Crystal structure and Hirshfeld surface analysis of bis(2,6-diaminopyridinium) tetrachloridocobaltate(II)
In the title molecular salt, (C5H8N3)2[CoCl4], the cations are protonated at their pyridine N atoms and the anion is an almost regular tetrahedron. The crystal structure consists of alternating inorganic layers, built from tetrachloridocobaltate anions, and organic layers formed by protonated cation...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2018-04-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989018003171 |
| _version_ | 1818971243727028224 |
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| author | Oumaima Ben Moussa Hammouda Chebbi Mohamed Faouzi Zid |
| author_facet | Oumaima Ben Moussa Hammouda Chebbi Mohamed Faouzi Zid |
| author_sort | Oumaima Ben Moussa |
| collection | DOAJ |
| description | In the title molecular salt, (C5H8N3)2[CoCl4], the cations are protonated at their pyridine N atoms and the anion is an almost regular tetrahedron. The crystal structure consists of alternating inorganic layers, built from tetrachloridocobaltate anions, and organic layers formed by protonated cations of 2,6-diaminopyridinium. The crystal packing is governed by C/N—H...Cl hydrogen-bonding interactions between the organic and the inorganic ions and Cl...Cl interactions. Moreover, the cations show a π–π stacking interaction [intercentroid distance = 3.763 (2) Å]. The prevalence of these interactions is illustrated by an analysis of the three-dimensional Hirshfeld surface and by two-dimensional fingerprint plots. |
| first_indexed | 2024-12-20T14:49:17Z |
| format | Article |
| id | doaj.art-dff65271e1fb4722be24bdf853b3a10b |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-12-20T14:49:17Z |
| publishDate | 2018-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-dff65271e1fb4722be24bdf853b3a10b2022-12-21T19:37:01ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902018-04-0174443644010.1107/S2056989018003171hb7732Crystal structure and Hirshfeld surface analysis of bis(2,6-diaminopyridinium) tetrachloridocobaltate(II)Oumaima Ben Moussa0Hammouda Chebbi1Mohamed Faouzi Zid2University of Tunis El Manar, Faculty of Sciences of Tunis, Laboratory of Materials, Crystal Chemistry and Applied Thermodynamics, 2092 El Manar II, Tunis, TunisiaUniversity of Tunis El Manar, Faculty of Sciences of Tunis, Laboratory of Materials, Crystal Chemistry and Applied Thermodynamics, 2092 El Manar II, Tunis, TunisiaUniversity of Tunis El Manar, Faculty of Sciences of Tunis, Laboratory of Materials, Crystal Chemistry and Applied Thermodynamics, 2092 El Manar II, Tunis, TunisiaIn the title molecular salt, (C5H8N3)2[CoCl4], the cations are protonated at their pyridine N atoms and the anion is an almost regular tetrahedron. The crystal structure consists of alternating inorganic layers, built from tetrachloridocobaltate anions, and organic layers formed by protonated cations of 2,6-diaminopyridinium. The crystal packing is governed by C/N—H...Cl hydrogen-bonding interactions between the organic and the inorganic ions and Cl...Cl interactions. Moreover, the cations show a π–π stacking interaction [intercentroid distance = 3.763 (2) Å]. The prevalence of these interactions is illustrated by an analysis of the three-dimensional Hirshfeld surface and by two-dimensional fingerprint plots.http://scripts.iucr.org/cgi-bin/paper?S2056989018003171cobalt(II)hybrid organic–inorganic materialscrystal structureHirshfeld surfacefingerprint plots |
| spellingShingle | Oumaima Ben Moussa Hammouda Chebbi Mohamed Faouzi Zid Crystal structure and Hirshfeld surface analysis of bis(2,6-diaminopyridinium) tetrachloridocobaltate(II) Acta Crystallographica Section E: Crystallographic Communications cobalt(II) hybrid organic–inorganic materials crystal structure Hirshfeld surface fingerprint plots |
| title | Crystal structure and Hirshfeld surface analysis of bis(2,6-diaminopyridinium) tetrachloridocobaltate(II) |
| title_full | Crystal structure and Hirshfeld surface analysis of bis(2,6-diaminopyridinium) tetrachloridocobaltate(II) |
| title_fullStr | Crystal structure and Hirshfeld surface analysis of bis(2,6-diaminopyridinium) tetrachloridocobaltate(II) |
| title_full_unstemmed | Crystal structure and Hirshfeld surface analysis of bis(2,6-diaminopyridinium) tetrachloridocobaltate(II) |
| title_short | Crystal structure and Hirshfeld surface analysis of bis(2,6-diaminopyridinium) tetrachloridocobaltate(II) |
| title_sort | crystal structure and hirshfeld surface analysis of bis 2 6 diaminopyridinium tetrachloridocobaltate ii |
| topic | cobalt(II) hybrid organic–inorganic materials crystal structure Hirshfeld surface fingerprint plots |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989018003171 |
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