Synthesis and structural characterization of a novel lead coordination polymer: [Pb(L)(1,3-bdc)]·2H2O

A novel coordination polymer, [Pb(L)(1,3-bdc)]·2H2O (1), (L = 2-(2,6-dichlorophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline, 1,3-H2bdc = 1,3-benzenedicarboxylic acid) has been successfully prepared under hydrothermal conditions. The structure of 1 is a 1D chain structure, which further stacks togethe...

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Bibliographic Details
Main Authors: Li Ziru, Zhao Jiaqi, Lou Meiqi, Wang Xiuyan
Format: Article
Language:English
Published: De Gruyter 2022-09-01
Series:Main Group Metal Chemistry
Subjects:
Online Access:https://doi.org/10.1515/mgmc-2022-0021
Description
Summary:A novel coordination polymer, [Pb(L)(1,3-bdc)]·2H2O (1), (L = 2-(2,6-dichlorophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline, 1,3-H2bdc = 1,3-benzenedicarboxylic acid) has been successfully prepared under hydrothermal conditions. The structure of 1 is a 1D chain structure, which further stacks together to form a 3D supramolecular architecture by π–π interactions and C–H⋯π interactions. In addition, the thermogravimetric analysis of 1 has been investigated.
ISSN:2191-0219