C5H5)(CO)2(C3H9P)2]CF3SO3, the cationic complex displays a classical four-legged piano-stool square-pyramidal geometry with a trans configuration of the basal ligands around the Mo atom. The cyclopentadienyl (Cp) ligand occupies the apical position of the piano-stool configuration. The average Mo—P bond length of the two trans PMe3 ligands is 2.474 (5) Å and the Mo—Cp centroid distance is 2.003 (2) Å. |
| first_indexed | 2024-12-13T10:33:03Z |
| format | Article |
| id | doaj.art-de5795c537b04f5f8b774560e4c974d6 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T10:33:03Z |
| publishDate | 2008-11-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-de5795c537b04f5f8b774560e4c974d62022-12-21T23:50:49ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-11-016411m1401m140110.1107/S1600536808032662Dicarbonyl(η5-cyclopentadienyl)bis(trimethylphosphine)molybdenum(II) trifluoromethanesulfonateSamuel JaliHolger B. FriedrichMuhammad D. BalaIn the title compound, [Mo(C5H5)(CO)2(C3H9P)2]CF3SO3, the cationic complex displays a classical four-legged piano-stool square-pyramidal geometry with a trans configuration of the basal ligands around the Mo atom. The cyclopentadienyl (Cp) ligand occupies the apical position of the piano-stool configuration. The average Mo—P bond length of the two trans PMe3 ligands is 2.474 (5) Å and the Mo—Cp centroid distance is 2.003 (2) Å.http://scripts.iucr.org/cgi-bin/paper?S1600536808032662 |
| spellingShingle | Samuel Jali Holger B. Friedrich Muhammad D. Bala Dicarbonyl(η5-cyclopentadienyl)bis(trimethylphosphine)molybdenum(II) trifluoromethanesulfonate Acta Crystallographica Section E |
| title | Dicarbonyl(η5-cyclopentadienyl)bis(trimethylphosphine)molybdenum(II) trifluoromethanesulfonate |
| title_full | Dicarbonyl(η5-cyclopentadienyl)bis(trimethylphosphine)molybdenum(II) trifluoromethanesulfonate |
| title_fullStr | Dicarbonyl(η5-cyclopentadienyl)bis(trimethylphosphine)molybdenum(II) trifluoromethanesulfonate |
| title_full_unstemmed | Dicarbonyl(η5-cyclopentadienyl)bis(trimethylphosphine)molybdenum(II) trifluoromethanesulfonate |
| title_short | Dicarbonyl(η5-cyclopentadienyl)bis(trimethylphosphine)molybdenum(II) trifluoromethanesulfonate |
| title_sort | dicarbonyl 951 5 cyclopentadienyl bis trimethylphosphine molybdenum ii trifluoromethanesulfonate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808032662 |
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