Nanodiamond Particles as Secondary Additive for Polyalphaolefin Oil Lubrication of Steel–Aluminium Contact

Nanodiamond (ND) particles are effective lubricant additives. Attention of research has shifted towards investigating the particles as secondary additives. ND particles provide more benefits as secondary additives than as the sole lubricant additive for steel–steel contacts. In this work, the influe...

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Main Authors: Ankush Raina, Mir Irfan Ul Haq, Ankush Anand, Sanjay Mohan, Rajiv Kumar, Subramanian Jayalakshmi, Ramachandra Arvind Singh
Format: Article
Language:English
Published: MDPI AG 2021-05-01
Series:Nanomaterials
Subjects:
Online Access:https://www.mdpi.com/2079-4991/11/6/1438
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author Ankush Raina
Mir Irfan Ul Haq
Ankush Anand
Sanjay Mohan
Rajiv Kumar
Subramanian Jayalakshmi
Ramachandra Arvind Singh
author_facet Ankush Raina
Mir Irfan Ul Haq
Ankush Anand
Sanjay Mohan
Rajiv Kumar
Subramanian Jayalakshmi
Ramachandra Arvind Singh
author_sort Ankush Raina
collection DOAJ
description Nanodiamond (ND) particles are effective lubricant additives. Attention of research has shifted towards investigating the particles as secondary additives. ND particles provide more benefits as secondary additives than as the sole lubricant additive for steel–steel contacts. In this work, the influence of ND particles as secondary additives on oil lubrication of steel–aluminium tribopair (hard–soft contact) was examined. AISI 52100 steel balls were slid against AA2024 aluminium alloy discs, in the presence of polyalphaolefin (PAO) base oil, in boundary lubrication regime (applied normal load: 10 N to 50 N). Primary additives were copper oxide (CuO) and hexagonal boron nitride (h-BN) nanoparticles. The addition of ND particles to PAO, with CuO and h-BN as primary additives, at the lowest applied normal load of 10 N: (i) decreased the volumetric wear of the aluminium discs by 28% and 63%, respectively, and (ii) decreased the coefficient of friction by 15% and 33%, respectively. At the highest applied normal load of 50 N, it: (i) decreased the volumetric wear of the aluminium discs by 20% and 38%, respectively, and (ii) decreased the coefficient of friction by 5.4% and 8%, respectively. ND particles as secondary additives significantly reduce energy loss and power loss as a consequence of an effective reduction in friction during sliding. Unique characteristics of ND particles—such as their (a) physicochemical and thermal properties, (b) ball bearing and polishing effects and (c) synergistic interaction with primary additives to form stable tribofilms—enhance the lubrication performance of steel–aluminium contact. ND particles in combination with h-BN nanoparticles showed the best performance, due to better synergy between the primary additive and the secondary additive. Results from the investigation indicate that ND particles taken as secondary additives in small amount (0.2 wt%) can improve oil lubrication performance of hard–soft contacts in engineering systems.
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spelling doaj.art-e009af62c88040749a27b4e48a6386722023-11-21T22:01:03ZengMDPI AGNanomaterials2079-49912021-05-01116143810.3390/nano11061438Nanodiamond Particles as Secondary Additive for Polyalphaolefin Oil Lubrication of Steel–Aluminium ContactAnkush Raina0Mir Irfan Ul Haq1Ankush Anand2Sanjay Mohan3Rajiv Kumar4Subramanian Jayalakshmi5Ramachandra Arvind Singh6School of Mechanical Engineering, Shri Mata Vaishno Devi University, Katra 182320, Jammu and Kashmir, IndiaSchool of Mechanical Engineering, Shri Mata Vaishno Devi University, Katra 182320, Jammu and Kashmir, IndiaSchool of Mechanical Engineering, Shri Mata Vaishno Devi University, Katra 182320, Jammu and Kashmir, IndiaSchool of Mechanical Engineering, Shri Mata Vaishno Devi University, Katra 182320, Jammu and Kashmir, IndiaSchool of Mechanical Engineering, Shri Mata Vaishno Devi University, Katra 182320, Jammu and Kashmir, IndiaSchool of Mechanical and Electrical Engineering, Wenzhou University, Wenzhou 325035, ChinaSchool of Mechanical and Electrical Engineering, Wenzhou University, Wenzhou 325035, ChinaNanodiamond (ND) particles are effective lubricant additives. Attention of research has shifted towards investigating the particles as secondary additives. ND particles provide more benefits as secondary additives than as the sole lubricant additive for steel–steel contacts. In this work, the influence of ND particles as secondary additives on oil lubrication of steel–aluminium tribopair (hard–soft contact) was examined. AISI 52100 steel balls were slid against AA2024 aluminium alloy discs, in the presence of polyalphaolefin (PAO) base oil, in boundary lubrication regime (applied normal load: 10 N to 50 N). Primary additives were copper oxide (CuO) and hexagonal boron nitride (h-BN) nanoparticles. The addition of ND particles to PAO, with CuO and h-BN as primary additives, at the lowest applied normal load of 10 N: (i) decreased the volumetric wear of the aluminium discs by 28% and 63%, respectively, and (ii) decreased the coefficient of friction by 15% and 33%, respectively. At the highest applied normal load of 50 N, it: (i) decreased the volumetric wear of the aluminium discs by 20% and 38%, respectively, and (ii) decreased the coefficient of friction by 5.4% and 8%, respectively. ND particles as secondary additives significantly reduce energy loss and power loss as a consequence of an effective reduction in friction during sliding. Unique characteristics of ND particles—such as their (a) physicochemical and thermal properties, (b) ball bearing and polishing effects and (c) synergistic interaction with primary additives to form stable tribofilms—enhance the lubrication performance of steel–aluminium contact. ND particles in combination with h-BN nanoparticles showed the best performance, due to better synergy between the primary additive and the secondary additive. Results from the investigation indicate that ND particles taken as secondary additives in small amount (0.2 wt%) can improve oil lubrication performance of hard–soft contacts in engineering systems.https://www.mdpi.com/2079-4991/11/6/1438nanodiamondPAO oilcopper oxidehexagonal boron nitridenanolubricationwear
spellingShingle Ankush Raina
Mir Irfan Ul Haq
Ankush Anand
Sanjay Mohan
Rajiv Kumar
Subramanian Jayalakshmi
Ramachandra Arvind Singh
Nanodiamond Particles as Secondary Additive for Polyalphaolefin Oil Lubrication of Steel–Aluminium Contact
Nanomaterials
nanodiamond
PAO oil
copper oxide
hexagonal boron nitride
nanolubrication
wear
title Nanodiamond Particles as Secondary Additive for Polyalphaolefin Oil Lubrication of Steel–Aluminium Contact
title_full Nanodiamond Particles as Secondary Additive for Polyalphaolefin Oil Lubrication of Steel–Aluminium Contact
title_fullStr Nanodiamond Particles as Secondary Additive for Polyalphaolefin Oil Lubrication of Steel–Aluminium Contact
title_full_unstemmed Nanodiamond Particles as Secondary Additive for Polyalphaolefin Oil Lubrication of Steel–Aluminium Contact
title_short Nanodiamond Particles as Secondary Additive for Polyalphaolefin Oil Lubrication of Steel–Aluminium Contact
title_sort nanodiamond particles as secondary additive for polyalphaolefin oil lubrication of steel aluminium contact
topic nanodiamond
PAO oil
copper oxide
hexagonal boron nitride
nanolubrication
wear
url https://www.mdpi.com/2079-4991/11/6/1438
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