Pentakis(ethylenediammonium) tri-μ-sulfato-bis[trisulfatocerate(IV)] trihydrate
In the cerate(IV) anion of the title salt, (C2H10N2)5[Ce2(SO4)9]·3H2O, the two metal atoms are bridged by three sulfate units; each metal atom is itself chelated by other three sulfate units so that the metal atoms exist in nine-coordinate tricapped trigonal-prismatic geometries. The an...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010-07-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810021811 |
| _version_ | 1818283920823681024 |
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| author | Nadia Jabeen Saeed Ahmad Ali Farooq Meer Islam Ullah Khan Seik Weng Ng |
| author_facet | Nadia Jabeen Saeed Ahmad Ali Farooq Meer Islam Ullah Khan Seik Weng Ng |
| author_sort | Nadia Jabeen |
| collection | DOAJ |
| description | In the cerate(IV) anion of the title salt, (C2H10N2)5[Ce2(SO4)9]·3H2O, the two metal atoms are bridged by three sulfate units; each metal atom is itself chelated by other three sulfate units so that the metal atoms exist in nine-coordinate tricapped trigonal-prismatic geometries. The anions, cations and uncoordinated water molecules are linked by O—H...O and N—H...O hydrogen bonds, forming a three-dimensional network. One of the five cations is disordered with respect to the ethylene portion in a 1:1 ratio. |
| first_indexed | 2024-12-13T00:44:35Z |
| format | Article |
| id | doaj.art-df9602268a424e0794d775b3569c183d |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T00:44:35Z |
| publishDate | 2010-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-df9602268a424e0794d775b3569c183d2022-12-22T00:05:04ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-07-01667m797m79810.1107/S1600536810021811Pentakis(ethylenediammonium) tri-μ-sulfato-bis[trisulfatocerate(IV)] trihydrateNadia JabeenSaeed AhmadAli Farooq MeerIslam Ullah KhanSeik Weng NgIn the cerate(IV) anion of the title salt, (C2H10N2)5[Ce2(SO4)9]·3H2O, the two metal atoms are bridged by three sulfate units; each metal atom is itself chelated by other three sulfate units so that the metal atoms exist in nine-coordinate tricapped trigonal-prismatic geometries. The anions, cations and uncoordinated water molecules are linked by O—H...O and N—H...O hydrogen bonds, forming a three-dimensional network. One of the five cations is disordered with respect to the ethylene portion in a 1:1 ratio.http://scripts.iucr.org/cgi-bin/paper?S1600536810021811 |
| spellingShingle | Nadia Jabeen Saeed Ahmad Ali Farooq Meer Islam Ullah Khan Seik Weng Ng Pentakis(ethylenediammonium) tri-μ-sulfato-bis[trisulfatocerate(IV)] trihydrate Acta Crystallographica Section E |
| title | Pentakis(ethylenediammonium) tri-μ-sulfato-bis[trisulfatocerate(IV)] trihydrate |
| title_full | Pentakis(ethylenediammonium) tri-μ-sulfato-bis[trisulfatocerate(IV)] trihydrate |
| title_fullStr | Pentakis(ethylenediammonium) tri-μ-sulfato-bis[trisulfatocerate(IV)] trihydrate |
| title_full_unstemmed | Pentakis(ethylenediammonium) tri-μ-sulfato-bis[trisulfatocerate(IV)] trihydrate |
| title_short | Pentakis(ethylenediammonium) tri-μ-sulfato-bis[trisulfatocerate(IV)] trihydrate |
| title_sort | pentakis ethylenediammonium tri amp 956 sulfato bis trisulfatocerate iv trihydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810021811 |
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