Bis{μ-5-(diethylamino)-2-[(2-oxidoethoxy)iminomethyl]phenolato}dicopper(II) acetone solvate
The title complex, [Cu2(C13H18N2O3)2]·C3H6O, has been synthesized by the reaction of copper(II) acetate monohydrate with 5,5′-bis(diethylamino)-2,2′-[ethylenedioxybis(nitrilomethylidyne)]diphenol, where one of the N—O bonds of the ligand was cleaved during the...
Main Authors: | , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
International Union of Crystallography
2008-09-01
|
Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808024707 |
_version_ | 1818321817501171712 |
---|---|
author | Zhong-Wu Lv Xiao-Lu Tang Xue-Ni He Xiao Chen Wen-Kui Dong |
author_facet | Zhong-Wu Lv Xiao-Lu Tang Xue-Ni He Xiao Chen Wen-Kui Dong |
author_sort | Zhong-Wu Lv |
collection | DOAJ |
description | The title complex, [Cu2(C13H18N2O3)2]·C3H6O, has been synthesized by the reaction of copper(II) acetate monohydrate with 5,5′-bis(diethylamino)-2,2′-[ethylenedioxybis(nitrilomethylidyne)]diphenol, where one of the N—O bonds of the ligand was cleaved during the reaction. The complex molecule has a μ-dialkoxo-bridged binuclear structure with both CuII centers exhibiting a square-planar coordination geometry. |
first_indexed | 2024-12-13T10:46:56Z |
format | Article |
id | doaj.art-e095ec5428ca4fd8a16b9377709212d1 |
institution | Directory Open Access Journal |
issn | 1600-5368 |
language | English |
last_indexed | 2024-12-13T10:46:56Z |
publishDate | 2008-09-01 |
publisher | International Union of Crystallography |
record_format | Article |
series | Acta Crystallographica Section E |
spelling | doaj.art-e095ec5428ca4fd8a16b9377709212d12022-12-21T23:50:07ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-09-01649m1133m113310.1107/S1600536808024707Bis{μ-5-(diethylamino)-2-[(2-oxidoethoxy)iminomethyl]phenolato}dicopper(II) acetone solvateZhong-Wu LvXiao-Lu TangXue-Ni HeXiao ChenWen-Kui DongThe title complex, [Cu2(C13H18N2O3)2]·C3H6O, has been synthesized by the reaction of copper(II) acetate monohydrate with 5,5′-bis(diethylamino)-2,2′-[ethylenedioxybis(nitrilomethylidyne)]diphenol, where one of the N—O bonds of the ligand was cleaved during the reaction. The complex molecule has a μ-dialkoxo-bridged binuclear structure with both CuII centers exhibiting a square-planar coordination geometry.http://scripts.iucr.org/cgi-bin/paper?S1600536808024707 |
spellingShingle | Zhong-Wu Lv Xiao-Lu Tang Xue-Ni He Xiao Chen Wen-Kui Dong Bis{μ-5-(diethylamino)-2-[(2-oxidoethoxy)iminomethyl]phenolato}dicopper(II) acetone solvate Acta Crystallographica Section E |
title | Bis{μ-5-(diethylamino)-2-[(2-oxidoethoxy)iminomethyl]phenolato}dicopper(II) acetone solvate |
title_full | Bis{μ-5-(diethylamino)-2-[(2-oxidoethoxy)iminomethyl]phenolato}dicopper(II) acetone solvate |
title_fullStr | Bis{μ-5-(diethylamino)-2-[(2-oxidoethoxy)iminomethyl]phenolato}dicopper(II) acetone solvate |
title_full_unstemmed | Bis{μ-5-(diethylamino)-2-[(2-oxidoethoxy)iminomethyl]phenolato}dicopper(II) acetone solvate |
title_short | Bis{μ-5-(diethylamino)-2-[(2-oxidoethoxy)iminomethyl]phenolato}dicopper(II) acetone solvate |
title_sort | bis 956 5 diethylamino 2 2 oxidoethoxy iminomethyl phenolato dicopper ii acetone solvate |
url | http://scripts.iucr.org/cgi-bin/paper?S1600536808024707 |
work_keys_str_mv | AT zhongwulv bis9565diethylamino22oxidoethoxyiminomethylphenolatodicopperiiacetonesolvate AT xiaolutang bis9565diethylamino22oxidoethoxyiminomethylphenolatodicopperiiacetonesolvate AT xuenihe bis9565diethylamino22oxidoethoxyiminomethylphenolatodicopperiiacetonesolvate AT xiaochen bis9565diethylamino22oxidoethoxyiminomethylphenolatodicopperiiacetonesolvate AT wenkuidong bis9565diethylamino22oxidoethoxyiminomethylphenolatodicopperiiacetonesolvate |