Template-Free Synthesis of Sb2S3 Hollow Microspheres as Anode Materials for Lithium-Ion and Sodium-Ion Batteries
Abstract Hierarchical Sb2S3 hollow microspheres assembled by nanowires have been successfully synthesized by a simple and practical hydrothermal reaction. The possible formation process of this architecture was investigated by X-ray diffraction, focused-ion beam-scanning electron microscopy dual-bea...
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| Format: | Article |
| Language: | English |
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SpringerOpen
2017-10-01
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| Series: | Nano-Micro Letters |
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| Online Access: | http://link.springer.com/article/10.1007/s40820-017-0165-1 |
| _version_ | 1818544084583710720 |
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| author | Jianjun Xie Li Liu Jing Xia Yue Zhang Min Li Yan Ouyang Su Nie Xianyou Wang |
| author_facet | Jianjun Xie Li Liu Jing Xia Yue Zhang Min Li Yan Ouyang Su Nie Xianyou Wang |
| author_sort | Jianjun Xie |
| collection | DOAJ |
| description | Abstract Hierarchical Sb2S3 hollow microspheres assembled by nanowires have been successfully synthesized by a simple and practical hydrothermal reaction. The possible formation process of this architecture was investigated by X-ray diffraction, focused-ion beam-scanning electron microscopy dual-beam system, and transmission electron microscopy. When used as the anode material for lithium-ion batteries, Sb2S3 hollow microspheres manifest excellent rate property and enhanced lithium-storage capability and can deliver a discharge capacity of 674 mAh g−1 at a current density of 200 mA g−1 after 50 cycles. Even at a high current density of 5000 mA g−1, a discharge capacity of 541 mAh g−1 is achieved. Sb2S3 hollow microspheres also display a prominent sodium-storage capacity and maintain a reversible discharge capacity of 384 mAh g−1 at a current density of 200 mA g−1 after 50 cycles. The remarkable lithium/sodium-storage property may be attributed to the synergetic effect of its nanometer size and three-dimensional hierarchical architecture, and the outstanding stability property is attributed to the sufficient interior void space, which can buffer the volume expansion. |
| first_indexed | 2024-12-11T22:43:49Z |
| format | Article |
| id | doaj.art-dfdfa0cacc9f473ba782780bd60c585c |
| institution | Directory Open Access Journal |
| issn | 2311-6706 2150-5551 |
| language | English |
| last_indexed | 2024-12-11T22:43:49Z |
| publishDate | 2017-10-01 |
| publisher | SpringerOpen |
| record_format | Article |
| series | Nano-Micro Letters |
| spelling | doaj.art-dfdfa0cacc9f473ba782780bd60c585c2022-12-22T00:47:42ZengSpringerOpenNano-Micro Letters2311-67062150-55512017-10-0110111210.1007/s40820-017-0165-1Template-Free Synthesis of Sb2S3 Hollow Microspheres as Anode Materials for Lithium-Ion and Sodium-Ion BatteriesJianjun Xie0Li Liu1Jing Xia2Yue Zhang3Min Li4Yan Ouyang5Su Nie6Xianyou Wang7National Base for International Science and Technology Cooperation, National Local Joint Engineering Laboratory for Key Materials of New Energy Storage Battery, Hunan Province Key Laboratory of Electrochemical Energy Storage and Conversion, School of Chemistry, Xiangtan UniversityNational Base for International Science and Technology Cooperation, National Local Joint Engineering Laboratory for Key Materials of New Energy Storage Battery, Hunan Province Key Laboratory of Electrochemical Energy Storage and Conversion, School of Chemistry, Xiangtan UniversityNational Base for International Science and Technology Cooperation, National Local Joint Engineering Laboratory for Key Materials of New Energy Storage Battery, Hunan Province Key Laboratory of Electrochemical Energy Storage and Conversion, School of Chemistry, Xiangtan UniversityNational Base for International Science and Technology Cooperation, National Local Joint Engineering Laboratory for Key Materials of New Energy Storage Battery, Hunan Province Key Laboratory of Electrochemical Energy Storage and Conversion, School of Chemistry, Xiangtan UniversityNational Base for International Science and Technology Cooperation, National Local Joint Engineering Laboratory for Key Materials of New Energy Storage Battery, Hunan Province Key Laboratory of Electrochemical Energy Storage and Conversion, School of Chemistry, Xiangtan UniversityNational Base for International Science and Technology Cooperation, National Local Joint Engineering Laboratory for Key Materials of New Energy Storage Battery, Hunan Province Key Laboratory of Electrochemical Energy Storage and Conversion, School of Chemistry, Xiangtan UniversityNational Base for International Science and Technology Cooperation, National Local Joint Engineering Laboratory for Key Materials of New Energy Storage Battery, Hunan Province Key Laboratory of Electrochemical Energy Storage and Conversion, School of Chemistry, Xiangtan UniversityNational Base for International Science and Technology Cooperation, National Local Joint Engineering Laboratory for Key Materials of New Energy Storage Battery, Hunan Province Key Laboratory of Electrochemical Energy Storage and Conversion, School of Chemistry, Xiangtan UniversityAbstract Hierarchical Sb2S3 hollow microspheres assembled by nanowires have been successfully synthesized by a simple and practical hydrothermal reaction. The possible formation process of this architecture was investigated by X-ray diffraction, focused-ion beam-scanning electron microscopy dual-beam system, and transmission electron microscopy. When used as the anode material for lithium-ion batteries, Sb2S3 hollow microspheres manifest excellent rate property and enhanced lithium-storage capability and can deliver a discharge capacity of 674 mAh g−1 at a current density of 200 mA g−1 after 50 cycles. Even at a high current density of 5000 mA g−1, a discharge capacity of 541 mAh g−1 is achieved. Sb2S3 hollow microspheres also display a prominent sodium-storage capacity and maintain a reversible discharge capacity of 384 mAh g−1 at a current density of 200 mA g−1 after 50 cycles. The remarkable lithium/sodium-storage property may be attributed to the synergetic effect of its nanometer size and three-dimensional hierarchical architecture, and the outstanding stability property is attributed to the sufficient interior void space, which can buffer the volume expansion.http://link.springer.com/article/10.1007/s40820-017-0165-1Sb2S3Hollow microspheresAnode materialLithium-ion batteriesSodium-storage property |
| spellingShingle | Jianjun Xie Li Liu Jing Xia Yue Zhang Min Li Yan Ouyang Su Nie Xianyou Wang Template-Free Synthesis of Sb2S3 Hollow Microspheres as Anode Materials for Lithium-Ion and Sodium-Ion Batteries Nano-Micro Letters Sb2S3 Hollow microspheres Anode material Lithium-ion batteries Sodium-storage property |
| title | Template-Free Synthesis of Sb2S3 Hollow Microspheres as Anode Materials for Lithium-Ion and Sodium-Ion Batteries |
| title_full | Template-Free Synthesis of Sb2S3 Hollow Microspheres as Anode Materials for Lithium-Ion and Sodium-Ion Batteries |
| title_fullStr | Template-Free Synthesis of Sb2S3 Hollow Microspheres as Anode Materials for Lithium-Ion and Sodium-Ion Batteries |
| title_full_unstemmed | Template-Free Synthesis of Sb2S3 Hollow Microspheres as Anode Materials for Lithium-Ion and Sodium-Ion Batteries |
| title_short | Template-Free Synthesis of Sb2S3 Hollow Microspheres as Anode Materials for Lithium-Ion and Sodium-Ion Batteries |
| title_sort | template free synthesis of sb2s3 hollow microspheres as anode materials for lithium ion and sodium ion batteries |
| topic | Sb2S3 Hollow microspheres Anode material Lithium-ion batteries Sodium-storage property |
| url | http://link.springer.com/article/10.1007/s40820-017-0165-1 |
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