An Approach to Paracyclophane-Based Tetrathiafulvalenes: Synthesis and Characterization of a <i>Pseudo-Geminal</i> [2.2]Paracyclophane 1,3-Dithia-2-Thione

An Approach to Paracyclophane-Based Tetrathiafulvalenes: Synthesis and Characterization of a <i>Pseudo-Geminal</i> [2.2]Paracyclophane 1,3-Dithia-2-Thione

The synthesis of paracyclophane-based tetrathiafulvalene precursors is described in the context of the importance of these compounds in the field of material chemistry. <i>Pseudo-geminal</i> bis(1,3-dithia-2-thione) was synthesized via the corresponding 1,3-dithiol-2-ylium salt. The latt...

Full description

Bibliographic Details
Main Authors:	Lucian G. Bahrin, Henning Hopf, Peter G. Jones, Mihail L. Birsa, Laura G. Sarbu
Format:	Article
Language:	English
Published:	MDPI AG 2020-11-01
Series:	Molecules
Subjects:	[2.2]paracyclophanes dithiocarbamates 1,3-dithiolium salts trithiones
Online Access:	https://www.mdpi.com/1420-3049/25/22/5262

Similar Items

An Improved Synthetic Method for Sensitive Iodine Containing Tricyclic Flavonoids
by: Mihail Lucian Birsa, et al.
Published: (2022-12-01)

Recent Progress in Research on [2.2]Paracyclophane-Based Dyes
by: Wenjing Liu, et al.
Published: (2023-03-01)

[(2-Dimesitylboryl)phenyl]ethynyl-Substituted [2.2]Paracyclophane Exhibiting Circularly Polarized Luminescence in Both Solution and Solid-State
by: Lianfeng Guo, et al.
Published: (2025-01-01)

Synthesis of Mono‐, Di‐, Tri‐, and Tetra‐cationic Pyridinium and Vinylpyridinium Modified [2.2]Paracyclophanes: Modular Receptors for Supramolecular Systems
by: Dr. Yichuan Wang, et al.
Published: (2024-08-01)

Fluorescent Paracyclophanes: Unveiling Ultra‐Strong Binding with Cucurbit[8]uril in Aqueous Environments
by: Laura Marie Grimm, et al.
Published: (2024-05-01)

Tetraphenylethene-Embedded Pillar[5]arene and [15]Paracyclophane: Distorted Cavities and Host–Guest Binding Properties
by: Yingtao Fan, et al.
Published: (2021-09-01)

Synthesis of New Planar-Chiral Linked [2.2]Paracyclophanes-<i>N</i>-([2.2]-Paracyclophanylcarbamoyl)-4-([2.2]Paracyclophanylcarboxamide, [2.2]Paracyclophanyl-Substituted Triazolthiones and -Substituted Oxadiazoles
by: Ashraf A. Aly, et al.
Published: (2020-07-01)

Comparison of the reactivity of [2.2]paracyclophane and p-xylene
by: Dyson, P, et al.
Published: (1995)

Organocatalytic desymmetrization provides access to planar chiral [2.2]paracyclophanes
by: Vojtěch Dočekal, et al.
Published: (2024-04-01)

A Structure–Activity Relationship Study on the Antioxidant Properties of Dithiocarbamic Flavanones
by: Mihail Lucian Birsa, et al.
Published: (2024-08-01)

Kinetic resolution of substituted amido[2.2]paracyclophanes via asymmetric electrophilic amination
by: Shaoze Yu, et al.
Published: (2023-08-01)

The reactivity of [2.2.2]paracyclophane towards Cr(CO)(6): Experimental and theoretical considerations
by: Dyson, P, et al.
Published: (1997)

Synthesis of bisnitroepoxides and their applications in the synthesis of bis(thiazolidine-2-thiones), bis(dithiocarbamates), bis(xanthates) and bis(thiazoles)
by: Azim Ziyaei Halimehjani, et al.
Published: (2024-09-01)

Molecular-Simulation–Inspired Synthesis of [6]-Prismane via Photoisomerisation of Octafluoro[2.2]paracyclophane
by: Yoichi Hosokawa, et al.
Published: (2024-02-01)

Interactions of a paracyclophane-based conjugated oligoelectrolyte with biological membranes
by: Limwongyut, Jakarin, et al.
Published: (2020)

Design, synthesis and anti-PVY activity of planar chiral thiourea derivatives incorporated with [2.2]paracyclophane
by: Shu, Liangzhen, et al.
Published: (2024)

Penentuan ditiokarbamat dengan kaedah rongga-kepala statik /
by: 397475 Lau, Choi Yin
Published: (1999)

Complexation reactions of dithiocarbamates /
by: 276182 Hulanicki, Adam

[2,2] Paracyclophanes-based double helicates for constructing artificial light-harvesting systems and white LED device
by: Zhe Lian, et al.
Published: (2023-05-01)

New Nostocyclophanes from <i>Nostoc linckia</i>
by: Jingqiu Dai, et al.
Published: (2023-01-01)

Aggregation-induced emission from optically active X-shaped molecules based on planar chiral [2.2]paracyclophane
by: Keishi Jikuhara, et al.
Published: (2023-12-01)

SYNTHESIS, CHARACTERIZATION AND CORROSION INHIBITION SCREENING: Cu[EtBenzdtc]2 and Cu[BuMedtc]2
by: NUR NADIA DZULKIFLI, et al.
Published: (2021-04-01)

An Eco-Friendly Method to Synthesize Potent Antimicrobial Tricyclic Flavonoids
by: Loredana-Elena Mantea, et al.
Published: (2024-08-01)

Synthesis of a Ni Complex Chelated by a [2.2]Paracyclophane-Functionalized Diimine Ligand and Its Catalytic Activity for Olefin Oligomerization
by: Daisuke Takeuchi, et al.
Published: (2021-05-01)

Aseries of M-M_heterometallic coordination polymers: syntheses structures properties (M=Ni+2/M-=Ag+1 ,Cd+2 ,Zn+2)
by: Hiba F. AL. Katib
Published: (2016-09-01)

Bis(N-benzyl-N-methyldithiocarbamato-κ2S,S′)(pyridine-κN)cadmium(II)
by: Muhammad Ali Ehsan, et al.
Published: (2016-01-01)

Dithiocarbamates as potential PTP1B inhibitors for diabetes management
by: Tanvi A. Deshpande, et al.
Published: (2022-01-01)

Microwave-Assisted Improved Synthesis of Oxazolidin-2-ones, Oxazolidine-2-thiones and Thiazolidine-2-thione Chiral Auxiliaries
by: Mario Ordóñez, et al.
Published: (2011-10-01)

The crystal structure of (S, R p)-4–benzhydrylideneamino-12-(4-tert-butyl oxazolin-2-yl)[2.2]paracyclophane, C36H36N2O
by: Chen Zhen, et al.
Published: (2023-08-01)

Co[MeCycHexdtc]2 AND Co[EtCycHexdtc]2: SYNTHESIS, CHARACTERIZATION AND CORROSION INHIBITION SCREENING IN HCl AND H2SO4
by: Mimi Wahidah Mohd Radzi, et al.
Published: (2021-10-01)

Multicomponent synthesis of some new (1S,4S)-2,5-diazabicyclo[2.2.1]heptane-dithiocarbamates and their in vitro anti-proliferative activity against CaSki, MDA-MB-231 and SK-Lu-1 tumour cells as apoptosis inducing agents without necrosis
by: Sujay Laskar, et al.
Published: (2017-01-01)

Design, Synthesis, and Molecular Docking of Paracyclophanyl-Thiazole Hybrids as Novel CDK1 Inhibitors and Apoptosis Inducing Anti-Melanoma Agents
by: Ashraf A. Aly, et al.
Published: (2020-11-01)

Anticancer Activity and Apoptosis Induction of Gold(III) Complexes Containing 2,2′-Bipyridine-3,3′-dicarboxylic Acid and Dithiocarbamates
by: Ali Alhoshani, et al.
Published: (2021-06-01)

PbS Nanoparticles Prepared Using 1, 10-Phenanthroline Adduct of Lead(II) Bis(<i>N</i>-alkyl-<i>N</i>-phenyl dithiocarbamate) as Single Source Precursors
by: Jerry O. Adeyemi, et al.
Published: (2020-04-01)

Crystal structures and Hirshfeld surface analyses of bis[N,N-bis(2-methoxyethyl)dithiocarbamato-κ2S,S′]di-n-butyltin(IV) and [N-(2-methoxyethyl)-N-methyldithiocarbamato-κ2S,S′]triphenyltin(IV)
by: Rapidah Mohamad, et al.
Published: (2018-03-01)

Nb<sub>2</sub>S<sub>4</sub>(CS<sub>2</sub>NH<sub>2</sub>)<sub>4</sub>—A New Precursor for NbS<sub>2</sub> and Its Transition Metal Inserted Derivatives
by: Sebastian Mangelsen, et al.
Published: (2023-12-01)

Synthesis and characterization of metal dithiocarbamate derivatives of (S)-1-phenyl-1,2,3,4-tetrahydroisoquinoline
by: Azim Ziyaei Halimehjani, et al.
Published: (2024-11-01)

Benzo[<i>d</i>][1,3]oxathiole-2-thione
by: R. Alan Aitken, et al.
Published: (2024-09-01)

New Paracyclophanylthiazoles with Anti-Leukemia Activity: Design, Synthesis, Molecular Docking, and Mechanistic Studies
by: Ashraf A Aly, et al.
Published: (2020-07-01)

Effects of Halide Ions on the Carbamidocyclophane Biosynthesis in Nostoc sp. CAVN2
by: Michael Preisitsch, et al.
Published: (2016-01-01)