Potassium (2,2′-bipyridine-κ2N,N′)bis(carbonato-κ2O,O′)cobaltate(III) dihydrate
In the title compound, K[Co(CO3)2(C10H8N2)]·2H2O, the Co(III) atom is coordinated by two bipyridine N atoms and four O atoms from two bidentate chelating carbonate anions, and thus adopts a distorted octahedral N2O4 environment. The [Co(bipy)(CO3)2]− (bipy is 2,2&#...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010-10-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810037463 |
| _version_ | 1819281412225761280 |
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| author | Jian-Li Lin Jian-Fei Wang |
| author_facet | Jian-Li Lin Jian-Fei Wang |
| author_sort | Jian-Li Lin |
| collection | DOAJ |
| description | In the title compound, K[Co(CO3)2(C10H8N2)]·2H2O, the Co(III) atom is coordinated by two bipyridine N atoms and four O atoms from two bidentate chelating carbonate anions, and thus adopts a distorted octahedral N2O4 environment. The [Co(bipy)(CO3)2]− (bipy is 2,2′-bipyridine) units are stacked along [100] via π–π stacking interactions, with interplanar distances between the bipyridine rings of 3.36 (4) and 3.44 (6) Å, forming chains. Classical O—H...O hydrogen-bonding interactions link the chains, forming channels along (100) in which the K+ ions reside and leading to a three-dimensional supramolecular architecture. |
| first_indexed | 2024-12-24T00:59:17Z |
| format | Article |
| id | doaj.art-defe5dae6c944524b32004499c249733 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T00:59:17Z |
| publishDate | 2010-10-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-defe5dae6c944524b32004499c2497332022-12-21T17:23:24ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-10-016610m1310m131010.1107/S1600536810037463Potassium (2,2′-bipyridine-κ2N,N′)bis(carbonato-κ2O,O′)cobaltate(III) dihydrateJian-Li LinJian-Fei WangIn the title compound, K[Co(CO3)2(C10H8N2)]·2H2O, the Co(III) atom is coordinated by two bipyridine N atoms and four O atoms from two bidentate chelating carbonate anions, and thus adopts a distorted octahedral N2O4 environment. The [Co(bipy)(CO3)2]− (bipy is 2,2′-bipyridine) units are stacked along [100] via π–π stacking interactions, with interplanar distances between the bipyridine rings of 3.36 (4) and 3.44 (6) Å, forming chains. Classical O—H...O hydrogen-bonding interactions link the chains, forming channels along (100) in which the K+ ions reside and leading to a three-dimensional supramolecular architecture.http://scripts.iucr.org/cgi-bin/paper?S1600536810037463 |
| spellingShingle | Jian-Li Lin Jian-Fei Wang Potassium (2,2′-bipyridine-κ2N,N′)bis(carbonato-κ2O,O′)cobaltate(III) dihydrate Acta Crystallographica Section E |
| title | Potassium (2,2′-bipyridine-κ2N,N′)bis(carbonato-κ2O,O′)cobaltate(III) dihydrate |
| title_full | Potassium (2,2′-bipyridine-κ2N,N′)bis(carbonato-κ2O,O′)cobaltate(III) dihydrate |
| title_fullStr | Potassium (2,2′-bipyridine-κ2N,N′)bis(carbonato-κ2O,O′)cobaltate(III) dihydrate |
| title_full_unstemmed | Potassium (2,2′-bipyridine-κ2N,N′)bis(carbonato-κ2O,O′)cobaltate(III) dihydrate |
| title_short | Potassium (2,2′-bipyridine-κ2N,N′)bis(carbonato-κ2O,O′)cobaltate(III) dihydrate |
| title_sort | potassium 2 2 amp 8242 bipyridine amp 954 2n n amp 8242 bis carbonato amp 954 2o o amp 8242 cobaltate iii dihydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810037463 |
| work_keys_str_mv | AT jianlilin potassium22amp8242bipyridineamp9542nnamp8242biscarbonatoamp9542ooamp8242cobaltateiiidihydrate AT jianfeiwang potassium22amp8242bipyridineamp9542nnamp8242biscarbonatoamp9542ooamp8242cobaltateiiidihydrate |