Trityl Cation-Catalyzed Hosomi-Sakurai Reaction of Allylsilane with β,γ-Unsaturated α-Ketoester to Form γ,γ-Disubstituted α-Ketoesters

Trityl Cation-Catalyzed Hosomi-Sakurai Reaction of Allylsilane with β,γ-Unsaturated α-Ketoester to Form γ,γ-Disubstituted α-Ketoesters

(Ph<sub>3</sub>C)[BPh(<sup>F</sup>)<sub>4</sub>]-catalyzed Hosomi-Sakurai allylation of allylsilanes with β,γ-unsaturated α-ketoesters has been developed to give γ,γ-disubstituted α-ketoesters in high yields with excellent chemoselectivity. Preliminary mechanistic...

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Bibliographic Details
Main Authors: Zubao Gan, Deyun Cui, Hongyun Zhang, Ying Feng, Liying Huang, Yingying Gui, Lu Gao, Zhenlei Song
Format: Article
Language:English
Published: MDPI AG 2022-07-01
Series:Molecules
Subjects:
allylsilane
α-ketoester
Hosomi-Sakurai allylation
trityl cation
Online Access:https://www.mdpi.com/1420-3049/27/15/4730

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