4,4′-(Ethene-1,2-diyl)dipyridinium 4-[2-(pyridin-4-yl)ethenyl]pyridinium octacyanidomolybdate(V) tetrahydrate
The crystal structure of the title compound, (C12H12N2)(C12H11N2)[Mo(CN)8]·4H2O, consists of 4,4′-(ethene-1,2-diyl)dipyridinium and 4-[2-(pyridin-4-yl)ethenyl]pyridinium cations disordered over the same site, an [Mo(CN)8]3− anion and four water molecules of crystallizati...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2013-03-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813002985 |
| _version_ | 1818500191353831424 |
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| author | Ai-Hua Yuan Ai-Yun Hu Xiao-Zhen Yang |
| author_facet | Ai-Hua Yuan Ai-Yun Hu Xiao-Zhen Yang |
| author_sort | Ai-Hua Yuan |
| collection | DOAJ |
| description | The crystal structure of the title compound, (C12H12N2)(C12H11N2)[Mo(CN)8]·4H2O, consists of 4,4′-(ethene-1,2-diyl)dipyridinium and 4-[2-(pyridin-4-yl)ethenyl]pyridinium cations disordered over the same site, an [Mo(CN)8]3− anion and four water molecules of crystallization. The eight-coordinate [Mo(CN)8]3− unit exhibits a slightly distorted square-antiprismatic geometry. In the structure, the cations (crystallographic symmetry, 2) and anions (crystallographic symmetry, 222) are arranged alternately by N—H...O and O—H...N hydrogen bonds, forming layers parallel to the bc plane. These layers are further linked through O—H...N hydrogen bonds, generating a three-dimensional supramolecular network. |
| first_indexed | 2024-12-10T20:39:29Z |
| format | Article |
| id | doaj.art-df8922fbcdb847dbb7670f6de63c8c79 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-10T20:39:29Z |
| publishDate | 2013-03-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-df8922fbcdb847dbb7670f6de63c8c792022-12-22T01:34:25ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-03-01693m132m13210.1107/S16005368130029854,4′-(Ethene-1,2-diyl)dipyridinium 4-[2-(pyridin-4-yl)ethenyl]pyridinium octacyanidomolybdate(V) tetrahydrateAi-Hua YuanAi-Yun HuXiao-Zhen YangThe crystal structure of the title compound, (C12H12N2)(C12H11N2)[Mo(CN)8]·4H2O, consists of 4,4′-(ethene-1,2-diyl)dipyridinium and 4-[2-(pyridin-4-yl)ethenyl]pyridinium cations disordered over the same site, an [Mo(CN)8]3− anion and four water molecules of crystallization. The eight-coordinate [Mo(CN)8]3− unit exhibits a slightly distorted square-antiprismatic geometry. In the structure, the cations (crystallographic symmetry, 2) and anions (crystallographic symmetry, 222) are arranged alternately by N—H...O and O—H...N hydrogen bonds, forming layers parallel to the bc plane. These layers are further linked through O—H...N hydrogen bonds, generating a three-dimensional supramolecular network.http://scripts.iucr.org/cgi-bin/paper?S1600536813002985 |
| spellingShingle | Ai-Hua Yuan Ai-Yun Hu Xiao-Zhen Yang 4,4′-(Ethene-1,2-diyl)dipyridinium 4-[2-(pyridin-4-yl)ethenyl]pyridinium octacyanidomolybdate(V) tetrahydrate Acta Crystallographica Section E |
| title | 4,4′-(Ethene-1,2-diyl)dipyridinium 4-[2-(pyridin-4-yl)ethenyl]pyridinium octacyanidomolybdate(V) tetrahydrate |
| title_full | 4,4′-(Ethene-1,2-diyl)dipyridinium 4-[2-(pyridin-4-yl)ethenyl]pyridinium octacyanidomolybdate(V) tetrahydrate |
| title_fullStr | 4,4′-(Ethene-1,2-diyl)dipyridinium 4-[2-(pyridin-4-yl)ethenyl]pyridinium octacyanidomolybdate(V) tetrahydrate |
| title_full_unstemmed | 4,4′-(Ethene-1,2-diyl)dipyridinium 4-[2-(pyridin-4-yl)ethenyl]pyridinium octacyanidomolybdate(V) tetrahydrate |
| title_short | 4,4′-(Ethene-1,2-diyl)dipyridinium 4-[2-(pyridin-4-yl)ethenyl]pyridinium octacyanidomolybdate(V) tetrahydrate |
| title_sort | 4 4 8242 ethene 1 2 diyl dipyridinium 4 2 pyridin 4 yl ethenyl pyridinium octacyanidomolybdate v tetrahydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536813002985 |
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