Synthesis and Characterization of a Binuclear Copper(II)-dipyriamethyrin Complex: [Cu<sub>2</sub>(dipyriamethyrin)(μ<sub>2</sub>-1,1-acetato)<sub>2</sub>]
The reaction between dipyriamethyrin and copper(II) acetate [Cu(OAc)<sub>2</sub>] afforded what is, to our knowledge, the first transition metal-dipyriamethyrin complex. Molecular and electronic characterization of this binuclear Cu(II) complex via EPR, UV-vis, and single crystal X-ray d...
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| Format: | Article |
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MDPI AG
2020-03-01
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| Series: | Molecules |
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| Online Access: | https://www.mdpi.com/1420-3049/25/6/1446 |
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| author | James T. Brewster Harrison D. Root Hadiqa Zafar Gregory D. Thiabaud Adam C. Sedgwick Jiaming He Vincent M. Lynch Jonathan L. Sessler |
| author_facet | James T. Brewster Harrison D. Root Hadiqa Zafar Gregory D. Thiabaud Adam C. Sedgwick Jiaming He Vincent M. Lynch Jonathan L. Sessler |
| author_sort | James T. Brewster |
| collection | DOAJ |
| description | The reaction between dipyriamethyrin and copper(II) acetate [Cu(OAc)<sub>2</sub>] afforded what is, to our knowledge, the first transition metal-dipyriamethyrin complex. Molecular and electronic characterization of this binuclear Cu(II) complex via EPR, UV-vis, and single crystal X-ray diffraction analysis revealed marked differences between the present constructs and previously reported binuclear copper(II) hexaphyrin species. UV-vis titration analyses provided evidence for a homotropic positive allosteric effect, wherein the binuclear species is formed without significant intermediacy of a monomeric complex. |
| first_indexed | 2024-12-13T02:34:25Z |
| format | Article |
| id | doaj.art-dfbc258acff7499883222b27b9c32ba1 |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-12-13T02:34:25Z |
| publishDate | 2020-03-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-dfbc258acff7499883222b27b9c32ba12022-12-22T00:02:26ZengMDPI AGMolecules1420-30492020-03-01256144610.3390/molecules25061446molecules25061446Synthesis and Characterization of a Binuclear Copper(II)-dipyriamethyrin Complex: [Cu<sub>2</sub>(dipyriamethyrin)(μ<sub>2</sub>-1,1-acetato)<sub>2</sub>]James T. Brewster0Harrison D. Root1Hadiqa Zafar2Gregory D. Thiabaud3Adam C. Sedgwick4Jiaming He5Vincent M. Lynch6Jonathan L. Sessler7Department of Chemistry, The University of Texas at Austin 105 E 24th Street-Stop A5300, Austin, TX 78712-1224, USADepartment of Chemistry, The University of Texas at Austin 105 E 24th Street-Stop A5300, Austin, TX 78712-1224, USADepartment of Chemistry, The University of Texas at Austin 105 E 24th Street-Stop A5300, Austin, TX 78712-1224, USADepartment of Chemistry, The University of Texas at Austin 105 E 24th Street-Stop A5300, Austin, TX 78712-1224, USADepartment of Chemistry, The University of Texas at Austin 105 E 24th Street-Stop A5300, Austin, TX 78712-1224, USAMaterials Science and Engineering Program and Texas Materials Institute, The University of Texas at Austin, Austin, TX 78712, USADepartment of Chemistry, The University of Texas at Austin 105 E 24th Street-Stop A5300, Austin, TX 78712-1224, USADepartment of Chemistry, The University of Texas at Austin 105 E 24th Street-Stop A5300, Austin, TX 78712-1224, USAThe reaction between dipyriamethyrin and copper(II) acetate [Cu(OAc)<sub>2</sub>] afforded what is, to our knowledge, the first transition metal-dipyriamethyrin complex. Molecular and electronic characterization of this binuclear Cu(II) complex via EPR, UV-vis, and single crystal X-ray diffraction analysis revealed marked differences between the present constructs and previously reported binuclear copper(II) hexaphyrin species. UV-vis titration analyses provided evidence for a homotropic positive allosteric effect, wherein the binuclear species is formed without significant intermediacy of a monomeric complex.https://www.mdpi.com/1420-3049/25/6/1446dipyriamethyrinexpanded porphyrinbinuclear copperporphyrinoidallosteric effect |
| spellingShingle | James T. Brewster Harrison D. Root Hadiqa Zafar Gregory D. Thiabaud Adam C. Sedgwick Jiaming He Vincent M. Lynch Jonathan L. Sessler Synthesis and Characterization of a Binuclear Copper(II)-dipyriamethyrin Complex: [Cu<sub>2</sub>(dipyriamethyrin)(μ<sub>2</sub>-1,1-acetato)<sub>2</sub>] Molecules dipyriamethyrin expanded porphyrin binuclear copper porphyrinoid allosteric effect |
| title | Synthesis and Characterization of a Binuclear Copper(II)-dipyriamethyrin Complex: [Cu<sub>2</sub>(dipyriamethyrin)(μ<sub>2</sub>-1,1-acetato)<sub>2</sub>] |
| title_full | Synthesis and Characterization of a Binuclear Copper(II)-dipyriamethyrin Complex: [Cu<sub>2</sub>(dipyriamethyrin)(μ<sub>2</sub>-1,1-acetato)<sub>2</sub>] |
| title_fullStr | Synthesis and Characterization of a Binuclear Copper(II)-dipyriamethyrin Complex: [Cu<sub>2</sub>(dipyriamethyrin)(μ<sub>2</sub>-1,1-acetato)<sub>2</sub>] |
| title_full_unstemmed | Synthesis and Characterization of a Binuclear Copper(II)-dipyriamethyrin Complex: [Cu<sub>2</sub>(dipyriamethyrin)(μ<sub>2</sub>-1,1-acetato)<sub>2</sub>] |
| title_short | Synthesis and Characterization of a Binuclear Copper(II)-dipyriamethyrin Complex: [Cu<sub>2</sub>(dipyriamethyrin)(μ<sub>2</sub>-1,1-acetato)<sub>2</sub>] |
| title_sort | synthesis and characterization of a binuclear copper ii dipyriamethyrin complex cu sub 2 sub dipyriamethyrin μ sub 2 sub 1 1 acetato sub 2 sub |
| topic | dipyriamethyrin expanded porphyrin binuclear copper porphyrinoid allosteric effect |
| url | https://www.mdpi.com/1420-3049/25/6/1446 |
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