{N1-[2-(Butylselanyl)benzyl]-N2,N2-dimethylethane-1,2-diamine}dichloridomercury(II)
In the title compound, [HgCl2(C16H28N2Se)], the primary geometry around the Se and Hg atoms is distorted trigonal–pyramidal and distorted square-pyramidal, respectively. The distortion of the molecular geometry in the complex is caused by the steric demands of the ligands attached to the Se atom. Th...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2018-08-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989018010423 |
| _version_ | 1798027085529219072 |
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| author | Pushpendra Singh Harkesh B. Singh Ray J. Butcher |
| author_facet | Pushpendra Singh Harkesh B. Singh Ray J. Butcher |
| author_sort | Pushpendra Singh |
| collection | DOAJ |
| description | In the title compound, [HgCl2(C16H28N2Se)], the primary geometry around the Se and Hg atoms is distorted trigonal–pyramidal and distorted square-pyramidal, respectively. The distortion of the molecular geometry in the complex is caused by the steric demands of the ligands attached to the Se atom. The Hg atom is coordinated through two chloride anions, an N atom and an Se atom, making up an unusual HgNSeCl2 coordination sphere with an additional long Hg...N interaction. Intermolecular C—H...Cl interactions are the only identified intermolecular hydrogen-bonding interactions that seem to be responsible for the self assembly. These relatively weak C—H...Cl hydrogen bonds possess the required linearity and donor–acceptor distances. They act as molecular associative forces that result in a supramolecular assembly along the b-axis direction in the solid state of the title compound. |
| first_indexed | 2024-04-11T18:45:43Z |
| format | Article |
| id | doaj.art-ded1d7d76d0e497a83ad939a2bcfcd54 |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-04-11T18:45:43Z |
| publishDate | 2018-08-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-ded1d7d76d0e497a83ad939a2bcfcd542022-12-22T04:08:49ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902018-08-017481151115410.1107/S2056989018010423lh5877{N1-[2-(Butylselanyl)benzyl]-N2,N2-dimethylethane-1,2-diamine}dichloridomercury(II)Pushpendra Singh0Harkesh B. Singh1Ray J. Butcher2Department of Chemistry, Dr. Shakuntala Misra National Rehabilitation University, Mohaan Road Lucknow, 226017, IndiaDepartment of Chemistry, Indian Institute of Technology Bombay, Powai 400 076, Mumbai, IndiaDepartment of Chemistry, Howard University, 525 College Street NW, Washington, DC 20059, USAIn the title compound, [HgCl2(C16H28N2Se)], the primary geometry around the Se and Hg atoms is distorted trigonal–pyramidal and distorted square-pyramidal, respectively. The distortion of the molecular geometry in the complex is caused by the steric demands of the ligands attached to the Se atom. The Hg atom is coordinated through two chloride anions, an N atom and an Se atom, making up an unusual HgNSeCl2 coordination sphere with an additional long Hg...N interaction. Intermolecular C—H...Cl interactions are the only identified intermolecular hydrogen-bonding interactions that seem to be responsible for the self assembly. These relatively weak C—H...Cl hydrogen bonds possess the required linearity and donor–acceptor distances. They act as molecular associative forces that result in a supramolecular assembly along the b-axis direction in the solid state of the title compound.http://scripts.iucr.org/cgi-bin/paper?S2056989018010423crystal structuremercury (II) complexesmercury–selenium bonding |
| spellingShingle | Pushpendra Singh Harkesh B. Singh Ray J. Butcher {N1-[2-(Butylselanyl)benzyl]-N2,N2-dimethylethane-1,2-diamine}dichloridomercury(II) Acta Crystallographica Section E: Crystallographic Communications crystal structure mercury (II) complexes mercury–selenium bonding |
| title | {N1-[2-(Butylselanyl)benzyl]-N2,N2-dimethylethane-1,2-diamine}dichloridomercury(II) |
| title_full | {N1-[2-(Butylselanyl)benzyl]-N2,N2-dimethylethane-1,2-diamine}dichloridomercury(II) |
| title_fullStr | {N1-[2-(Butylselanyl)benzyl]-N2,N2-dimethylethane-1,2-diamine}dichloridomercury(II) |
| title_full_unstemmed | {N1-[2-(Butylselanyl)benzyl]-N2,N2-dimethylethane-1,2-diamine}dichloridomercury(II) |
| title_short | {N1-[2-(Butylselanyl)benzyl]-N2,N2-dimethylethane-1,2-diamine}dichloridomercury(II) |
| title_sort | n1 2 butylselanyl benzyl n2 n2 dimethylethane 1 2 diamine dichloridomercury ii |
| topic | crystal structure mercury (II) complexes mercury–selenium bonding |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989018010423 |
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