Influence of basement rocks on fluid evolution during multiphase deformation: the example of the Estamariu thrust in the Pyrenean Axial Zone

<p>Calcite veins precipitated in the Estamariu thrust during two tectonic events are studied in order to (i) decipher the temporal and spatial relationships between deformation and fluid migration in a long-lived thrust and (ii) determine the influence of basement rocks on the fluid chemistry...

Full description

Bibliographic Details
Main Authors: D. Muñoz-López, G. Alías, D. Cruset, I. Cantarero, C. M. John, A. Travé
Format: Article
Language:English
Published: Copernicus Publications 2020-11-01
Series:Solid Earth
Online Access:https://se.copernicus.org/articles/11/2257/2020/se-11-2257-2020.pdf
_version_ 1818566121054273536
author D. Muñoz-López
G. Alías
D. Cruset
I. Cantarero
C. M. John
A. Travé
author_facet D. Muñoz-López
G. Alías
D. Cruset
I. Cantarero
C. M. John
A. Travé
author_sort D. Muñoz-López
collection DOAJ
description <p>Calcite veins precipitated in the Estamariu thrust during two tectonic events are studied in order to (i) decipher the temporal and spatial relationships between deformation and fluid migration in a long-lived thrust and (ii) determine the influence of basement rocks on the fluid chemistry during deformation. Structural and petrological observations constrain the relative timing of fluid migration and vein formation, whilst geochemical analyses (<span class="inline-formula"><i>δ</i><sup>13</sup>C</span>, <span class="inline-formula"><i>δ</i><sup>18</sup>O</span>, <span class="inline-formula"><sup>87</sup>Sr∕<sup>86</sup>Sr</span>, clumped isotope thermometry, and elemental composition) applied to the related calcite cements and host rocks indicate the fluid origin, pathways, and extent of fluid–rock interaction. The first tectonic event, recorded by calcite cements Cc1a and Cc2, is attributed to the Alpine reactivation of the Estamariu thrust. Analytical data indicate that these cements precipitated from heated meteoric fluids (temperatures in the range of 50 to 100&thinsp;<span class="inline-formula"><sup>∘</sup></span>C) that had interacted with basement rocks (<span class="inline-formula"><sup>87</sup>Sr∕<sup>86</sup>Sr</span> <span class="inline-formula"><i>&gt;</i></span>&thinsp;0.71) before upflowing through the thrust zone. The second tectonic event, attributed to the Neogene extension, is characterized by the reactivation of the Estamariu thrust and the formation of normal faults and shear fractures sealed by calcite cements Cc3, Cc4, and Cc5. Analytical data indicate that cements Cc3 and Cc4 precipitated from hydrothermal fluids (temperatures between 130 and 210&thinsp;<span class="inline-formula"><sup>∘</sup></span>C and between 100 and 170&thinsp;<span class="inline-formula"><sup>∘</sup></span>C, respectively) that had interacted with basement rocks (<span class="inline-formula"><sup>87</sup>Sr∕<sup>86</sup>Sr</span> <span class="inline-formula"><i>&gt;</i></span>&thinsp;0.71) and been expelled through fault zones during deformation. In contrast, cement Cc5 probably precipitated from meteoric waters that likely percolated from the surface through small shear fractures.</p> <p>The comparison between our results and already published data in other structures from the southern Pyrenees suggests that regardless of the origin of the fluids and the tectonic context, basement rocks have a significant influence on the fluid chemistry, particularly on the <span class="inline-formula"><sup>87</sup>Sr∕<sup>86</sup>Sr</span> ratio. Accordingly, the cements precipitated from fluids that have interacted with basement rocks have significantly higher <span class="inline-formula"><sup>87</sup>Sr∕<sup>86</sup>Sr</span> ratios (<span class="inline-formula"><i>&gt;</i></span>&thinsp;0.710) with respect to those precipitated from fluids that have interacted with the sedimentary cover (<span class="inline-formula"><i>&lt;</i></span>&thinsp;0.710), which involves younger and less radiogenic rocks.</p>
first_indexed 2024-12-14T01:49:41Z
format Article
id doaj.art-de913ec2d3674d319eb4f2a15880829c
institution Directory Open Access Journal
issn 1869-9510
1869-9529
language English
last_indexed 2024-12-14T01:49:41Z
publishDate 2020-11-01
publisher Copernicus Publications
record_format Article
series Solid Earth
spelling doaj.art-de913ec2d3674d319eb4f2a15880829c2022-12-21T23:21:26ZengCopernicus PublicationsSolid Earth1869-95101869-95292020-11-01112257228110.5194/se-11-2257-2020Influence of basement rocks on fluid evolution during multiphase deformation: the example of the Estamariu thrust in the Pyrenean Axial ZoneD. Muñoz-López0G. Alías1D. Cruset2I. Cantarero3C. M. John4A. Travé5Department de Mineralogia, Petrologia i Geologia Aplicada, Facultat de Ciències de la Terra, Universitat de Barcelona (UB), C/ Martí i Franquès s/n, 08028 Barcelona, SpainDepartment de Mineralogia, Petrologia i Geologia Aplicada, Facultat de Ciències de la Terra, Universitat de Barcelona (UB), C/ Martí i Franquès s/n, 08028 Barcelona, SpainGroup of Dynamics of the Lithosphere (GDL), Geosciences Barcelona, GEO3BCN-CSIC, Lluís Solé i Sabarís s/n, 08028 Barcelona, SpainDepartment de Mineralogia, Petrologia i Geologia Aplicada, Facultat de Ciències de la Terra, Universitat de Barcelona (UB), C/ Martí i Franquès s/n, 08028 Barcelona, SpainDepartment of Earth Science and Engineering, Imperial College London, London SW7 2BP, UKDepartment de Mineralogia, Petrologia i Geologia Aplicada, Facultat de Ciències de la Terra, Universitat de Barcelona (UB), C/ Martí i Franquès s/n, 08028 Barcelona, Spain<p>Calcite veins precipitated in the Estamariu thrust during two tectonic events are studied in order to (i) decipher the temporal and spatial relationships between deformation and fluid migration in a long-lived thrust and (ii) determine the influence of basement rocks on the fluid chemistry during deformation. Structural and petrological observations constrain the relative timing of fluid migration and vein formation, whilst geochemical analyses (<span class="inline-formula"><i>δ</i><sup>13</sup>C</span>, <span class="inline-formula"><i>δ</i><sup>18</sup>O</span>, <span class="inline-formula"><sup>87</sup>Sr∕<sup>86</sup>Sr</span>, clumped isotope thermometry, and elemental composition) applied to the related calcite cements and host rocks indicate the fluid origin, pathways, and extent of fluid–rock interaction. The first tectonic event, recorded by calcite cements Cc1a and Cc2, is attributed to the Alpine reactivation of the Estamariu thrust. Analytical data indicate that these cements precipitated from heated meteoric fluids (temperatures in the range of 50 to 100&thinsp;<span class="inline-formula"><sup>∘</sup></span>C) that had interacted with basement rocks (<span class="inline-formula"><sup>87</sup>Sr∕<sup>86</sup>Sr</span> <span class="inline-formula"><i>&gt;</i></span>&thinsp;0.71) before upflowing through the thrust zone. The second tectonic event, attributed to the Neogene extension, is characterized by the reactivation of the Estamariu thrust and the formation of normal faults and shear fractures sealed by calcite cements Cc3, Cc4, and Cc5. Analytical data indicate that cements Cc3 and Cc4 precipitated from hydrothermal fluids (temperatures between 130 and 210&thinsp;<span class="inline-formula"><sup>∘</sup></span>C and between 100 and 170&thinsp;<span class="inline-formula"><sup>∘</sup></span>C, respectively) that had interacted with basement rocks (<span class="inline-formula"><sup>87</sup>Sr∕<sup>86</sup>Sr</span> <span class="inline-formula"><i>&gt;</i></span>&thinsp;0.71) and been expelled through fault zones during deformation. In contrast, cement Cc5 probably precipitated from meteoric waters that likely percolated from the surface through small shear fractures.</p> <p>The comparison between our results and already published data in other structures from the southern Pyrenees suggests that regardless of the origin of the fluids and the tectonic context, basement rocks have a significant influence on the fluid chemistry, particularly on the <span class="inline-formula"><sup>87</sup>Sr∕<sup>86</sup>Sr</span> ratio. Accordingly, the cements precipitated from fluids that have interacted with basement rocks have significantly higher <span class="inline-formula"><sup>87</sup>Sr∕<sup>86</sup>Sr</span> ratios (<span class="inline-formula"><i>&gt;</i></span>&thinsp;0.710) with respect to those precipitated from fluids that have interacted with the sedimentary cover (<span class="inline-formula"><i>&lt;</i></span>&thinsp;0.710), which involves younger and less radiogenic rocks.</p>https://se.copernicus.org/articles/11/2257/2020/se-11-2257-2020.pdf
spellingShingle D. Muñoz-López
G. Alías
D. Cruset
I. Cantarero
C. M. John
A. Travé
Influence of basement rocks on fluid evolution during multiphase deformation: the example of the Estamariu thrust in the Pyrenean Axial Zone
Solid Earth
title Influence of basement rocks on fluid evolution during multiphase deformation: the example of the Estamariu thrust in the Pyrenean Axial Zone
title_full Influence of basement rocks on fluid evolution during multiphase deformation: the example of the Estamariu thrust in the Pyrenean Axial Zone
title_fullStr Influence of basement rocks on fluid evolution during multiphase deformation: the example of the Estamariu thrust in the Pyrenean Axial Zone
title_full_unstemmed Influence of basement rocks on fluid evolution during multiphase deformation: the example of the Estamariu thrust in the Pyrenean Axial Zone
title_short Influence of basement rocks on fluid evolution during multiphase deformation: the example of the Estamariu thrust in the Pyrenean Axial Zone
title_sort influence of basement rocks on fluid evolution during multiphase deformation the example of the estamariu thrust in the pyrenean axial zone
url https://se.copernicus.org/articles/11/2257/2020/se-11-2257-2020.pdf
work_keys_str_mv AT dmunozlopez influenceofbasementrocksonfluidevolutionduringmultiphasedeformationtheexampleoftheestamariuthrustinthepyreneanaxialzone
AT galias influenceofbasementrocksonfluidevolutionduringmultiphasedeformationtheexampleoftheestamariuthrustinthepyreneanaxialzone
AT dcruset influenceofbasementrocksonfluidevolutionduringmultiphasedeformationtheexampleoftheestamariuthrustinthepyreneanaxialzone
AT icantarero influenceofbasementrocksonfluidevolutionduringmultiphasedeformationtheexampleoftheestamariuthrustinthepyreneanaxialzone
AT cmjohn influenceofbasementrocksonfluidevolutionduringmultiphasedeformationtheexampleoftheestamariuthrustinthepyreneanaxialzone
AT atrave influenceofbasementrocksonfluidevolutionduringmultiphasedeformationtheexampleoftheestamariuthrustinthepyreneanaxialzone