The microstructural changes of Ge2Sb2Te5 thin film during crystallization process

Phase change memory is known as the most promising candidate for the next generation nonvolatile memory technology. In this paper, the microstructural changes of Ge2Sb2Te5 film, which is the most common choice of phase change memory material, has been carefully studied by the combination of several...

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Main Authors: Jingbo Xu, Chao Qi, Limin Chen, Long Zheng, Qiyun Xie
Format: Article
Language:English
Published: AIP Publishing LLC 2018-05-01
Series:AIP Advances
Online Access:http://dx.doi.org/10.1063/1.5025204
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author Jingbo Xu
Chao Qi
Limin Chen
Long Zheng
Qiyun Xie
author_facet Jingbo Xu
Chao Qi
Limin Chen
Long Zheng
Qiyun Xie
author_sort Jingbo Xu
collection DOAJ
description Phase change memory is known as the most promising candidate for the next generation nonvolatile memory technology. In this paper, the microstructural changes of Ge2Sb2Te5 film, which is the most common choice of phase change memory material, has been carefully studied by the combination of several characterization techniques. The combination of resistance measurements, X-ray diffraction, Raman spectroscopy and X-ray reflectivity allows us to simultaneously extract the characteristics of microstructural changes during crystallization process. The existence of surface/interface Ge2Sb2Te5 layer has been proposed here based on X-ray reflectivity measurements. Although the total film thickness decreases, as a result of the phase transition from amorphous to metastable crystalline cubic and then to the stable hexagonal phase, the surface/interface thickness increases after crystallization. Moreover, the increase of average grain size, density and surface roughness has been confirmed during thermal annealing process.
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spelling doaj.art-df76e107c06345b89722cf37e2e40f2d2022-12-21T18:00:03ZengAIP Publishing LLCAIP Advances2158-32262018-05-0185055006055006-610.1063/1.5025204017805ADVThe microstructural changes of Ge2Sb2Te5 thin film during crystallization processJingbo Xu0Chao Qi1Limin Chen2Long Zheng3Qiyun Xie4Key Laboratory of Radio Frequency and Micro-Nano Electronics of Jiangsu Province, Nanjing 210023, Jiangsu, ChinaKey Laboratory of Radio Frequency and Micro-Nano Electronics of Jiangsu Province, Nanjing 210023, Jiangsu, ChinaKey Laboratory of Radio Frequency and Micro-Nano Electronics of Jiangsu Province, Nanjing 210023, Jiangsu, ChinaSchool of Mathematics and Physics, Jiangsu University of Technology, Changzhou 213001, ChinaKey Laboratory of Radio Frequency and Micro-Nano Electronics of Jiangsu Province, Nanjing 210023, Jiangsu, ChinaPhase change memory is known as the most promising candidate for the next generation nonvolatile memory technology. In this paper, the microstructural changes of Ge2Sb2Te5 film, which is the most common choice of phase change memory material, has been carefully studied by the combination of several characterization techniques. The combination of resistance measurements, X-ray diffraction, Raman spectroscopy and X-ray reflectivity allows us to simultaneously extract the characteristics of microstructural changes during crystallization process. The existence of surface/interface Ge2Sb2Te5 layer has been proposed here based on X-ray reflectivity measurements. Although the total film thickness decreases, as a result of the phase transition from amorphous to metastable crystalline cubic and then to the stable hexagonal phase, the surface/interface thickness increases after crystallization. Moreover, the increase of average grain size, density and surface roughness has been confirmed during thermal annealing process.http://dx.doi.org/10.1063/1.5025204
spellingShingle Jingbo Xu
Chao Qi
Limin Chen
Long Zheng
Qiyun Xie
The microstructural changes of Ge2Sb2Te5 thin film during crystallization process
AIP Advances
title The microstructural changes of Ge2Sb2Te5 thin film during crystallization process
title_full The microstructural changes of Ge2Sb2Te5 thin film during crystallization process
title_fullStr The microstructural changes of Ge2Sb2Te5 thin film during crystallization process
title_full_unstemmed The microstructural changes of Ge2Sb2Te5 thin film during crystallization process
title_short The microstructural changes of Ge2Sb2Te5 thin film during crystallization process
title_sort microstructural changes of ge2sb2te5 thin film during crystallization process
url http://dx.doi.org/10.1063/1.5025204
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