MICROWAVE DIELECTRIC PROPERTIES OF Ba0.75Sr0.25 (NdxBi1-x)2Ti4O12 SOLID SOLUTION

This work investigated the influences of Bi content on the phase structure, phase composition, microstructure and microwave properties of tungstenbronze-type like Ba0.75Sr0.25(NdxBi1-x)2Ti4O12 ceramics. XRD patterns showed that the main crystal phase of the ceramics with different Bi content (0.75 ≤...

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Huvudupphovsmän: Long Mingzhu, ZHuang WENDONG, Tang Bin, Yu Shengquan, Zhou Xiaohua, Zhang Shuren
Materialtyp: Artikel
Språk:English
Publicerad: University of Chemistry and Technology, Prague 2011-12-01
Serie:Ceramics-Silikáty
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Länkar:http://www.ceramics-silikaty.cz/2011/pdf/2011_04_373.pdf
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author Long Mingzhu
ZHuang WENDONG
Tang Bin
Yu Shengquan
Zhou Xiaohua
Zhang Shuren
author_facet Long Mingzhu
ZHuang WENDONG
Tang Bin
Yu Shengquan
Zhou Xiaohua
Zhang Shuren
author_sort Long Mingzhu
collection DOAJ
description This work investigated the influences of Bi content on the phase structure, phase composition, microstructure and microwave properties of tungstenbronze-type like Ba0.75Sr0.25(NdxBi1-x)2Ti4O12 ceramics. XRD patterns showed that the main crystal phase of the ceramics with different Bi content (0.75 ≤ x ≤ 0.9) sintered at 1250°C to 1400°C for 3 h was BaNd2Ti4O12 with small amount of second phase Ba2Ti9O20. SEM photographs suggest that Bi could work as sintering aids promoting the densification and grain growth. In the case of the ratio of Nd and Bi (x : (1-x)) is 3:1 namely x is 0.75(B13), this ceramic shows optimum dielectric properties with a high dielectric constant (ε) of 118.5, a quality factor (Q × f) of 4907 (f = 2.8 GHz), and a temperature coefficient of resonant frequency tf = –1.3 ppm/°C. As the addition of Bi increased from 0.1 to 0.25, the value of ε markedly increased, the value of Q × f and tf decreased with a tf value finally approaching to zero.
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spelling doaj.art-e09bb841ef4b4574b4cd09a32da4d26c2022-12-22T01:22:15ZengUniversity of Chemistry and Technology, PragueCeramics-Silikáty0862-54681804-58472011-12-01554373377MICROWAVE DIELECTRIC PROPERTIES OF Ba0.75Sr0.25 (NdxBi1-x)2Ti4O12 SOLID SOLUTIONLong MingzhuZHuang WENDONGTang BinYu ShengquanZhou XiaohuaZhang ShurenThis work investigated the influences of Bi content on the phase structure, phase composition, microstructure and microwave properties of tungstenbronze-type like Ba0.75Sr0.25(NdxBi1-x)2Ti4O12 ceramics. XRD patterns showed that the main crystal phase of the ceramics with different Bi content (0.75 ≤ x ≤ 0.9) sintered at 1250°C to 1400°C for 3 h was BaNd2Ti4O12 with small amount of second phase Ba2Ti9O20. SEM photographs suggest that Bi could work as sintering aids promoting the densification and grain growth. In the case of the ratio of Nd and Bi (x : (1-x)) is 3:1 namely x is 0.75(B13), this ceramic shows optimum dielectric properties with a high dielectric constant (ε) of 118.5, a quality factor (Q × f) of 4907 (f = 2.8 GHz), and a temperature coefficient of resonant frequency tf = –1.3 ppm/°C. As the addition of Bi increased from 0.1 to 0.25, the value of ε markedly increased, the value of Q × f and tf decreased with a tf value finally approaching to zero.http://www.ceramics-silikaty.cz/2011/pdf/2011_04_373.pdfBa0.75Sr0.25 (NdxBi1-x)2Ti4O12Tungstenbronze-typeDielectric propertiesMicrowave
spellingShingle Long Mingzhu
ZHuang WENDONG
Tang Bin
Yu Shengquan
Zhou Xiaohua
Zhang Shuren
MICROWAVE DIELECTRIC PROPERTIES OF Ba0.75Sr0.25 (NdxBi1-x)2Ti4O12 SOLID SOLUTION
Ceramics-Silikáty
Ba0.75Sr0.25 (NdxBi1-x)2Ti4O12
Tungstenbronze-type
Dielectric properties
Microwave
title MICROWAVE DIELECTRIC PROPERTIES OF Ba0.75Sr0.25 (NdxBi1-x)2Ti4O12 SOLID SOLUTION
title_full MICROWAVE DIELECTRIC PROPERTIES OF Ba0.75Sr0.25 (NdxBi1-x)2Ti4O12 SOLID SOLUTION
title_fullStr MICROWAVE DIELECTRIC PROPERTIES OF Ba0.75Sr0.25 (NdxBi1-x)2Ti4O12 SOLID SOLUTION
title_full_unstemmed MICROWAVE DIELECTRIC PROPERTIES OF Ba0.75Sr0.25 (NdxBi1-x)2Ti4O12 SOLID SOLUTION
title_short MICROWAVE DIELECTRIC PROPERTIES OF Ba0.75Sr0.25 (NdxBi1-x)2Ti4O12 SOLID SOLUTION
title_sort microwave dielectric properties of ba0 75sr0 25 ndxbi1 x 2ti4o12 solid solution
topic Ba0.75Sr0.25 (NdxBi1-x)2Ti4O12
Tungstenbronze-type
Dielectric properties
Microwave
url http://www.ceramics-silikaty.cz/2011/pdf/2011_04_373.pdf
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AT tangbin microwavedielectricpropertiesofba075sr025ndxbi1x2ti4o12solidsolution
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