Eley–Rideal model of heterogeneous catalytic carbamate formation based on CO2–MEA absorptions with CaCO3, MgCO3 and BaCO3

Eley–Rideal model of heterogeneous catalytic carbamate formation based on CO2–MEA absorptions with CaCO3, MgCO3 and BaCO3

The mechanism was proposed of heterogeneous catalytic CO2 absorptions with primary/secondary amines involving ‘catalytic carbamate formation’. Compared with the non-catalytic ‘Zwitterion mechanism’, this Eley–Rideal model was proposed for CO2 + RR′NH with MCO3 (M = Ca, Mg, and Ba) with four elementa...

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Detalles Bibliográficos
Main Authors: Huancong Shi, Min Huang, Yuandong Huang, Lifeng Cui, Linna Zheng, Mingqi Cui, Linhua Jiang, Hussameldin Ibrahim, Paitoon Tontiwachwuthikul
Formato: Artigo
Idioma:English
Publicado: The Royal Society 2019-05-01
Series:Royal Society Open Science
Subjects:
co2 absorption and desorption
heterogeneous catalysis
eley–rideal model
zwitterion mechanism
solid surface reactions
Acceso en liña:https://royalsocietypublishing.org/doi/pdf/10.1098/rsos.190311

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