{2,2′-[o-Phenylenebis(nitrilomethanylylidene)]diphenolato-κ4O,N,N′,O′}nickel(II) monohydrate
The NiII atom in the title monohydrate, [Ni(C20H14N2O2)]·H2O, is coordinated within a cis-N2O2 square-planar donor set provided by the tetradentate Schiff base ligand. Overall, the molecule has a curved shape with the dihedral angle formed between the planes of the outer benzene rings b...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011-11-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811039730 |
| Summary: | The NiII atom in the title monohydrate, [Ni(C20H14N2O2)]·H2O, is coordinated within a cis-N2O2 square-planar donor set provided by the tetradentate Schiff base ligand. Overall, the molecule has a curved shape with the dihedral angle formed between the planes of the outer benzene rings being 13.92 (18)°. The water molecule was found to be disordered over two positions [ratio 0.80 (1):0.20 (1)] and the major component is linked to the complex via an O—H...O hydrogen bond. |
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| ISSN: | 1600-5368 |