Analysis of the behavior of magnesium and CO vapor in the carbothermic reduction of magnesia in a vacuum
The aim of this paper is to experimentally investigate the behavior of magnesium and carbon monoxide vapor in the carbothermic reduction of magnesia at condensing zone temperatures ranging from 923 K to 1223 K. The phase, surface morphology, and composition of the condensates obtained were examined...
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Format: | Article |
Language: | English |
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KeAi Communications Co., Ltd.
2014-03-01
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Series: | Journal of Magnesium and Alloys |
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Online Access: | http://www.sciencedirect.com/science/article/pii/S2213956714000231 |
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author | Cheng-bo Yang Yang Tian Tao Qu Bin Yang Bao-qiang Xu Yong-nian Dai |
author_facet | Cheng-bo Yang Yang Tian Tao Qu Bin Yang Bao-qiang Xu Yong-nian Dai |
author_sort | Cheng-bo Yang |
collection | DOAJ |
description | The aim of this paper is to experimentally investigate the behavior of magnesium and carbon monoxide vapor in the carbothermic reduction of magnesia at condensing zone temperatures ranging from 923 K to 1223 K. The phase, surface morphology, and composition of the condensates obtained were examined by means of scanning electron microscopy and energy-dispersive X-ray spectroscopy. The main findings of this paper include: the reverse reaction products, carbon and magnesium oxide, were formed following the process of magnesium vapor condensation, preventing two metal clusters from mutually combining. Moreover, the nearer the temperature of the condensation zone approached the liquid transformation temperature (810–910 K), the lower the rate of the reverse reaction between carbon monoxide and magnesium vapor. Decrease in the rate of the reverse reaction of magnesium was possible by controlling the condensation temperature. |
first_indexed | 2024-04-24T08:16:33Z |
format | Article |
id | doaj.art-df573335438649839f0e4159afe5f9ae |
institution | Directory Open Access Journal |
issn | 2213-9567 |
language | English |
last_indexed | 2024-04-24T08:16:33Z |
publishDate | 2014-03-01 |
publisher | KeAi Communications Co., Ltd. |
record_format | Article |
series | Journal of Magnesium and Alloys |
spelling | doaj.art-df573335438649839f0e4159afe5f9ae2024-04-17T03:54:51ZengKeAi Communications Co., Ltd.Journal of Magnesium and Alloys2213-95672014-03-0121505810.1016/j.jma.2014.02.003Analysis of the behavior of magnesium and CO vapor in the carbothermic reduction of magnesia in a vacuumCheng-bo Yang0Yang Tian1Tao Qu2Bin Yang3Bao-qiang Xu4Yong-nian Dai5National Engineering Laboratory for Vacuum Metallurgy, Kunming University of Science and Technology, Kunming 650093, ChinaNational Engineering Laboratory for Vacuum Metallurgy, Kunming University of Science and Technology, Kunming 650093, ChinaNational Engineering Laboratory for Vacuum Metallurgy, Kunming University of Science and Technology, Kunming 650093, ChinaNational Engineering Laboratory for Vacuum Metallurgy, Kunming University of Science and Technology, Kunming 650093, ChinaNational Engineering Laboratory for Vacuum Metallurgy, Kunming University of Science and Technology, Kunming 650093, ChinaNational Engineering Laboratory for Vacuum Metallurgy, Kunming University of Science and Technology, Kunming 650093, ChinaThe aim of this paper is to experimentally investigate the behavior of magnesium and carbon monoxide vapor in the carbothermic reduction of magnesia at condensing zone temperatures ranging from 923 K to 1223 K. The phase, surface morphology, and composition of the condensates obtained were examined by means of scanning electron microscopy and energy-dispersive X-ray spectroscopy. The main findings of this paper include: the reverse reaction products, carbon and magnesium oxide, were formed following the process of magnesium vapor condensation, preventing two metal clusters from mutually combining. Moreover, the nearer the temperature of the condensation zone approached the liquid transformation temperature (810–910 K), the lower the rate of the reverse reaction between carbon monoxide and magnesium vapor. Decrease in the rate of the reverse reaction of magnesium was possible by controlling the condensation temperature.http://www.sciencedirect.com/science/article/pii/S2213956714000231Carbon monoxideMagnesium vaporCarbothermic reductionCondensationVacuum |
spellingShingle | Cheng-bo Yang Yang Tian Tao Qu Bin Yang Bao-qiang Xu Yong-nian Dai Analysis of the behavior of magnesium and CO vapor in the carbothermic reduction of magnesia in a vacuum Journal of Magnesium and Alloys Carbon monoxide Magnesium vapor Carbothermic reduction Condensation Vacuum |
title | Analysis of the behavior of magnesium and CO vapor in the carbothermic reduction of magnesia in a vacuum |
title_full | Analysis of the behavior of magnesium and CO vapor in the carbothermic reduction of magnesia in a vacuum |
title_fullStr | Analysis of the behavior of magnesium and CO vapor in the carbothermic reduction of magnesia in a vacuum |
title_full_unstemmed | Analysis of the behavior of magnesium and CO vapor in the carbothermic reduction of magnesia in a vacuum |
title_short | Analysis of the behavior of magnesium and CO vapor in the carbothermic reduction of magnesia in a vacuum |
title_sort | analysis of the behavior of magnesium and co vapor in the carbothermic reduction of magnesia in a vacuum |
topic | Carbon monoxide Magnesium vapor Carbothermic reduction Condensation Vacuum |
url | http://www.sciencedirect.com/science/article/pii/S2213956714000231 |
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