t-3-Benzyl-r-2,c-6-diphenylpiperidin-4-one
The asymmetric unit of the title compound, C24H23NO, contains two crystallographically independent molecules (A and B). In both molecules, the piperidine rings adopt a chair conformation and the phenyl rings and the benzyl group substituents are attached equatorially. The dihedral angle between the...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2016-02-01
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| Series: | IUCrData |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314616001887 |
| _version_ | 1818253861190631424 |
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| author | R. Arulraj S. Sivakumar A. Thiruvalluvar A. Manimekalai |
| author_facet | R. Arulraj S. Sivakumar A. Thiruvalluvar A. Manimekalai |
| author_sort | R. Arulraj |
| collection | DOAJ |
| description | The asymmetric unit of the title compound, C24H23NO, contains two crystallographically independent molecules (A and B). In both molecules, the piperidine rings adopt a chair conformation and the phenyl rings and the benzyl group substituents are attached equatorially. The dihedral angle between the phenyl rings is 60.80 (10)° in molecule A and 68.43 (9)° in molecule B. The phenyl ring of the benzyl group makes dihedral angles of 76.95 (9) and 42.25 (10)° with the phenyl rings in molecule A, and dihedral angles of 81.38 (11) and 30.19 (11)° in molecule B. In the crystal, the two molecules are linked by N—H...O hydrogen bonds, forming –A–B–A–B– chains along [100]. In addition, five C—H...π interactions are also present, linking the chains to form a three-dimensional structure. |
| first_indexed | 2024-12-12T16:46:48Z |
| format | Article |
| id | doaj.art-ded64cf212244966b3b805193ec5c744 |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-12-12T16:46:48Z |
| publishDate | 2016-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-ded64cf212244966b3b805193ec5c7442022-12-22T00:18:28ZengInternational Union of CrystallographyIUCrData2414-31462016-02-0112x16018810.1107/S2414314616001887su4012t-3-Benzyl-r-2,c-6-diphenylpiperidin-4-oneR. Arulraj0S. Sivakumar1A. Thiruvalluvar2A. Manimekalai3Research and Development Centre, Bharathiar University, Coimbatore 641 046, Tamilnadu, IndiaResearch and Development Centre, Bharathiar University, Coimbatore 641 046, Tamilnadu, IndiaPostgraduate Research Department of Physics, Rajah Serfoji Government College (Autonomous), Thanjavur 613 005, Tamilnadu, IndiaDepartment of Chemistry, Annamalai University, Annamalai Nagar 608 002, Tamilnadu, IndiaThe asymmetric unit of the title compound, C24H23NO, contains two crystallographically independent molecules (A and B). In both molecules, the piperidine rings adopt a chair conformation and the phenyl rings and the benzyl group substituents are attached equatorially. The dihedral angle between the phenyl rings is 60.80 (10)° in molecule A and 68.43 (9)° in molecule B. The phenyl ring of the benzyl group makes dihedral angles of 76.95 (9) and 42.25 (10)° with the phenyl rings in molecule A, and dihedral angles of 81.38 (11) and 30.19 (11)° in molecule B. In the crystal, the two molecules are linked by N—H...O hydrogen bonds, forming –A–B–A–B– chains along [100]. In addition, five C—H...π interactions are also present, linking the chains to form a three-dimensional structure.http://scripts.iucr.org/cgi-bin/paper?S2414314616001887crystal structurepiperidin-4-oneN—H...O hydrogen bondingC—H...π interactions |
| spellingShingle | R. Arulraj S. Sivakumar A. Thiruvalluvar A. Manimekalai t-3-Benzyl-r-2,c-6-diphenylpiperidin-4-one IUCrData crystal structure piperidin-4-one N—H...O hydrogen bonding C—H...π interactions |
| title | t-3-Benzyl-r-2,c-6-diphenylpiperidin-4-one |
| title_full | t-3-Benzyl-r-2,c-6-diphenylpiperidin-4-one |
| title_fullStr | t-3-Benzyl-r-2,c-6-diphenylpiperidin-4-one |
| title_full_unstemmed | t-3-Benzyl-r-2,c-6-diphenylpiperidin-4-one |
| title_short | t-3-Benzyl-r-2,c-6-diphenylpiperidin-4-one |
| title_sort | t 3 benzyl r 2 c 6 diphenylpiperidin 4 one |
| topic | crystal structure piperidin-4-one N—H...O hydrogen bonding C—H...π interactions |
| url | http://scripts.iucr.org/cgi-bin/paper?S2414314616001887 |
| work_keys_str_mv | AT rarulraj t3benzylr2c6diphenylpiperidin4one AT ssivakumar t3benzylr2c6diphenylpiperidin4one AT athiruvalluvar t3benzylr2c6diphenylpiperidin4one AT amanimekalai t3benzylr2c6diphenylpiperidin4one |