(R)-[1-(2-Chlorophenyl)-2-methoxy-2-oxoethyl][2-(thiophen-2-yl)ethyl]ammonium (+)-camphor-10-sulfonate acetone monosolvate
The title compound, C15H17ClNO2S+·C10H15O4S−·C3H6O, was synthesized by N-alkylation of α-amino-(2-chlorophenyl)acetate with 2-thienylethyl p-toluenesulfonate, followed by reaction with (+)-camphor-10-sulfonic acid. In the crystal, the cations and...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010-12-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053681004523X |
| _version_ | 1828854925277265920 |
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| author | Deng-Ke Liu Ying Liu Shuai Mu Yan-Shu Liang |
| author_facet | Deng-Ke Liu Ying Liu Shuai Mu Yan-Shu Liang |
| author_sort | Deng-Ke Liu |
| collection | DOAJ |
| description | The title compound, C15H17ClNO2S+·C10H15O4S−·C3H6O, was synthesized by N-alkylation of α-amino-(2-chlorophenyl)acetate with 2-thienylethyl p-toluenesulfonate, followed by reaction with (+)-camphor-10-sulfonic acid. In the crystal, the cations and anions are linked through N—H...O hydrogen bonds. The thiophene ring of the cation was found to be disordered over two sites, with refined occupancies of 0.798 (4) and 0.202 (4). |
| first_indexed | 2024-12-13T00:44:35Z |
| format | Article |
| id | doaj.art-e079783c98fa4f478b04873a45752ace |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T00:44:35Z |
| publishDate | 2010-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-e079783c98fa4f478b04873a45752ace2022-12-22T00:05:04ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-12-016612o3117o311710.1107/S160053681004523X(R)-[1-(2-Chlorophenyl)-2-methoxy-2-oxoethyl][2-(thiophen-2-yl)ethyl]ammonium (+)-camphor-10-sulfonate acetone monosolvateDeng-Ke LiuYing LiuShuai MuYan-Shu LiangThe title compound, C15H17ClNO2S+·C10H15O4S−·C3H6O, was synthesized by N-alkylation of α-amino-(2-chlorophenyl)acetate with 2-thienylethyl p-toluenesulfonate, followed by reaction with (+)-camphor-10-sulfonic acid. In the crystal, the cations and anions are linked through N—H...O hydrogen bonds. The thiophene ring of the cation was found to be disordered over two sites, with refined occupancies of 0.798 (4) and 0.202 (4).http://scripts.iucr.org/cgi-bin/paper?S160053681004523X |
| spellingShingle | Deng-Ke Liu Ying Liu Shuai Mu Yan-Shu Liang (R)-[1-(2-Chlorophenyl)-2-methoxy-2-oxoethyl][2-(thiophen-2-yl)ethyl]ammonium (+)-camphor-10-sulfonate acetone monosolvate Acta Crystallographica Section E |
| title | (R)-[1-(2-Chlorophenyl)-2-methoxy-2-oxoethyl][2-(thiophen-2-yl)ethyl]ammonium (+)-camphor-10-sulfonate acetone monosolvate |
| title_full | (R)-[1-(2-Chlorophenyl)-2-methoxy-2-oxoethyl][2-(thiophen-2-yl)ethyl]ammonium (+)-camphor-10-sulfonate acetone monosolvate |
| title_fullStr | (R)-[1-(2-Chlorophenyl)-2-methoxy-2-oxoethyl][2-(thiophen-2-yl)ethyl]ammonium (+)-camphor-10-sulfonate acetone monosolvate |
| title_full_unstemmed | (R)-[1-(2-Chlorophenyl)-2-methoxy-2-oxoethyl][2-(thiophen-2-yl)ethyl]ammonium (+)-camphor-10-sulfonate acetone monosolvate |
| title_short | (R)-[1-(2-Chlorophenyl)-2-methoxy-2-oxoethyl][2-(thiophen-2-yl)ethyl]ammonium (+)-camphor-10-sulfonate acetone monosolvate |
| title_sort | r 1 2 chlorophenyl 2 methoxy 2 oxoethyl 2 thiophen 2 yl ethyl ammonium camphor 10 sulfonate acetone monosolvate |
| url | http://scripts.iucr.org/cgi-bin/paper?S160053681004523X |
| work_keys_str_mv | AT dengkeliu r12chlorophenyl2methoxy2oxoethyl2thiophen2ylethylammoniumcamphor10sulfonateacetonemonosolvate AT yingliu r12chlorophenyl2methoxy2oxoethyl2thiophen2ylethylammoniumcamphor10sulfonateacetonemonosolvate AT shuaimu r12chlorophenyl2methoxy2oxoethyl2thiophen2ylethylammoniumcamphor10sulfonateacetonemonosolvate AT yanshuliang r12chlorophenyl2methoxy2oxoethyl2thiophen2ylethylammoniumcamphor10sulfonateacetonemonosolvate |