(1,4,7,10-Tetraazacyclododecane-κ4N1,N4,N7,N10)(tetraoxidomolybdato-κO)copper(II) monohydrate
In the title compound, [CuMoO4(C8H20N4)]·H2O, the CuII atom is coordinated by four N atoms of the 1,4,7,10-tetraazacyclododecane (cyclen) ligand and one O atom of the molybdate unit in a distorted square-pyramidal environment. The water molecules are linked to the complex unit to form c...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810026000 |
| _version_ | 1818887162257473536 |
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| author | Dorothea Rohde Kurt Merzweiler |
| author_facet | Dorothea Rohde Kurt Merzweiler |
| author_sort | Dorothea Rohde |
| collection | DOAJ |
| description | In the title compound, [CuMoO4(C8H20N4)]·H2O, the CuII atom is coordinated by four N atoms of the 1,4,7,10-tetraazacyclododecane (cyclen) ligand and one O atom of the molybdate unit in a distorted square-pyramidal environment. The water molecules are linked to the complex unit to form centrosymmetric dimers [R44(12) and R44(16)] and discrete D32(9), D33(11) and D33(13) chains by O—H...O and N—H...O interactions. Additionally, the complex molecules are linked into C44(18) chain motifs by N—H...O interactions. As a result [(cyclen)CuMoO4] units and water molecules are linked to layers that are oriented parallel to the ac plane. The stacking of the layers in the b-axis direction is supported by weak C—H...O hydrogen bridges. |
| first_indexed | 2024-12-19T16:32:51Z |
| format | Article |
| id | doaj.art-df9d894a72b148e5aa753d4425b509d2 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-19T16:32:51Z |
| publishDate | 2010-08-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-df9d894a72b148e5aa753d4425b509d22022-12-21T20:14:08ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-08-01668m894m89410.1107/S1600536810026000(1,4,7,10-Tetraazacyclododecane-κ4N1,N4,N7,N10)(tetraoxidomolybdato-κO)copper(II) monohydrateDorothea RohdeKurt MerzweilerIn the title compound, [CuMoO4(C8H20N4)]·H2O, the CuII atom is coordinated by four N atoms of the 1,4,7,10-tetraazacyclododecane (cyclen) ligand and one O atom of the molybdate unit in a distorted square-pyramidal environment. The water molecules are linked to the complex unit to form centrosymmetric dimers [R44(12) and R44(16)] and discrete D32(9), D33(11) and D33(13) chains by O—H...O and N—H...O interactions. Additionally, the complex molecules are linked into C44(18) chain motifs by N—H...O interactions. As a result [(cyclen)CuMoO4] units and water molecules are linked to layers that are oriented parallel to the ac plane. The stacking of the layers in the b-axis direction is supported by weak C—H...O hydrogen bridges.http://scripts.iucr.org/cgi-bin/paper?S1600536810026000 |
| spellingShingle | Dorothea Rohde Kurt Merzweiler (1,4,7,10-Tetraazacyclododecane-κ4N1,N4,N7,N10)(tetraoxidomolybdato-κO)copper(II) monohydrate Acta Crystallographica Section E |
| title | (1,4,7,10-Tetraazacyclododecane-κ4N1,N4,N7,N10)(tetraoxidomolybdato-κO)copper(II) monohydrate |
| title_full | (1,4,7,10-Tetraazacyclododecane-κ4N1,N4,N7,N10)(tetraoxidomolybdato-κO)copper(II) monohydrate |
| title_fullStr | (1,4,7,10-Tetraazacyclododecane-κ4N1,N4,N7,N10)(tetraoxidomolybdato-κO)copper(II) monohydrate |
| title_full_unstemmed | (1,4,7,10-Tetraazacyclododecane-κ4N1,N4,N7,N10)(tetraoxidomolybdato-κO)copper(II) monohydrate |
| title_short | (1,4,7,10-Tetraazacyclododecane-κ4N1,N4,N7,N10)(tetraoxidomolybdato-κO)copper(II) monohydrate |
| title_sort | 1 4 7 10 tetraazacyclododecane amp 954 4n1 n4 n7 n10 tetraoxidomolybdato amp 954 o copper ii monohydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810026000 |
| work_keys_str_mv | AT dorothearohde 14710tetraazacyclododecaneamp9544n1n4n7n10tetraoxidomolybdatoamp954ocopperiimonohydrate AT kurtmerzweiler 14710tetraazacyclododecaneamp9544n1n4n7n10tetraoxidomolybdatoamp954ocopperiimonohydrate |