Covalent Triazine Frameworks Based on the First <i>Pseudo</i>-Octahedral Hexanitrile Monomer via Nitrile Trimerization: Synthesis, Porosity, and CO<sub>2</sub> Gas Sorption Properties

Covalent Triazine Frameworks Based on the First <i>Pseudo</i>-Octahedral Hexanitrile Monomer via Nitrile Trimerization: Synthesis, Porosity, and CO<sub>2</sub> Gas Sorption Properties

Herein, we report the first synthesis of covalent triazine-based frameworks (CTFs) based on a hexanitrile monomer, namely the novel pseudo-octahedral hexanitrile 1,4-bis(tris(4′-cyano-phenyl)methyl)benzene <b>1</b> using both ionothermal reaction conditions with ZnCl<sub>2</sub&...

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Bibliographic Details
Main Authors: Isabelle D. Wessely, Alexandra M. Schade, Subarna Dey, Asamanjoy Bhunia, Alexander Nuhnen, Christoph Janiak, Stefan Bräse
Format: Article
Language:English
Published: MDPI AG 2021-06-01
Series:Materials
Subjects:
covalent triazine frameworks
CTFs
carbon dioxide adsorption
pseudo-octahedral hexanitrile
mixed linker
Online Access:https://www.mdpi.com/1996-1944/14/12/3214

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