Tris(phenanthroline-κ2N,N′)cobalt(II) tetrafluoridoborate acetonitrile solvate
In the crystal structure of the title compound, [Co(C12H8N2)3](BF4)2·CH3CN, the molecular packing involves dimers of distorted octahedrally coordinated cations which are held together by one π–π [centroid–centroid = 3.542 (4) ...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2008-12-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808036611 |
| _version_ | 1819290828955189248 |
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| author | Harry Adams Phimphaka Harding David J. Harding |
| author_facet | Harry Adams Phimphaka Harding David J. Harding |
| author_sort | Harry Adams |
| collection | DOAJ |
| description | In the crystal structure of the title compound, [Co(C12H8N2)3](BF4)2·CH3CN, the molecular packing involves dimers of distorted octahedrally coordinated cations which are held together by one π–π [centroid–centroid = 3.542 (4) Å] and two C—H...π interactions [2.573 (4) Å] resulting in a P4AE (Parallel Fourfold Aryl Embrace) motif. The anions are found in aryl boxes formed from the phenanthroline ligands. |
| first_indexed | 2024-12-24T03:28:57Z |
| format | Article |
| id | doaj.art-dfea092c11704e4ba87e982ec566a531 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T03:28:57Z |
| publishDate | 2008-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-dfea092c11704e4ba87e982ec566a5312022-12-21T17:17:16ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-12-016412m1538m153810.1107/S1600536808036611Tris(phenanthroline-κ2N,N′)cobalt(II) tetrafluoridoborate acetonitrile solvateHarry AdamsPhimphaka HardingDavid J. HardingIn the crystal structure of the title compound, [Co(C12H8N2)3](BF4)2·CH3CN, the molecular packing involves dimers of distorted octahedrally coordinated cations which are held together by one π–π [centroid–centroid = 3.542 (4) Å] and two C—H...π interactions [2.573 (4) Å] resulting in a P4AE (Parallel Fourfold Aryl Embrace) motif. The anions are found in aryl boxes formed from the phenanthroline ligands.http://scripts.iucr.org/cgi-bin/paper?S1600536808036611 |
| spellingShingle | Harry Adams Phimphaka Harding David J. Harding Tris(phenanthroline-κ2N,N′)cobalt(II) tetrafluoridoborate acetonitrile solvate Acta Crystallographica Section E |
| title | Tris(phenanthroline-κ2N,N′)cobalt(II) tetrafluoridoborate acetonitrile solvate |
| title_full | Tris(phenanthroline-κ2N,N′)cobalt(II) tetrafluoridoborate acetonitrile solvate |
| title_fullStr | Tris(phenanthroline-κ2N,N′)cobalt(II) tetrafluoridoborate acetonitrile solvate |
| title_full_unstemmed | Tris(phenanthroline-κ2N,N′)cobalt(II) tetrafluoridoborate acetonitrile solvate |
| title_short | Tris(phenanthroline-κ2N,N′)cobalt(II) tetrafluoridoborate acetonitrile solvate |
| title_sort | tris phenanthroline 954 2n n 8242 cobalt ii tetrafluoridoborate acetonitrile solvate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808036611 |
| work_keys_str_mv | AT harryadams trisphenanthroline9542nn8242cobaltiitetrafluoridoborateacetonitrilesolvate AT phimphakaharding trisphenanthroline9542nn8242cobaltiitetrafluoridoborateacetonitrilesolvate AT davidjharding trisphenanthroline9542nn8242cobaltiitetrafluoridoborateacetonitrilesolvate |