Anisotropic MOF-on-MOF Growth of Isostructural Multilayer Metal–Organic Framework Heterostructures
Isostructural MOFs with similar crystallographic parameter are easily available for MOF-on-MOF growth and possible to form core–shell structure by isotropic growth. However, due to well-matched cell lattice, selective growth in isostructural MOF heterostructures remains a great challenge for enginee...
| Main Authors: | , , , , , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
American Association for the Advancement of Science (AAAS)
2021-01-01
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| Series: | Research |
| Online Access: | http://dx.doi.org/10.34133/2021/9854946 |
| _version_ | 1797287532061261824 |
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| author | Zhida Gu Wenlei Zhang Ting Pan Yu Shen Peishan Qin Peng Zhang Xiaohan Li Liwei Liu Linjie Li Yu Fu Weina Zhang Fengwei Huo |
| author_facet | Zhida Gu Wenlei Zhang Ting Pan Yu Shen Peishan Qin Peng Zhang Xiaohan Li Liwei Liu Linjie Li Yu Fu Weina Zhang Fengwei Huo |
| author_sort | Zhida Gu |
| collection | DOAJ |
| description | Isostructural MOFs with similar crystallographic parameter are easily available for MOF-on-MOF growth and possible to form core–shell structure by isotropic growth. However, due to well-matched cell lattice, selective growth in isostructural MOF heterostructures remains a great challenge for engineering atypical MOF heterostructures. Herein, an anisotropic MOF-on-MOF growth strategy was developed to structure a range of multilayer sandwich-like ZIF-L heterostructures via stacking isostructural ZIF-L-Zn and ZIF-L-Co alternately with three-, five-, seven-, and more layer structures. Moreover, these heterostructures with highly designable feature were fantastic precursors for fabricating derivatives with tunable magnetic and catalytic properties. Such strategy explores a novel way of achieving anisotropic MOF-on-MOF growth between isostructural MOFs and opens up new horizons for regulating the properties by MOF modular assembly in versatile functional nanocomposites. |
| first_indexed | 2024-03-07T18:34:31Z |
| format | Article |
| id | doaj.art-dfa6178612bf44a98adc7ed997bbee1c |
| institution | Directory Open Access Journal |
| issn | 2639-5274 |
| language | English |
| last_indexed | 2024-03-07T18:34:31Z |
| publishDate | 2021-01-01 |
| publisher | American Association for the Advancement of Science (AAAS) |
| record_format | Article |
| series | Research |
| spelling | doaj.art-dfa6178612bf44a98adc7ed997bbee1c2024-03-02T05:26:17ZengAmerican Association for the Advancement of Science (AAAS)Research2639-52742021-01-01202110.34133/2021/9854946Anisotropic MOF-on-MOF Growth of Isostructural Multilayer Metal–Organic Framework HeterostructuresZhida Gu0Wenlei Zhang1Ting Pan2Yu Shen3Peishan Qin4Peng Zhang5Xiaohan Li6Liwei Liu7Linjie Li8Yu Fu9Weina Zhang10Fengwei Huo11College of Science, Northeastern University, Shenyang 100819, ChinaCollege of Science, Northeastern University, Shenyang 100819, ChinaKey Laboratory of Flexible Electronics (KLOFE), Institute of Advanced Materials (IAM), Nanjing Tech University (NanjingTech), Nanjing 211800, ChinaKey Laboratory of Flexible Electronics (KLOFE), Institute of Advanced Materials (IAM), Nanjing Tech University (NanjingTech), Nanjing 211800, ChinaKey Laboratory of Flexible Electronics (KLOFE), Institute of Advanced Materials (IAM), Nanjing Tech University (NanjingTech), Nanjing 211800, ChinaKey Laboratory of Flexible Electronics (KLOFE), Institute of Advanced Materials (IAM), Nanjing Tech University (NanjingTech), Nanjing 211800, ChinaCollege of Science, Northeastern University, Shenyang 100819, ChinaKey Laboratory of Flexible Electronics (KLOFE), Institute of Advanced Materials (IAM), Nanjing Tech University (NanjingTech), Nanjing 211800, ChinaCollege of Science, Northeastern University, Shenyang 100819, ChinaCollege of Science, Northeastern University, Shenyang 100819, ChinaKey Laboratory of Flexible Electronics (KLOFE), Institute of Advanced Materials (IAM), Nanjing Tech University (NanjingTech), Nanjing 211800, ChinaKey Laboratory of Flexible Electronics (KLOFE), Institute of Advanced Materials (IAM), Nanjing Tech University (NanjingTech), Nanjing 211800, ChinaIsostructural MOFs with similar crystallographic parameter are easily available for MOF-on-MOF growth and possible to form core–shell structure by isotropic growth. However, due to well-matched cell lattice, selective growth in isostructural MOF heterostructures remains a great challenge for engineering atypical MOF heterostructures. Herein, an anisotropic MOF-on-MOF growth strategy was developed to structure a range of multilayer sandwich-like ZIF-L heterostructures via stacking isostructural ZIF-L-Zn and ZIF-L-Co alternately with three-, five-, seven-, and more layer structures. Moreover, these heterostructures with highly designable feature were fantastic precursors for fabricating derivatives with tunable magnetic and catalytic properties. Such strategy explores a novel way of achieving anisotropic MOF-on-MOF growth between isostructural MOFs and opens up new horizons for regulating the properties by MOF modular assembly in versatile functional nanocomposites.http://dx.doi.org/10.34133/2021/9854946 |
| spellingShingle | Zhida Gu Wenlei Zhang Ting Pan Yu Shen Peishan Qin Peng Zhang Xiaohan Li Liwei Liu Linjie Li Yu Fu Weina Zhang Fengwei Huo Anisotropic MOF-on-MOF Growth of Isostructural Multilayer Metal–Organic Framework Heterostructures Research |
| title | Anisotropic MOF-on-MOF Growth of Isostructural Multilayer Metal–Organic Framework Heterostructures |
| title_full | Anisotropic MOF-on-MOF Growth of Isostructural Multilayer Metal–Organic Framework Heterostructures |
| title_fullStr | Anisotropic MOF-on-MOF Growth of Isostructural Multilayer Metal–Organic Framework Heterostructures |
| title_full_unstemmed | Anisotropic MOF-on-MOF Growth of Isostructural Multilayer Metal–Organic Framework Heterostructures |
| title_short | Anisotropic MOF-on-MOF Growth of Isostructural Multilayer Metal–Organic Framework Heterostructures |
| title_sort | anisotropic mof on mof growth of isostructural multilayer metal organic framework heterostructures |
| url | http://dx.doi.org/10.34133/2021/9854946 |
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