Influence of basement rocks on fluid evolution during multiphase deformation: the example of the Estamariu thrust in the Pyrenean Axial Zone

<p>Calcite veins precipitated in the Estamariu thrust during two tectonic events are studied in order to (i) decipher the temporal and spatial relationships between deformation and fluid migration in a long-lived thrust and (ii) determine the influence of basement rocks on the fluid chemistry...

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Bibliographic Details
Main Authors: D. Muñoz-López, G. Alías, D. Cruset, I. Cantarero, C. M. John, A. Travé
Format: Article
Language:English
Published: Copernicus Publications 2020-11-01
Series:Solid Earth
Online Access:https://se.copernicus.org/articles/11/2257/2020/se-11-2257-2020.pdf
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Summary:<p>Calcite veins precipitated in the Estamariu thrust during two tectonic events are studied in order to (i) decipher the temporal and spatial relationships between deformation and fluid migration in a long-lived thrust and (ii) determine the influence of basement rocks on the fluid chemistry during deformation. Structural and petrological observations constrain the relative timing of fluid migration and vein formation, whilst geochemical analyses (<span class="inline-formula"><i>δ</i><sup>13</sup>C</span>, <span class="inline-formula"><i>δ</i><sup>18</sup>O</span>, <span class="inline-formula"><sup>87</sup>Sr∕<sup>86</sup>Sr</span>, clumped isotope thermometry, and elemental composition) applied to the related calcite cements and host rocks indicate the fluid origin, pathways, and extent of fluid–rock interaction. The first tectonic event, recorded by calcite cements Cc1a and Cc2, is attributed to the Alpine reactivation of the Estamariu thrust. Analytical data indicate that these cements precipitated from heated meteoric fluids (temperatures in the range of 50 to 100&thinsp;<span class="inline-formula"><sup>∘</sup></span>C) that had interacted with basement rocks (<span class="inline-formula"><sup>87</sup>Sr∕<sup>86</sup>Sr</span> <span class="inline-formula"><i>&gt;</i></span>&thinsp;0.71) before upflowing through the thrust zone. The second tectonic event, attributed to the Neogene extension, is characterized by the reactivation of the Estamariu thrust and the formation of normal faults and shear fractures sealed by calcite cements Cc3, Cc4, and Cc5. Analytical data indicate that cements Cc3 and Cc4 precipitated from hydrothermal fluids (temperatures between 130 and 210&thinsp;<span class="inline-formula"><sup>∘</sup></span>C and between 100 and 170&thinsp;<span class="inline-formula"><sup>∘</sup></span>C, respectively) that had interacted with basement rocks (<span class="inline-formula"><sup>87</sup>Sr∕<sup>86</sup>Sr</span> <span class="inline-formula"><i>&gt;</i></span>&thinsp;0.71) and been expelled through fault zones during deformation. In contrast, cement Cc5 probably precipitated from meteoric waters that likely percolated from the surface through small shear fractures.</p> <p>The comparison between our results and already published data in other structures from the southern Pyrenees suggests that regardless of the origin of the fluids and the tectonic context, basement rocks have a significant influence on the fluid chemistry, particularly on the <span class="inline-formula"><sup>87</sup>Sr∕<sup>86</sup>Sr</span> ratio. Accordingly, the cements precipitated from fluids that have interacted with basement rocks have significantly higher <span class="inline-formula"><sup>87</sup>Sr∕<sup>86</sup>Sr</span> ratios (<span class="inline-formula"><i>&gt;</i></span>&thinsp;0.710) with respect to those precipitated from fluids that have interacted with the sedimentary cover (<span class="inline-formula"><i>&lt;</i></span>&thinsp;0.710), which involves younger and less radiogenic rocks.</p>
ISSN:1869-9510
1869-9529