Synthesis and length dependent photoluminescence property of zinc oxide nanorods

One-dimensional nanostructure ZnO nanorods (NRs) with controlled lengths and diameters were synthesized by the growth of colloidal nanoparticles and then characterized by XRD, TEM, Raman, PL and UV–Vis. The growth time parameter plays an important role in the formation process of ZnO NRs. The as-pre...

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Main Authors: Ishaq Musa, Naser Qamhieh, Saleh Thaker Mahmoud
Format: Article
Language:English
Published: Elsevier 2017-01-01
Series:Results in Physics
Online Access:http://www.sciencedirect.com/science/article/pii/S2211379717311403
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author Ishaq Musa
Naser Qamhieh
Saleh Thaker Mahmoud
author_facet Ishaq Musa
Naser Qamhieh
Saleh Thaker Mahmoud
author_sort Ishaq Musa
collection DOAJ
description One-dimensional nanostructure ZnO nanorods (NRs) with controlled lengths and diameters were synthesized by the growth of colloidal nanoparticles and then characterized by XRD, TEM, Raman, PL and UV–Vis. The growth time parameter plays an important role in the formation process of ZnO NRs. The as-prepared nanoparticles has spherical shape with size about 4 nm, and formed single-crystalline NRs of length up to 150 nm and 16–20 nm in diameters. Raman spectra of the as-grown ZnO nanorods revealed the existence of Raman silent modes B1(low) and B1(high) at 273 and 538 cm−1 respectively. Photoluminescence (PL) and UV–visible absorption measurements have been performed at room temperature. The PL spectrum showed that the relative intensity of ultraviolet (UV) and defect bands depend on the length of ZnO nanorods. The peak of photoluminescence of UV band around 395 nm is strongly enhanced when the length of ZnO nanorods is reduced and the humps around 580 nm decreases. Keywords: ZnO nanorods, Raman spectroscopy, UV–Vis spectroscopy, Photoluminescence spectroscopy
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spelling doaj.art-dfd56e1ce5bd4f279a33e61ee61cdf772022-12-22T01:56:16ZengElsevierResults in Physics2211-37972017-01-01735523556Synthesis and length dependent photoluminescence property of zinc oxide nanorodsIshaq Musa0Naser Qamhieh1Saleh Thaker Mahmoud2Department of Physics, Palestine Technical University-Kadoorie, Tulkarm, P.O. Box 7, Palestine; Corresponding author.Department of Physics, UAE University, Al-Ain, P.O. Box 15551, United Arab EmiratesDepartment of Physics, UAE University, Al-Ain, P.O. Box 15551, United Arab EmiratesOne-dimensional nanostructure ZnO nanorods (NRs) with controlled lengths and diameters were synthesized by the growth of colloidal nanoparticles and then characterized by XRD, TEM, Raman, PL and UV–Vis. The growth time parameter plays an important role in the formation process of ZnO NRs. The as-prepared nanoparticles has spherical shape with size about 4 nm, and formed single-crystalline NRs of length up to 150 nm and 16–20 nm in diameters. Raman spectra of the as-grown ZnO nanorods revealed the existence of Raman silent modes B1(low) and B1(high) at 273 and 538 cm−1 respectively. Photoluminescence (PL) and UV–visible absorption measurements have been performed at room temperature. The PL spectrum showed that the relative intensity of ultraviolet (UV) and defect bands depend on the length of ZnO nanorods. The peak of photoluminescence of UV band around 395 nm is strongly enhanced when the length of ZnO nanorods is reduced and the humps around 580 nm decreases. Keywords: ZnO nanorods, Raman spectroscopy, UV–Vis spectroscopy, Photoluminescence spectroscopyhttp://www.sciencedirect.com/science/article/pii/S2211379717311403
spellingShingle Ishaq Musa
Naser Qamhieh
Saleh Thaker Mahmoud
Synthesis and length dependent photoluminescence property of zinc oxide nanorods
Results in Physics
title Synthesis and length dependent photoluminescence property of zinc oxide nanorods
title_full Synthesis and length dependent photoluminescence property of zinc oxide nanorods
title_fullStr Synthesis and length dependent photoluminescence property of zinc oxide nanorods
title_full_unstemmed Synthesis and length dependent photoluminescence property of zinc oxide nanorods
title_short Synthesis and length dependent photoluminescence property of zinc oxide nanorods
title_sort synthesis and length dependent photoluminescence property of zinc oxide nanorods
url http://www.sciencedirect.com/science/article/pii/S2211379717311403
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