Analysis of the behavior of magnesium and CO vapor in the carbothermic reduction of magnesia in a vacuum

The aim of this paper is to experimentally investigate the behavior of magnesium and carbon monoxide vapor in the carbothermic reduction of magnesia at condensing zone temperatures ranging from 923 K to 1223 K. The phase, surface morphology, and composition of the condensates obtained were examined...

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Main Authors: Cheng-bo Yang, Yang Tian, Tao Qu, Bin Yang, Bao-qiang Xu, Yong-nian Dai
Format: Article
Language:English
Published: KeAi Communications Co., Ltd. 2014-03-01
Series:Journal of Magnesium and Alloys
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2213956714000231
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author Cheng-bo Yang
Yang Tian
Tao Qu
Bin Yang
Bao-qiang Xu
Yong-nian Dai
author_facet Cheng-bo Yang
Yang Tian
Tao Qu
Bin Yang
Bao-qiang Xu
Yong-nian Dai
author_sort Cheng-bo Yang
collection DOAJ
description The aim of this paper is to experimentally investigate the behavior of magnesium and carbon monoxide vapor in the carbothermic reduction of magnesia at condensing zone temperatures ranging from 923 K to 1223 K. The phase, surface morphology, and composition of the condensates obtained were examined by means of scanning electron microscopy and energy-dispersive X-ray spectroscopy. The main findings of this paper include: the reverse reaction products, carbon and magnesium oxide, were formed  following the process of magnesium vapor condensation, preventing two metal clusters from mutually combining. Moreover, the nearer the temperature of the condensation zone approached the liquid transformation temperature (810–910 K), the lower the rate of the reverse reaction between carbon monoxide and magnesium vapor. Decrease in the rate of the reverse reaction of magnesium was possible by controlling the condensation temperature.
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spelling doaj.art-df573335438649839f0e4159afe5f9ae2024-04-17T03:54:51ZengKeAi Communications Co., Ltd.Journal of Magnesium and Alloys2213-95672014-03-0121505810.1016/j.jma.2014.02.003Analysis of the behavior of magnesium and CO vapor in the carbothermic reduction of magnesia in a vacuumCheng-bo Yang0Yang Tian1Tao Qu2Bin Yang3Bao-qiang Xu4Yong-nian Dai5National Engineering Laboratory for Vacuum Metallurgy, Kunming University of Science and Technology, Kunming 650093, ChinaNational Engineering Laboratory for Vacuum Metallurgy, Kunming University of Science and Technology, Kunming 650093, ChinaNational Engineering Laboratory for Vacuum Metallurgy, Kunming University of Science and Technology, Kunming 650093, ChinaNational Engineering Laboratory for Vacuum Metallurgy, Kunming University of Science and Technology, Kunming 650093, ChinaNational Engineering Laboratory for Vacuum Metallurgy, Kunming University of Science and Technology, Kunming 650093, ChinaNational Engineering Laboratory for Vacuum Metallurgy, Kunming University of Science and Technology, Kunming 650093, ChinaThe aim of this paper is to experimentally investigate the behavior of magnesium and carbon monoxide vapor in the carbothermic reduction of magnesia at condensing zone temperatures ranging from 923 K to 1223 K. The phase, surface morphology, and composition of the condensates obtained were examined by means of scanning electron microscopy and energy-dispersive X-ray spectroscopy. The main findings of this paper include: the reverse reaction products, carbon and magnesium oxide, were formed  following the process of magnesium vapor condensation, preventing two metal clusters from mutually combining. Moreover, the nearer the temperature of the condensation zone approached the liquid transformation temperature (810–910 K), the lower the rate of the reverse reaction between carbon monoxide and magnesium vapor. Decrease in the rate of the reverse reaction of magnesium was possible by controlling the condensation temperature.http://www.sciencedirect.com/science/article/pii/S2213956714000231Carbon monoxideMagnesium vaporCarbothermic reductionCondensationVacuum
spellingShingle Cheng-bo Yang
Yang Tian
Tao Qu
Bin Yang
Bao-qiang Xu
Yong-nian Dai
Analysis of the behavior of magnesium and CO vapor in the carbothermic reduction of magnesia in a vacuum
Journal of Magnesium and Alloys
Carbon monoxide
Magnesium vapor
Carbothermic reduction
Condensation
Vacuum
title Analysis of the behavior of magnesium and CO vapor in the carbothermic reduction of magnesia in a vacuum
title_full Analysis of the behavior of magnesium and CO vapor in the carbothermic reduction of magnesia in a vacuum
title_fullStr Analysis of the behavior of magnesium and CO vapor in the carbothermic reduction of magnesia in a vacuum
title_full_unstemmed Analysis of the behavior of magnesium and CO vapor in the carbothermic reduction of magnesia in a vacuum
title_short Analysis of the behavior of magnesium and CO vapor in the carbothermic reduction of magnesia in a vacuum
title_sort analysis of the behavior of magnesium and co vapor in the carbothermic reduction of magnesia in a vacuum
topic Carbon monoxide
Magnesium vapor
Carbothermic reduction
Condensation
Vacuum
url http://www.sciencedirect.com/science/article/pii/S2213956714000231
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