1-(3,5-Dinitrobenzoyl)-4-(2-methoxyphenyl)piperazine
In the title compound, C18H18N4O6, the piperazine ring adopts a chair conformation, the amidic N atom is planar (sum of angles = 360°) and the non-amidic N atom is pyramidal (343°). There are no hydrogen bonds of any kind in the crystal, but the molecules are linked by two independent π(nitrobenzene...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2020-11-01
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| Series: | IUCrData |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314620015230 |
| _version_ | 1819299100529524736 |
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| author | Chayanna Harish Chinthal Channappa N. Kavitha Hemmige S. Yathirajan Sabine Foro Christopher Glidewell |
| author_facet | Chayanna Harish Chinthal Channappa N. Kavitha Hemmige S. Yathirajan Sabine Foro Christopher Glidewell |
| author_sort | Chayanna Harish Chinthal |
| collection | DOAJ |
| description | In the title compound, C18H18N4O6, the piperazine ring adopts a chair conformation, the amidic N atom is planar (sum of angles = 360°) and the non-amidic N atom is pyramidal (343°). There are no hydrogen bonds of any kind in the crystal, but the molecules are linked by two independent π(nitrobenzene)...π(methoxybenzene) stacking interactions to form π-stacked sheets with inter-centroid separations of 3.8444 (12) and 3.9197 (12) Å. |
| first_indexed | 2024-12-24T05:40:26Z |
| format | Article |
| id | doaj.art-e08308ce09a04461bc5a673f6da08653 |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-12-24T05:40:26Z |
| publishDate | 2020-11-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-e08308ce09a04461bc5a673f6da086532022-12-21T17:12:51ZengInternational Union of CrystallographyIUCrData2414-31462020-11-01511x20152310.1107/S2414314620015230tk40651-(3,5-Dinitrobenzoyl)-4-(2-methoxyphenyl)piperazineChayanna Harish Chinthal0Channappa N. Kavitha1Hemmige S. Yathirajan2Sabine Foro3Christopher Glidewell4Department of Studies in Chemistry, University of Mysore, Manasagangotri, Mysuru-570 006, IndiaDepartment of Chemistry, Maharani's Science College for Women, Mysuru-570 001, IndiaDepartment of Studies in Chemistry, University of Mysore, Manasagangotri, Mysuru-570 006, IndiaInstitute of Materials Science, Darmstadt University of Technology, Alarich-Weiss-Strasse 2, D-64287 Darmstadt, GermanySchool of Chemistry, University of St Andrews, St Andrews, Fife KY16 9ST, UKIn the title compound, C18H18N4O6, the piperazine ring adopts a chair conformation, the amidic N atom is planar (sum of angles = 360°) and the non-amidic N atom is pyramidal (343°). There are no hydrogen bonds of any kind in the crystal, but the molecules are linked by two independent π(nitrobenzene)...π(methoxybenzene) stacking interactions to form π-stacked sheets with inter-centroid separations of 3.8444 (12) and 3.9197 (12) Å.http://scripts.iucr.org/cgi-bin/paper?S2414314620015230synthesiscrystalmolecular conformationπ–π stacking |
| spellingShingle | Chayanna Harish Chinthal Channappa N. Kavitha Hemmige S. Yathirajan Sabine Foro Christopher Glidewell 1-(3,5-Dinitrobenzoyl)-4-(2-methoxyphenyl)piperazine IUCrData synthesis crystal molecular conformation π–π stacking |
| title | 1-(3,5-Dinitrobenzoyl)-4-(2-methoxyphenyl)piperazine |
| title_full | 1-(3,5-Dinitrobenzoyl)-4-(2-methoxyphenyl)piperazine |
| title_fullStr | 1-(3,5-Dinitrobenzoyl)-4-(2-methoxyphenyl)piperazine |
| title_full_unstemmed | 1-(3,5-Dinitrobenzoyl)-4-(2-methoxyphenyl)piperazine |
| title_short | 1-(3,5-Dinitrobenzoyl)-4-(2-methoxyphenyl)piperazine |
| title_sort | 1 3 5 dinitrobenzoyl 4 2 methoxyphenyl piperazine |
| topic | synthesis crystal molecular conformation π–π stacking |
| url | http://scripts.iucr.org/cgi-bin/paper?S2414314620015230 |
| work_keys_str_mv | AT chayannaharishchinthal 135dinitrobenzoyl42methoxyphenylpiperazine AT channappankavitha 135dinitrobenzoyl42methoxyphenylpiperazine AT hemmigesyathirajan 135dinitrobenzoyl42methoxyphenylpiperazine AT sabineforo 135dinitrobenzoyl42methoxyphenylpiperazine AT christopherglidewell 135dinitrobenzoyl42methoxyphenylpiperazine |