Pentakis(ethylenediammonium) tri-μ-sulfato-bis[trisulfatocerate(IV)] trihydrate
In the cerate(IV) anion of the title salt, (C2H10N2)5[Ce2(SO4)9]·3H2O, the two metal atoms are bridged by three sulfate units; each metal atom is itself chelated by other three sulfate units so that the metal atoms exist in nine-coordinate tricapped trigonal-prismatic geometries. The an...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-07-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810021811 |
| Summary: | In the cerate(IV) anion of the title salt, (C2H10N2)5[Ce2(SO4)9]·3H2O, the two metal atoms are bridged by three sulfate units; each metal atom is itself chelated by other three sulfate units so that the metal atoms exist in nine-coordinate tricapped trigonal-prismatic geometries. The anions, cations and uncoordinated water molecules are linked by O—H...O and N—H...O hydrogen bonds, forming a three-dimensional network. One of the five cations is disordered with respect to the ethylene portion in a 1:1 ratio. |
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| ISSN: | 1600-5368 |