Et4N[NO3(SnClPh3)2(SnPh3NO3)]: a trinuclear organostannate complex and related derivatives
Four new di- and triorganonitrato stannate complexes and related derivatives have been synthesized and characterized by infrared and Mössbauer spectroscopy. The structure of Et4N[NO3(SnClPh3)2(SnPh3NO3)] (1) has been determined by single-crystal X-ray diffraction analysis. In the trinuclear organost...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
De Gruyter
2013-07-01
|
| Series: | Main Group Metal Chemistry |
| Subjects: | |
| Online Access: | https://doi.org/10.1515/mgmc-2013-0009 |
| _version_ | 1818666780003926016 |
|---|---|
| author | Diop Tidiane Diop Libasse Michaud François Ardisson José Domingos |
| author_facet | Diop Tidiane Diop Libasse Michaud François Ardisson José Domingos |
| author_sort | Diop Tidiane |
| collection | DOAJ |
| description | Four new di- and triorganonitrato stannate complexes and related derivatives have been synthesized and characterized by infrared and Mössbauer spectroscopy. The structure of Et4N[NO3(SnClPh3)2(SnPh3NO3)] (1) has been determined by single-crystal X-ray diffraction analysis. In the trinuclear organostannate complex, each SnIV atom is five-coordinated and adopts a trigonal-bipyramidal trans-OXSnC3 (X=O or Cl) geometry. The overall coordination environment of the SnIV atoms is trans-octahedral for 2 and 3 or cis-trigonal-bipyramidal for 4. In the related derivatives, the NO3- anions behave as monodentate ligands. |
| first_indexed | 2024-12-17T06:09:58Z |
| format | Article |
| id | doaj.art-de6dba43c0ec40118a3fa3fb53334079 |
| institution | Directory Open Access Journal |
| issn | 0792-1241 2191-0219 |
| language | English |
| last_indexed | 2024-12-17T06:09:58Z |
| publishDate | 2013-07-01 |
| publisher | De Gruyter |
| record_format | Article |
| series | Main Group Metal Chemistry |
| spelling | doaj.art-de6dba43c0ec40118a3fa3fb533340792022-12-21T22:00:40ZengDe GruyterMain Group Metal Chemistry0792-12412191-02192013-07-01363-4838810.1515/mgmc-2013-0009Et4N[NO3(SnClPh3)2(SnPh3NO3)]: a trinuclear organostannate complex and related derivativesDiop Tidiane0Diop Libasse1Michaud François2Ardisson José Domingos3Laboratoire de Chimie Minérale et Analytique, Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, UCAD-sénégal, B.P 5005, Dakar, SenegalLaboratoire de Chimie Minérale et Analytique, Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, UCAD-sénégal, B.P 5005, Dakar, SenegalService Commun d’Analyse par Diffraction Rayons X, Université de Bretagne Occidentale, 6 avenue Victor Le Gorgeu, CS93837, 29238 Brest Cedex 3, FranceCentro de Desenvolvimento da Tecnologia Nuclear (CDTN), Servico de Nanotecnologia (SENAN), Laboratorio de Fisica Aplicada, Av. Antonio Carlos 6.627, Campus da UFMG, Pampulha, 31270-901 Belo Horizonte, MG, BrazilFour new di- and triorganonitrato stannate complexes and related derivatives have been synthesized and characterized by infrared and Mössbauer spectroscopy. The structure of Et4N[NO3(SnClPh3)2(SnPh3NO3)] (1) has been determined by single-crystal X-ray diffraction analysis. In the trinuclear organostannate complex, each SnIV atom is five-coordinated and adopts a trigonal-bipyramidal trans-OXSnC3 (X=O or Cl) geometry. The overall coordination environment of the SnIV atoms is trans-octahedral for 2 and 3 or cis-trigonal-bipyramidal for 4. In the related derivatives, the NO3- anions behave as monodentate ligands.https://doi.org/10.1515/mgmc-2013-0009di- and triorganonitrato stannatemössbaueroctahedraltrigonal-bipyramidatrinuclear |
| spellingShingle | Diop Tidiane Diop Libasse Michaud François Ardisson José Domingos Et4N[NO3(SnClPh3)2(SnPh3NO3)]: a trinuclear organostannate complex and related derivatives Main Group Metal Chemistry di- and triorganonitrato stannate mössbauer octahedral trigonal-bipyramida trinuclear |
| title | Et4N[NO3(SnClPh3)2(SnPh3NO3)]: a trinuclear organostannate complex and related derivatives |
| title_full | Et4N[NO3(SnClPh3)2(SnPh3NO3)]: a trinuclear organostannate complex and related derivatives |
| title_fullStr | Et4N[NO3(SnClPh3)2(SnPh3NO3)]: a trinuclear organostannate complex and related derivatives |
| title_full_unstemmed | Et4N[NO3(SnClPh3)2(SnPh3NO3)]: a trinuclear organostannate complex and related derivatives |
| title_short | Et4N[NO3(SnClPh3)2(SnPh3NO3)]: a trinuclear organostannate complex and related derivatives |
| title_sort | et4n no3 snclph3 2 snph3no3 a trinuclear organostannate complex and related derivatives |
| topic | di- and triorganonitrato stannate mössbauer octahedral trigonal-bipyramida trinuclear |
| url | https://doi.org/10.1515/mgmc-2013-0009 |
| work_keys_str_mv | AT dioptidiane et4nno3snclph32snph3no3atrinuclearorganostannatecomplexandrelatedderivatives AT dioplibasse et4nno3snclph32snph3no3atrinuclearorganostannatecomplexandrelatedderivatives AT michaudfrancois et4nno3snclph32snph3no3atrinuclearorganostannatecomplexandrelatedderivatives AT ardissonjosedomingos et4nno3snclph32snph3no3atrinuclearorganostannatecomplexandrelatedderivatives |