A New Zn(II) Two-dimensional Coordination Polymer: Synthesis, Structure, Highly Efficient Fluorescence and DFT Study
A new two-dimensional coordinate polymer, {[Zn2(pbmpd)(H2O)4]·(H2O)}n (H4pbmpd = 1,1'-(1,4-phenylenebis(methylene))bis-(1H-pyrazole-3,5-dicarboxylic acid)), has been hydrothermally synthesized and characterized by IR spectrum, elemental analysis，TGA and X-ray single-crystal/powder diffraction....
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| Format: | Article |
| Language: | English |
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Slovenian Chemical Society
2022-09-01
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| Series: | Acta Chimica Slovenica |
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| Online Access: | https://journals.matheo.si/index.php/ACSi/article/view/7500 |
| _version_ | 1797962901838888960 |
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| author | Fen-Fang Li |
| author_facet | Fen-Fang Li |
| author_sort | Fen-Fang Li |
| collection | DOAJ |
| description | A new two-dimensional coordinate polymer, {[Zn2(pbmpd)(H2O)4]·(H2O)}n (H4pbmpd = 1,1'-(1,4-phenylenebis(methylene))bis-(1H-pyrazole-3,5-dicarboxylic acid)), has been hydrothermally synthesized and characterized by IR spectrum, elemental analysis，TGA and X-ray single-crystal/powder diffraction. Structural analyses reveal that complex 1 exhibits a two-dimensional sheet structure in the crystal lattice. In complex 1, the carboxylic oxygen atoms and conjugated N atoms of pbmpd4- bridge zinc(II) ions form indefinitely zigzag shaped one-dimensional chains through p···p stacking interactions which are further connected by [ZnO6] units to form a novel two-dimensional structure. Finally, p···p stacking interactions and intermolecular hydrogen bonds assemble the two dimensional networks into a three-dimensional framework. Furthermore, the luminescent properties are also discussed. Interestingly, the solid state photoluminescence properties of the title polymer show the enhancement effect of spectrum. Density functional theory (DFT) calculations were used to support the experimental data. |
| first_indexed | 2024-04-11T01:21:04Z |
| format | Article |
| id | doaj.art-df3bb40b877e46fb875d9ede71cb137d |
| institution | Directory Open Access Journal |
| issn | 1318-0207 1580-3155 |
| language | English |
| last_indexed | 2024-04-11T01:21:04Z |
| publishDate | 2022-09-01 |
| publisher | Slovenian Chemical Society |
| record_format | Article |
| series | Acta Chimica Slovenica |
| spelling | doaj.art-df3bb40b877e46fb875d9ede71cb137d2023-01-03T11:29:15ZengSlovenian Chemical SocietyActa Chimica Slovenica1318-02071580-31552022-09-0169359660310.17344/acsi.2022.75001091A New Zn(II) Two-dimensional Coordination Polymer: Synthesis, Structure, Highly Efficient Fluorescence and DFT StudyFen-Fang Li0Jinzhong universityA new two-dimensional coordinate polymer, {[Zn2(pbmpd)(H2O)4]·(H2O)}n (H4pbmpd = 1,1'-(1,4-phenylenebis(methylene))bis-(1H-pyrazole-3,5-dicarboxylic acid)), has been hydrothermally synthesized and characterized by IR spectrum, elemental analysis，TGA and X-ray single-crystal/powder diffraction. Structural analyses reveal that complex 1 exhibits a two-dimensional sheet structure in the crystal lattice. In complex 1, the carboxylic oxygen atoms and conjugated N atoms of pbmpd4- bridge zinc(II) ions form indefinitely zigzag shaped one-dimensional chains through p···p stacking interactions which are further connected by [ZnO6] units to form a novel two-dimensional structure. Finally, p···p stacking interactions and intermolecular hydrogen bonds assemble the two dimensional networks into a three-dimensional framework. Furthermore, the luminescent properties are also discussed. Interestingly, the solid state photoluminescence properties of the title polymer show the enhancement effect of spectrum. Density functional theory (DFT) calculations were used to support the experimental data.https://journals.matheo.si/index.php/ACSi/article/view/7500zn(ii) complexcrystal structure1,1'-(1,4- phenylenebis(methylene)) bis-(1h-pyrazole-3,5-dicarboxylic acid)fluorescence propertydft study |
| spellingShingle | Fen-Fang Li A New Zn(II) Two-dimensional Coordination Polymer: Synthesis, Structure, Highly Efficient Fluorescence and DFT Study Acta Chimica Slovenica zn(ii) complex crystal structure 1,1'-(1,4- phenylenebis(methylene)) bis-(1h-pyrazole-3,5-dicarboxylic acid) fluorescence property dft study |
| title | A New Zn(II) Two-dimensional Coordination Polymer: Synthesis, Structure, Highly Efficient Fluorescence and DFT Study |
| title_full | A New Zn(II) Two-dimensional Coordination Polymer: Synthesis, Structure, Highly Efficient Fluorescence and DFT Study |
| title_fullStr | A New Zn(II) Two-dimensional Coordination Polymer: Synthesis, Structure, Highly Efficient Fluorescence and DFT Study |
| title_full_unstemmed | A New Zn(II) Two-dimensional Coordination Polymer: Synthesis, Structure, Highly Efficient Fluorescence and DFT Study |
| title_short | A New Zn(II) Two-dimensional Coordination Polymer: Synthesis, Structure, Highly Efficient Fluorescence and DFT Study |
| title_sort | new zn ii two dimensional coordination polymer synthesis structure highly efficient fluorescence and dft study |
| topic | zn(ii) complex crystal structure 1,1'-(1,4- phenylenebis(methylene)) bis-(1h-pyrazole-3,5-dicarboxylic acid) fluorescence property dft study |
| url | https://journals.matheo.si/index.php/ACSi/article/view/7500 |
| work_keys_str_mv | AT fenfangli anewzniitwodimensionalcoordinationpolymersynthesisstructurehighlyefficientfluorescenceanddftstudy AT fenfangli newzniitwodimensionalcoordinationpolymersynthesisstructurehighlyefficientfluorescenceanddftstudy |