Cobalt(II) chloride complexes with some phosphine oxides: compatibility between structural data for the solid complexes and their stability constants in acetone medium
Binary complexes of general formula CoCl2L2, where L = triphenylphosphine oxide (TPPO), benzyldiphenylphosphine oxide (BDPPO), dibenzylphenylphosphine oxide (DBPPO) and tribenzylphosphine oxide (TBPO) were considered concerning X-ray structural data for the complexes in the solid state and their sta...
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| Format: | Article |
| Language: | English |
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Universidade Estadual Paulista
2019-04-01
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| Series: | Eclética Química |
| Online Access: | https://revista.iq.unesp.br/ojs/index.php/ecletica/article/view/1013 |
| _version_ | 1819210015490179072 |
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| author | Antonio Carlos Massabni Cristo Bladimiros Melios |
| author_facet | Antonio Carlos Massabni Cristo Bladimiros Melios |
| author_sort | Antonio Carlos Massabni |
| collection | DOAJ |
| description | Binary complexes of general formula CoCl2L2, where L = triphenylphosphine oxide (TPPO), benzyldiphenylphosphine oxide (BDPPO), dibenzylphenylphosphine oxide (DBPPO) and tribenzylphosphine oxide (TBPO) were considered concerning X-ray structural data for the complexes in the solid state and their stability constants in acetone solution. Compatibility between structural data and stability constants are pointed out. Previous investigations showed that in acetone medium, with CoCl2 as reference acceptor, the following basicity order is obeyed: TBPO > DBPPO > BDPPO > TPPO. This sequence is supported by X-ray diffraction data of the solid complexes and by electrolytic conductance values for these complexes both in acetone and in nitromethane media. |
| first_indexed | 2024-12-23T06:04:27Z |
| format | Article |
| id | doaj.art-dfcf3a3c182a4072a7f3e1908c4dc97d |
| institution | Directory Open Access Journal |
| issn | 1678-4618 |
| language | English |
| last_indexed | 2024-12-23T06:04:27Z |
| publishDate | 2019-04-01 |
| publisher | Universidade Estadual Paulista |
| record_format | Article |
| series | Eclética Química |
| spelling | doaj.art-dfcf3a3c182a4072a7f3e1908c4dc97d2022-12-21T17:57:35ZengUniversidade Estadual PaulistaEclética Química1678-46182019-04-01442535510.26850/1678-4618eqj.v44.2.2019.p53-551013Cobalt(II) chloride complexes with some phosphine oxides: compatibility between structural data for the solid complexes and their stability constants in acetone mediumAntonio Carlos Massabni0Cristo Bladimiros Melios1Institute of Chemistry Unesp Araraquara (Unesp) University of Araraquara (Uniara)Institute of Chemistry Unesp Araraquara (Unesp)Binary complexes of general formula CoCl2L2, where L = triphenylphosphine oxide (TPPO), benzyldiphenylphosphine oxide (BDPPO), dibenzylphenylphosphine oxide (DBPPO) and tribenzylphosphine oxide (TBPO) were considered concerning X-ray structural data for the complexes in the solid state and their stability constants in acetone solution. Compatibility between structural data and stability constants are pointed out. Previous investigations showed that in acetone medium, with CoCl2 as reference acceptor, the following basicity order is obeyed: TBPO > DBPPO > BDPPO > TPPO. This sequence is supported by X-ray diffraction data of the solid complexes and by electrolytic conductance values for these complexes both in acetone and in nitromethane media.https://revista.iq.unesp.br/ojs/index.php/ecletica/article/view/1013 |
| spellingShingle | Antonio Carlos Massabni Cristo Bladimiros Melios Cobalt(II) chloride complexes with some phosphine oxides: compatibility between structural data for the solid complexes and their stability constants in acetone medium Eclética Química |
| title | Cobalt(II) chloride complexes with some phosphine oxides: compatibility between structural data for the solid complexes and their stability constants in acetone medium |
| title_full | Cobalt(II) chloride complexes with some phosphine oxides: compatibility between structural data for the solid complexes and their stability constants in acetone medium |
| title_fullStr | Cobalt(II) chloride complexes with some phosphine oxides: compatibility between structural data for the solid complexes and their stability constants in acetone medium |
| title_full_unstemmed | Cobalt(II) chloride complexes with some phosphine oxides: compatibility between structural data for the solid complexes and their stability constants in acetone medium |
| title_short | Cobalt(II) chloride complexes with some phosphine oxides: compatibility between structural data for the solid complexes and their stability constants in acetone medium |
| title_sort | cobalt ii chloride complexes with some phosphine oxides compatibility between structural data for the solid complexes and their stability constants in acetone medium |
| url | https://revista.iq.unesp.br/ojs/index.php/ecletica/article/view/1013 |
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