| Summary: | Impact toughness is essential for evaluating the mechanical properties of ship hull steels. This study focused on understanding the embrittlement mechanism of NiAl precipitation-strengthened HSLA steels by integrating advanced characterization and atomic-scale calculations. The factors causing the deterioration of the impact toughness of NiAl precipitation-strengthened steels, which have been contentious, were identified. The embrittlement mechanism and crack propagation mode were revealed using first-principles calculations and 3D impact fracture morphology, respectively. The results suggested that the numerous homogeneous NiAl nanoparticles within the bcc-Fe matrix reduced the impact toughness of the HSLA steels. As the precipitate interparticle spacing (L) decreased, the impact toughness decreased until it attained a critical value (∼27 nm). This is interpreted effectively by the calculations indicating that the shear modulus (75 GPa) and fracture energy (4.5 J/m2) of the NiAl phase, particularly the NiAlMn phase (46 GPa, 4 J/m2), are significantly lower than those of bcc-Fe (83 GPa, 5 J/m2). This induces the fracture of nanoparticles under rapid impact loading, which functions as numerous crack initiations before plastic deformation of the matrix. The small L achieved after peak-hardening aging can result in the interconnection of these crack sources and cause instantaneous cleavage fractures, similar to brittle materials.
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