Synthesis, Characterization, and Luminescent Properties of Polymer Complexes of Nd(III) with β-Dicarbonyl Ligands
Abstract The neodymium(III) complexes with 2-methyl-5-phenylpenten-1-3,5-dione and allyl-3-oxo-butanoate were synthesized. The polycomplexes on their basis and copolymers with styrene and N-vinylcarbazole in ratio 5:95 were obtained by free-radical polymerization. The results of above studies have s...
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| Format: | Article |
| Language: | English |
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SpringerOpen
2017-05-01
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| Series: | Nanoscale Research Letters |
| Subjects: | |
| Online Access: | http://link.springer.com/article/10.1186/s11671-017-2074-0 |
| _version_ | 1797726748043902976 |
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| author | Oleksandra Berezhnytska Irina Savchenko Nadiya Ivakha Olena Trunova Nataliya Rusakova Sergiy Smola Oleksandr Rogovtsov |
| author_facet | Oleksandra Berezhnytska Irina Savchenko Nadiya Ivakha Olena Trunova Nataliya Rusakova Sergiy Smola Oleksandr Rogovtsov |
| author_sort | Oleksandra Berezhnytska |
| collection | DOAJ |
| description | Abstract The neodymium(III) complexes with 2-methyl-5-phenylpenten-1-3,5-dione and allyl-3-oxo-butanoate were synthesized. The polycomplexes on their basis and copolymers with styrene and N-vinylcarbazole in ratio 5:95 were obtained by free-radical polymerization. The results of above studies have shown that the configuration of the chelate unit is unchanged during the polymerization. As a result, the type of coordination was determined and the structure of coordination polyhedra was assumed. The luminescence spectra of obtained metallocomplexes and polymers in solutions and solid state are investigated and analyzed. |
| first_indexed | 2024-03-12T10:50:01Z |
| format | Article |
| id | doaj.art-dfeda40efbb948808660580d64bcaa79 |
| institution | Directory Open Access Journal |
| issn | 1931-7573 1556-276X |
| language | English |
| last_indexed | 2024-03-12T10:50:01Z |
| publishDate | 2017-05-01 |
| publisher | SpringerOpen |
| record_format | Article |
| series | Nanoscale Research Letters |
| spelling | doaj.art-dfeda40efbb948808660580d64bcaa792023-09-02T07:06:53ZengSpringerOpenNanoscale Research Letters1931-75731556-276X2017-05-011211810.1186/s11671-017-2074-0Synthesis, Characterization, and Luminescent Properties of Polymer Complexes of Nd(III) with β-Dicarbonyl LigandsOleksandra Berezhnytska0Irina Savchenko1Nadiya Ivakha2Olena Trunova3Nataliya Rusakova4Sergiy Smola5Oleksandr Rogovtsov6V.I.Vernadsky Institute of General and Inorganic Chemistry, NASUNational Taras Shevchenko University of KyivV.I.Vernadsky Institute of General and Inorganic Chemistry, NASUV.I.Vernadsky Institute of General and Inorganic Chemistry, NASUA.V. Bogatsky Physico-Chemical Institute, NASUA.V. Bogatsky Physico-Chemical Institute, NASUV.I.Vernadsky Institute of General and Inorganic Chemistry, NASUAbstract The neodymium(III) complexes with 2-methyl-5-phenylpenten-1-3,5-dione and allyl-3-oxo-butanoate were synthesized. The polycomplexes on their basis and copolymers with styrene and N-vinylcarbazole in ratio 5:95 were obtained by free-radical polymerization. The results of above studies have shown that the configuration of the chelate unit is unchanged during the polymerization. As a result, the type of coordination was determined and the structure of coordination polyhedra was assumed. The luminescence spectra of obtained metallocomplexes and polymers in solutions and solid state are investigated and analyzed.http://link.springer.com/article/10.1186/s11671-017-2074-0Neodymium(III)Polymer complexesSpectraStructureLuminescence |
| spellingShingle | Oleksandra Berezhnytska Irina Savchenko Nadiya Ivakha Olena Trunova Nataliya Rusakova Sergiy Smola Oleksandr Rogovtsov Synthesis, Characterization, and Luminescent Properties of Polymer Complexes of Nd(III) with β-Dicarbonyl Ligands Nanoscale Research Letters Neodymium(III) Polymer complexes Spectra Structure Luminescence |
| title | Synthesis, Characterization, and Luminescent Properties of Polymer Complexes of Nd(III) with β-Dicarbonyl Ligands |
| title_full | Synthesis, Characterization, and Luminescent Properties of Polymer Complexes of Nd(III) with β-Dicarbonyl Ligands |
| title_fullStr | Synthesis, Characterization, and Luminescent Properties of Polymer Complexes of Nd(III) with β-Dicarbonyl Ligands |
| title_full_unstemmed | Synthesis, Characterization, and Luminescent Properties of Polymer Complexes of Nd(III) with β-Dicarbonyl Ligands |
| title_short | Synthesis, Characterization, and Luminescent Properties of Polymer Complexes of Nd(III) with β-Dicarbonyl Ligands |
| title_sort | synthesis characterization and luminescent properties of polymer complexes of nd iii with β dicarbonyl ligands |
| topic | Neodymium(III) Polymer complexes Spectra Structure Luminescence |
| url | http://link.springer.com/article/10.1186/s11671-017-2074-0 |
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